Abstract
The reactions of commercial polychlorobiphenyl mixtures of Sovol and Trikhlorbifenil brands (Russia) with sodium methoxide were studied in dimethyl sulfoxide and methanol. It was shown for the first time that Sovol congeners are exhaustively converted, without formation of potentially toxic products, in the reaction with alkali metal alkoxide based on a monobasic aliphatic alcohol. This process is a stage of chemical pretreatment of polychlorobiphenyls subject to destruction for the subsequent microbiological mineralization of the new derivatives.
Similar content being viewed by others
References
Zanaveskin, L.N. and Aver’yanov, V.A., Usp. Khim., 1998, vol. 67, no. 8, pp. 789–800.
Gorbunova, T.I., Pervova, M.G., Zabelina, O.N., Saloutin, V.I., and Chupakhin, O.N., Polikhlorbifenily: Problemy ekologii, analiza i khimicheskoi utilizatsii (Polychlorobiphenyls: Environmental, Analytical, and Chemical Utilization Problems), Moscow: Krasand, 2011.
Egorova, D.O., Gorbunova, T.I., Pervova, M.G., and Demakov, V.A., Biotekhnol., 2013, no. 4, pp. 56–64.
Gorbunova, T.I., Pervova, M.G., Panyukova, A.A., Egorova, D.O., Saloutin, V.I., Demakov, V.A., and Chupakhin, O.N., Dokl. Chem., 2014, vol. 454, part 2, pp. 19–24.
van Noort, P.C.M., Chemosphere, 2009, vol. 74, no. 8, pp. 1024–1030.
Zabelina, O.N., Yatluk, Yu.G., Kirichenko, V.E., et al., Mass-Spektrom., 2005, vol. 2, no. 2, pp. 139–144.
Kirichenko, V.E., Pervova, M.G., Promyshlennikova, E.P., and Pashkevich, K.I., Analit. Kontrol., 2000, vol. 4, no. 1, pp. 41–44.
Shelepchikov, A.A. and Brodskii, E.S., Mass-Spektrom., 2015, vol. 12, no. 3, pp. 201–209.
Gorbunova, T.I., Subbotina, J.O., Saloutin, V.I., and Chupakhin, O.N., J. Hazard. Mater., 2014, vol. 278, pp. 491–499.
Pervova, M.G., Plotnikova, K.A., Gorbunova, T.I., Saloutin, V.I., and Chupakhin, O.N., Zh. Obshch. Khim., 2015, vol. 85, no. 8, pp. 1374–1379.
Treger, Yu.A., Khim. Zh., 2013, no. 1-2, pp. 30–34.
Zabelina, O.N., Gorbunova, T.I., Pervova, M.G., Kirichenko, V.E., Zapevalov, A.Ya., and Saloutin, V.I., Zh. Prikl. Khim., 2004, vol. 77, no. 9, pp. 1533–1538.
Author information
Authors and Affiliations
Additional information
Original Russian Text © K.A. Plotnikova, M.G. Pervova, T.I. Gorbunova, T.Sh. Khaibulova, V.P. Boyarskii, V.I. Saloutin, O.N. Chupakhin, 2017, published in Doklady Akademii Nauk, 2017, Vol. 476, No. 1, pp. 45–50.
Rights and permissions
About this article
Cite this article
Plotnikova, K.A., Pervova, M.G., Gorbunova, T.I. et al. Optimization of the chemical stage of pretreatment of technical polychlorobiphenyls for destruction. Dokl Chem 476, 206–210 (2017). https://doi.org/10.1134/S0012500817090038
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0012500817090038