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Isomerization of Xylenes in the Presence of Pt-Containing Catalysts Based on Halloysite Aluminosilicate Nanotubes

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Pt-containing catalysts based on halloysite aluminosilicate nanotubes and ZSM-5 zeolite were synthesized. The structure of the materials was confirmed by low-temperature nitrogen adsorption/desorption and by transmission electron microscopy. The activity and selectivity of the synthesized catalysts based on micromesoporous supports in isomerization of the xylene reforming fraction was studied on a flow-through laboratory installation with a fixed catalyst bed in the temperature interval 360–440°С at elevated hydrogen pressure. The influence exerted by the textural characteristics of the support and acidity of the materials on the catalyst activity in isomerization of o- and m-xylenes and of ethylbenzene with the aim of obtaining p-xylene was studied.

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Correspondence to A. P. Glotov.

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Original Russian Text © A.P. Glotov, E.A. Roldugina, M.I. Artemova, E.M. Smirnova, N.R. Demikhova, V.D. Stytsenko, S.V. Egazar’yants, A.L. Maksimov, V.A. Vinokurov, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 8, pp. 1173−1183.

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Glotov, A.P., Roldugina, E.A., Artemova, M.I. et al. Isomerization of Xylenes in the Presence of Pt-Containing Catalysts Based on Halloysite Aluminosilicate Nanotubes. Russ J Appl Chem 91, 1353–1362 (2018). https://doi.org/10.1134/S1070427218080141

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  • DOI: https://doi.org/10.1134/S1070427218080141

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