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Hydroconversion of Oxidation Products of Sulfur-Containing Aromatic Compounds

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

Hydroconversion of benzo- and dibenzothiophene sulfone on a Ni–Mo sulfide catalyst based on mesoporous aluminosilicate Al-HMS and on unsupported catalysts prepared in situ in the course of decomposition of poorly soluble precursors (molybdenum hexacarbonyl, nickel naphthenate) was studied. Hydrogenation of sulfones was perfpormed at 250, 340, and 380°С and elevated СО pressure in the presence of water ensuring in situ generation of hydrogen via water-gas shift reaction.

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Authors and Affiliations

  1. Moscow State University, Moscow, 119991, Russia

    A. V. Vutolkina, A. V. Akopyan, A. L. Maksimov & E. A. Karakhanov

  2. Gubkin Russian State University of Oil and Gas (Natural Research University), Moscow, 119991, Russia

    A. P. Glotov & M. S. Kotelev

  3. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia

    A. L. Maksimov

Authors
  1. A. V. Vutolkina
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  2. A. V. Akopyan
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  3. A. P. Glotov
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  4. M. S. Kotelev
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  5. A. L. Maksimov
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  6. E. A. Karakhanov
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Corresponding author

Correspondence to A. V. Vutolkina.

Additional information

Original Russian Text © A.V. Vutolkina, A.V. Akopyan, A.P. Glotov, M.S. Kotelev, A.L. Maksimov, E.A. Karakhanov, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 6, pp. 850−858.

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Vutolkina, A.V., Akopyan, A.V., Glotov, A.P. et al. Hydroconversion of Oxidation Products of Sulfur-Containing Aromatic Compounds. Russ J Appl Chem 91, 981–989 (2018). https://doi.org/10.1134/S1070427218060162

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  • DOI: https://doi.org/10.1134/S1070427218060162

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