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Reaction of 3,4,6-Triisopropyl-о-benzoquinone with 3,4,6-Triisopropylcatechol

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Abstract

Formation of protonated 3,4,6-triisopropylsemiquinone radicals in solution of a mixture of 3,4,6- triisopropyl-о-benzoquinone and 3,4,6-triisopropylcatechol was shown using ESR spectroscopy. Heating the mixture to 110°С leads to the formation of the condensation products, additional amount of 3,4,6-triisopropylcatechol, and evolution of propylene. Mathematical simulation of the kinetics of the reaction was performed.

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Authors and Affiliations

  1. G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhny Novgorod, 603950, Russia

    Yu. A. Kurskii, A. S. Shavyrin, T. I. Kulikova, V. A. Kuropatov & G. A. Abakumov

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  1. Yu. A. Kurskii
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  2. A. S. Shavyrin
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  3. T. I. Kulikova
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  4. V. A. Kuropatov
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  5. G. A. Abakumov
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Correspondence to Yu. A. Kurskii.

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Original Russian Text © Yu.А. Kurskii, А.S. Shavyrin, Т.I. Kulikova, V.А. Kuropatov, G.А. Abakumov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 8, pp. 1262–1267.

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Kurskii, Y.A., Shavyrin, A.S., Kulikova, T.I. et al. Reaction of 3,4,6-Triisopropyl-о-benzoquinone with 3,4,6-Triisopropylcatechol. Russ J Gen Chem 88, 1584–1589 (2018). https://doi.org/10.1134/S1070363218080054

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  • DOI: https://doi.org/10.1134/S1070363218080054

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