Skip to main content
Log in

Effect of bulky substituents on the photochromic properties of indoline spiropyrans containing an annelated aromatic or heteroaromatic fragment

  • Chemistry
  • Published:
Doklady Chemistry Aims and scope Submit manuscript

Abstract

Novel indoline spiropyrans containing bulky neopentyl substituents at the nitrogen atom of the indoline fragment were prepared. The structure of the obtained compounds was established by a set of physicochemical methods of analysis. Comparison was made for the spectral absorption and kinetic parameters of the obtained compounds and their analogs containing methyl and benzyl substituents instead of neopentyl ones.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Crano, J.C. and Gugliemetti, R.J., Organic Photocromic and Termochromic Compounds, London: Kluwer, 2002.

    Book  Google Scholar 

  2. Tkachev, V.V., Aldoshin, S.M., Sanina, M.A., Luk’yanov, B.S., Minkin, V.I., Utenyshev, A.N, Khalanskii, K.N., and Alekseenko, Yu.S., Khim. Geterotsikl. Soedin., 2007, no. 5, pp. 690–702.

    Google Scholar 

  3. Tyurin, R.V, Luk’yanov, B.S., Chernyshev, A.V., Borodkin, G.S., Khalanskii, K.N., Chepeleva, L.V., and Luk’yanova, M.B., Khim. Geterotsikl. Soedin., 2014, no. 5, pp. 797–805.

    Google Scholar 

  4. Chibisov, A.K. and Gorner, H., Phys. Chem. Chem. Phys., 2001, no. 3, pp. 424–431.

    Article  CAS  Google Scholar 

  5. Rickwood, M., Hepworth, J.D., Gabbutt, C.D., and Sean, D., US Patent 5446151.

  6. Krongauz, V., Chif, A., Aizikovich, A., and Tchernoivanov, V., US Patent 6891038.

  7. Gel’man, N.E. and Terent’eva, E.A., Shanina, T.M., and Kiparenko L.M., Metody kolichestvennogo organicheskogo elementnogo analiza (Methods of Quantitative Organic Elemental Analysis), Moscow: Khimiya, 1987.

    Google Scholar 

  8. Wizinger, R. and Wenning, H., Helv. Chim. Acta, 1940, no. 23, pp. 247–271.

    Article  CAS  Google Scholar 

  9. Braude, E.V. and Gal’bershtam, M.A., Khim. Geterotsikl. Soedin., 1974, no. 7, pp. 943–0945.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. V. Tyurin.

Additional information

Original Russian Text © R.V. Tyurin, B.S. Lukyanov, A.V. Chernyshev, V.I. Malay, A.S. Kozlenko, N.S. Tkacheva, O.N. Burov, M.B. Lukyanova, 2016, published in Doklady Akademii Nauk, 2016, Vol. 470, No. 3, pp. 297–302.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tyurin, R.V., Lukyanov, B.S., Chernyshev, A.V. et al. Effect of bulky substituents on the photochromic properties of indoline spiropyrans containing an annelated aromatic or heteroaromatic fragment. Dokl Chem 470, 268–273 (2016). https://doi.org/10.1134/S0012500816090081

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0012500816090081

Navigation