Abstract
A unique method for the self-assembly of multilayer multichromic molecular crystals from three various polymethine dyes absorbing light in the broad spectral range has been developed. This method is based on the formation of an anionic platform of J-aggregates of magnesium complexes of thiamonomethinecyanines in an aqueous solution followed by the matrix synthesis of J-aggregates of two cationic trimethinecyanines on the surface of the platform. Spectral, luminescent, and photoelectric properties of the multichromic crystals of dyes have been studied. It has been shown that each multichromic organic crystal is a multilayer photoelement which possesses photoconductivity in three maxima of exciton absorption in the blue, green, and red spectral ranges with efficiency from 2.7 to 6.1%. The results form the basis for the technological development of high-organized molecular structures possessing unique optical and photoelectric properties with the aim of applying them in organic and hybrid organic/inorganic photonics and optoelectronics, including in the form of thin-film photoconverters in broad spectral ranges.
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References
J-Aggregates, Ed. by T. Kobayashi (World Scientific, Hong Kong, Singapore, New Jersey, London, 1996).
B. I. Shapiro, “Molecular assemblies of polymethine dyes,” Russ. Chem. Rev. 75, 433–456 (2006).
F. Würthner, T. E. Kaiser, and C. R. Saha-Möller, “J-aggregates: from serendipitous discovery to supramolecular engineering of functional dye material,” Angew. Chem., Int. Ed. Engl. 50, 3376–3410 (2011).
T. James, The Theory of Photographic Process (Macmillan, New York, 1966).
B. I. Shapiro, Theoretical Fundamentals of Photographic Process (Editorial URSS, Moscow, 2000) [in Russian].
N. Kometani, M. Tsubonishi, T. Fujita, K. Asami, and Y. Yonezawa, “Preparation and optical absorption spectra of dye-coated Au, Ag, and Au/Ag colloidal nanoparticles in aqueous solutions and in alternate assemblies,” Langmuir 17, 578–580 (2001).
G. P. Wiederrecht, G. A. Wurtz, and A. Bouhelier, “Ultrafast hybrid plasmonics,” Chem. Phys. Lett. 461, 171–179 (2008).
V. S. Lebedev, A. G. Vitukhnovsky, A. Yoshida, N. Kometani, and Y. Yonezawa, “Absorption properties of the composite silver/dye nanoparticles in colloidal solutions,” Colloids Surf., A 326, 204–209 (2008).
V. S. Lebedev, A. S. Medvedev, D. N. Vasil’ev, D. A. Chubich, and A. G. Vitukhnovskii, “Optical properties of noble-metal nanoparticles coated with a dye J-aggregate monolayer,” Quantum Electron. 40, 246–253 (2010).
B. I. Shapiro, E. S. Koltsova, A. G. Vitukhnovskii, D. A. Chubich, A. I. Tolmachev, and Y. L. Slominskii, “Interaction between gold nanoparticle plasmons and aggregates of polymethine dyes: ‘invisible’ nanoparticles,” Nanotechnol. Russ. 6, 456–462 (2011).
A. Vujačić, V. Vasić, M. Dramićanin, S. Sovilj, N. Bibić, J. Hranisavljevic, and G. Wiederrecht, “Kinetics of J-aggregate formation on the surface of Au nanoparticle colloids,” J. Phys. Chem. C 116, 4655–4661 (2012).
G. Wiederrecht, G. Wurtz, and J. Hranisavljevic, “J-aggregates on metal nanoparticles characterized through ultrafast spectroscopy and near-field optics,” Scanning 26 (5), 2–9 (2004).
V. S. Lebedev and A. S. Medvedev, “Plasmon–exciton coupling effects in light absorption and scattering by metal/J-aggregate bilayer nanoparticles,” Quantum Electro. 42, 701–713 (2012).
V. S. Lebedev and A. S. Medvedev, “Absorption and scattering of light by hybrid metal/J-aggregate nanoparticles: plasmon-exciton coupling and size effects,” J. Russ. Laser Res. 34, 303–322 (2013).
T. J. Antosiewicz, S. P. Apell, and T. Shegai, “Plasmon-exciton interactions in a core-shell geometry: from enhanced absorption to strong coupling,” ACS Photon. 1, 454–463 (2014).
A. Yoshida and N. Kometani, “Effect of the interaction between molecular exciton and localized surface plasmon on the spectroscopic properties of silver nanoparticles coated with cyanine dye J-aggregates,” J. Phys. Chem. C 114, 2867–2872 (2010).
V. S. Lebedev and A. S. Medvedev, “Optical properties of three-layer metal-organic nanoparticles with a molecular J-aggregate shell,” Quantum Electron. 43, 1065–1077 (2013).
D. Gülen, “A numerical spectroscopic investigation on the functionality of molecular excitons in tuning the plasmonic splitting observed in core/shell hybrid nanostructures,” J. Phys. Chem. C 114, 13825–13831 (2010).
A. D. Kondorskiy, K. S. Kislov, N. T. Lam, and V. S. Lebedev, “Absorption of light by hybrid metalorganic nanostructures of elongated shape,” J. Russ. Laser Res. 36, 175–192 (2015).
A. Yoshida, N. Uchida, and N. Kometani, “Synthesis and spectroscopic studies of composite gold nanorods with a double-shell structure composed of spacer and cyanine dye J-aggregate layers,” Langmuir 25, 11802–11807 (2009).
W. Ni, T. Ambjornsson, S. P. Apell, H. Chen, and J. Wang, “Observing plasmonic-molecular resonance coupling on single gold nanorods,” Nano Lett. 10, 77–84 (2010).
G. Zengin, G. Johansson, P. Johansson, T. J. Antosiewicz, M. Kall, and T. Shegai, “Approaching the strong coupling limit in single plasmonic nanorods interacting with J-aggregates,” Nat. Sci. Rep. 3, 3074 (2013).
D. Melnikau, D. Savateeva, A. Susha, A. L. Rogach, and Y. P. Rakovich, “Strong plasmon-exciton coupling in a hybrid system of gold nanostars and J-aggregates,” Nanoscale Res. Lett. 8, 134–140 (2013).
B. I. Shapiro, E. S. Tyshkunova, A. D. Kondorskii, and V. S. Lebedev, “Light absorption and plasmon–exciton interaction in three-layer nanorods with a gold core and outer shell composed of molecular J-and H-aggregates of dyes,” Quantum Electron. 45, 1153–1160 (2015).
T. D. Slavnova, A. K. Chibisov, and H. Gorner, “Kinetics of salt-induced J-aggregation of cyanine dyes,” J. Phys. Chem. A 109, 4758–4765 (2005).
B. I. Shapiro, E. A. Belonozhkina, O. A. Tyapina, and V. A. Kuz’min, “Influence of multicharged inorganic and organic cations on J-aggregation of polymethine dyes,” Nanotechnol. Russ. 5, 58–66 (2010).
B. I. Shapiro, “Block building of polymethine dye aggregates,” Nanotechnol. Russ. 3, 139–150 (2008).
A. D. Nekrasov and B. I. Shapiro, “Effect of multiply charged paramagnetic metal cations on J-aggregation of thiacyanine dyes,” High Energy Chem. 45, 133–139 (2011).
B. I. Shapiro, E. A. Satalkina, and A. D. Nekrasov, “Matrix synthesis of multilayer aggregates of polymethine dyes,” Nanotechnol. Russ. 9, 356–362 (2014).
B. I. Shapiro and E. V. Manulik, “Multichromic J-aggregates of cyanine dyes for visible and IR range of spectrum,” Nanotechnol. Russ. 11, 273–279 (2016).
N. A. Davidenko, A. A. Ishchenko, and V. A. Pavlov, “Features of photogeneration of charge carriers in films of amorphous molecular semiconductors doped with squarly dye,” Zh. Nauch. Prikl. Fotogr. 44 (2), 52–56 (1999).
N. Kometani, H. Nakajima, K. Asami, Y. Yonezawa, I. G. Scheblykin, and A. G. Vitukhnovsky, “Luminescence properties of the J-aggregate of cyanine dyes in multilayer assemblies,” J. Lumin. 87–89, 770–772 (2000).
A. V. Sorokin, N. V. Pereverzev, I. I. Grankina, S. L. Yefimova, and Yu. V. Malyukin, “Evidence of exciton self-trapping in pseudoisocyanine J-aggregates formed in layered polymer films,” J. Phys. Chem. C 119, 27865–27873 (2015).
S. L. Yefimova, A. V. Sorokin, I. K. Katrunov, and Yu. V. Malyukin, “Excitation localization effects in nanoscale molecular clusters (J-aggregates),” Low Temp. Phys. 32, 157–162 (2011).
J. L. Bricks, Y. L. Slominskii, I. D. Panas, and A. P. Demchenko, “Fluorescent J-aggregates of cyanine dyes: basic research and applications review,” Methods Appl. Fluoresc. 6, 01200 (2017).
O. P. Dimitriev, Y. P. Piryatinski, and Y. L. Slominskii, “Excimer emission in J-aggregates,” J. Phys. Chem. Lett. 9, 2138–2143 (2018).
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Original Russian Text © B.I. Shapiro, A.D. Nekrasov, V.S. Krivobok, E.V. Manulik, V.S. Lebedev, 2018, published in Rossiiskie Nanotekhnologii, 2018, Vol. 13, Nos. 5–6.
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Shapiro, B.I., Nekrasov, A.D., Krivobok, V.S. et al. Synthesis and Photophysical Properties of Multichromic Nanocrystals of Polymethine Dyes. Nanotechnol Russia 13, 281–289 (2018). https://doi.org/10.1134/S1995078018030151
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DOI: https://doi.org/10.1134/S1995078018030151