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Syntheses and Characterization of Coordination Compounds of 3d-Metal 5-Sulfosalicylates with Phenylacethydrazide: Crystal Structure of [Ni(L)3]HSSal · 3H2O (L is Phenylacethydrazide, and HSSal2– is 5-Sulfosalicylic Acid Anion)

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Abstract

The complexes of 3d-metal 5-sulfosalicylates with phenylacethydrazide are synthesized: [Co(L)3]HSSal · 3H2O (I), [Ni(L)3]HSSal · 3H2O (II), and [Zn(L)3]HSSal · 6H2O (III) (L is phenylacethydrazide, and HSSal2– is 5-sulfosalicylic acid anion). Compounds I–III are characterized by the methods of chemical analysis, IR spectroscopy, diffuse reflectance spectroscopy, luminescence, and thermogravimetry. Compound II is studied by X-ray diffraction analysis (СIF file CCDC no. 1819696). In the complex cation [Ni(L)3]2+, the nickel atom has a face octahedral coordination mode by three O atoms and three N atoms of three bidentate chelate ligands L. The complex cations, HSSal2– anions, and crystallization water molecules are joined by a branched system of hydrogen bonds. Complexes I–III are luminescent, and complex III exhibits the brightest luminescence.

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REFERENCES

  1. Arjunan, V., Rani, T., Mythili, C.V., and Mohan, S., Spectrochim. Acta, Part A, 2011, vol. 79, no. 3, p. 486.

    Article  CAS  Google Scholar 

  2. Ul Ain, Q., Ashiq, U., Ara, J.R., and Mahrooof-Tahir, M., Spectrochim. Acta, Part A, 2013, vol. 115, p. 683.

    Article  CAS  Google Scholar 

  3. Fan, S.-R. and Zhu, L.-G., J. Mol. Struct., 2007, vol. 827, nos. 1–3, p. 188.

    Article  CAS  Google Scholar 

  4. Mistri, S., Zangrando, E., Farnetti, E., et al., Polyhedron, 2015, vol. 89, p. 250.

    Article  CAS  Google Scholar 

  5. Yan, Ch.-F., Jiang, F.-L., Chen, L., et al, J. Solid State Chem., 2009, vol. 182, no. 11, p. 3162.

    Article  CAS  Google Scholar 

  6. Lamshöft, M., Storp, J., Ivanova, B., et al., Polyhedron, 2011, vol. 30, no. 15, p. 2564.

    Article  CAS  Google Scholar 

  7. Koksharova, T.V., Sergienko, V.S., Surazhskaya, M.D., et al., Russ. J. Inorg. Chem., 2017, vol. 62, no. 12, p. 1568. doi 10.1134/S0036023617120105

    Article  CAS  Google Scholar 

  8. Xia, M. and Wei, C.-L., J. Struct. Chem., 2013, vol. 54, no. 1, p. 110.

    Article  CAS  Google Scholar 

  9. Gao, Sh., Huo, L.-H., Zhao, H., et al., Acta Crystallogr., Sect E: Struct. Rep. Online, 2005, vol. 61, no. 2, p. m290.

    Article  CAS  Google Scholar 

  10. Han, Q., Wang, X.-Ch., Li, X.-Y., et al., Acta Crystallogr., Sect E: Struct. Rep. Online, 2009, vol. 65, no. 11, p. m1282.

    Article  CAS  Google Scholar 

  11. Yenikaya, C., Sari, M., Ilkimen, H., et al., Polyhedron, 2011, vol. 30, no. 3, p. 535.

    Article  CAS  Google Scholar 

  12. Chen, Zh.-F., Shi, Sh.-M., Hu, R.-X., et al., Chin. J. Chem., 2003, vol. 21, no. 8, p. 1059.

    CAS  Google Scholar 

  13. Sun, Y.-Q., Fan, L.-L., Gao, D.-Zh., et al., Dalton Trans., 2010, vol. 39, no. 40, p. 9654.

    Article  CAS  PubMed  Google Scholar 

  14. Antsyshkina, A.S., Koksharova, T.V., Sergienko, V.S., et al., Russ. J. Inorg. Chem., 2014, vol. 59, no. 12, p. 1417. doi 10.1134/S0036023614120031

    Article  CAS  Google Scholar 

  15. Lagorio, M.G., Dicelio, L.E., Litter, M.I., et al., J. Chem. Soc., Faraday Trans., 1998, vol. 94, no. 3, p. 419.

    Article  Google Scholar 

  16. Bril, A. and de Jager-Veenis, A.W., J. Electrochem. Soc., 1976, vol. 123, no. 3, p. 396.

    Article  CAS  Google Scholar 

  17. Nazarov, M., Noh, D.Y., Sohn, J., et al., J. Solid State Chem., 2007, vol. 180, no. 9, p. 2493.

    Article  CAS  Google Scholar 

  18. APEX2, SAINT, SADABS, Madison: Bruker AXS Inc., 2008–2009.

  19. Altomare, A., Gascsrano, G., Giacovazzo, C., and Guagliard, A., J. Appl. Cryst. A, 1993, vol. 26, p. 343.

    Article  Google Scholar 

  20. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.

    Article  CAS  Google Scholar 

  21. Odunola, O.A., Adeoye, I.O., and Woods, J.A.O., Synth. React. Inorg. Metal-Org. Chem., 2002, vol. 32, no. 4, p. 801.

    Article  CAS  Google Scholar 

  22. Jensen, J.B., Acta Chem. Scand., 1956, vol. 10, no. 4, p. 667.

    Article  CAS  Google Scholar 

  23. Gordon, A. and Ford, R., The Chemist’s Companion: A Handbook of Practical Data, Techniques, and References, New York: Wiley, 1972.

    Google Scholar 

  24. Ul Ain, Q., Ashiq, U., Ara, J.R., et al., Arab. J. Chem., 2017, vol. 1, no. 4, p. 488.

    Article  CAS  Google Scholar 

  25. Issa, R.M., El-Shazly, M.F., and Iskander, M.F., Z. Anorg. Allg. Chem., 1967, vol. 354, nos. 1−2, p. 90.

    Article  CAS  Google Scholar 

  26. Zidan, A.S.A., Synth. React. Inorg. Metal-Org. Chem., 2004, vol. 34, no. 4, p. 743.

    Article  CAS  Google Scholar 

  27. Gogorishvili, P.V., Karkarashvili, M.V., and Kalandarishvili, D.Z., Zh. Neorg. Khim., 1969, vol. 14, no. 6, p. 1516.

    CAS  Google Scholar 

  28. Dutta, A.A. and Chaudhuri, N.R., J. Inorg. Nucl. Chem., 1971, vol. 33, no. 1, p. 189.

    Article  Google Scholar 

  29. Odunola, O.A., Adeoye, I.O., Woods, J.A.O., et al., Synth. React. Inorg Metal-Org. Chem., 2003, vol. 33, no. 2, p. 205.

    Article  CAS  Google Scholar 

  30. Narang, K.K. and Singh, M., Synth. React. Inorg. Metal-Org. Chem., 1985, vol. 15, no. 6, p. 821.

    Article  CAS  Google Scholar 

  31. Narang, K.K., Pandey, J.P., Singh, K.P., et al., Synth. React. Inorg. Metal-Org. Chem., 1990, vol. 20, no. 10, p. 1301.

    Article  CAS  Google Scholar 

  32. Fan, S.-R. and Zhu, L.-G., Chin. J. Chem., 2005, vol. 23, no. 10, p. 1292.

    Article  CAS  Google Scholar 

  33. Varghese, T.H., Panicker, Y.C., and Philip, D., J. Raman Spectrosc., 2007, vol. 38, no. 3, p. 309.

    Article  CAS  Google Scholar 

  34. Nakanishi, K. Infrared Spectra Absorption Spectroscopy, Tokyo: Nankodo Company, 1962.

    Google Scholar 

  35. Lever, A., Inorganic Electronic Spectroscopy, New York: Elesvier, 1984, vol. 2.

    Google Scholar 

  36. Fabbrizzi, L., Licchelli, M., Pallavicini, P., et al., Analyst, 1996, vol. 121, p. 1763.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Odessa National University, Odessa, Ukraine

    T. V. Koksharova & T. V. Mandzii

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    V. S. Sergienko & M. D. Surazhskaya

  3. All-Russia Institute of Scientific and Technical Information, Russian Academy of Sciences, Moscow, Russia

    V. S. Sergienko

  4. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine

    E. N. Fadeev

Authors
  1. T. V. Koksharova
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  2. V. S. Sergienko
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  3. M. D. Surazhskaya
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  4. T. V. Mandzii
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  5. E. N. Fadeev
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Correspondence to V. S. Sergienko.

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Translated by E. Yablonskaya

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Koksharova, T.V., Sergienko, V.S., Surazhskaya, M.D. et al. Syntheses and Characterization of Coordination Compounds of 3d-Metal 5-Sulfosalicylates with Phenylacethydrazide: Crystal Structure of [Ni(L)3]HSSal · 3H2O (L is Phenylacethydrazide, and HSSal2– is 5-Sulfosalicylic Acid Anion). Russ J Coord Chem 44, 678–687 (2018). https://doi.org/10.1134/S1070328418110040

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  • DOI: https://doi.org/10.1134/S1070328418110040

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