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Interaction products in the system sulfur dioxide–2,2′-bipyridine–water. Van der Waals clathrates

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Abstract

Crystallization of 2,2′-bipyridine from aqueous solution containing sulfur(IV) oxide afforded clathrates with the composition (bipy) k · (SO2) m · (H2O) n . X-Ray amorphous guest SO2 molecules occupy voids in the crystal lattice of 2,2′-bipyridine without distortion of its structure. The isolated compounds were characterized by elemental analyses, X-ray diffraction data, and IR, NMR, and mass spectra.

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Authors and Affiliations

  1. Physicochemical Institute for Environmental and Human Protection, Ministry of Education and Science and National Academy of Sciences of Ukraine, ul. Preobrazhenskaya 3, Odessa, 65082, Ukraine

    R. E. Khoma & A. A. Ennan

  2. Mechnikov Odessa Natsional University, Dvoryanskaya ul. 2, Odessa, 65082, Ukraine

    R. E. Khoma

  3. Odessa National Medical University, Valikhovskii per. 2, Odessa, 65082, Ukraine

    V. O. Gelmboldt

  4. Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, Kharkiv, 61001, Ukraine

    V. N. Baumer

  5. Karazin Kharkiv National University, Kharkov, pl. Svobody 4, Kharkiv, 61022, Ukraine

    V. N. Baumer

  6. Taras Shevchenko National University of Kyiv, Vladimirskaya ul. 60, Kyiv, 01033, Ukraine

    M. D. Tsapko

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  1. R. E. Khoma
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  2. V. O. Gelmboldt
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  3. A. A. Ennan
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  5. M. D. Tsapko
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Correspondence to R. E. Khoma.

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Original Russian Text © R.E. Khoma, V.O. Gelmboldt, A.A. Ennan, V.N. Baumer, M.D. Tsapko, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 9, pp. 1471–1476.

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Khoma, R.E., Gelmboldt, V.O., Ennan, A.A. et al. Interaction products in the system sulfur dioxide–2,2′-bipyridine–water. Van der Waals clathrates. Russ J Gen Chem 86, 2037–2041 (2016). https://doi.org/10.1134/S1070363216090097

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  • DOI: https://doi.org/10.1134/S1070363216090097

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