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Mono- and Binuclear Chloride and Bromide Complexes of Bi(III) with Double-Charged Cations Based on Pyridine: Syntheses and Crystal Structures

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Abstract

The reactions of solutions obtained by the reactions of Bi2O3 with 2 M HCl and HBr with the salts containing bis(pyridyl)alkane cations afford mono- and binuclear halide complexes (Py-(CH2)3-Py)3[Bi2Br9]2 (I), (H3O)(Py-(CH2)4-Py)[BiCl6] ⋅ 3H2O (II), and (H2Bpp)2[Bi2Br10] ⋅ 2H2O (Bpp is 1,3-bis(4-pyridyl)propane) (III). The structures of the synthesized compounds are determined by X-ray diffraction analysis (СIF files CCDC no. 1583338–1583340, respectively).

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Authors and Affiliations

  1. Novosibirsk State University, 630090, Novosibirsk, Russia

    I. D. Gorokh, S. A. Adonin, D. G. Samsonenko & V. P. Fedin

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    S. A. Adonin, D. G. Samsonenko, M. N. Sokolov & V. P. Fedin

  3. Kazan (Volga region) Federal University, Kazan, Russia

    M. N. Sokolov

Authors
  1. I. D. Gorokh
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  2. S. A. Adonin
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  3. D. G. Samsonenko
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  4. M. N. Sokolov
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  5. V. P. Fedin
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Correspondence to S. A. Adonin.

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Translated by E. Yablonskaya

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Gorokh, I.D., Adonin, S.A., Samsonenko, D.G. et al. Mono- and Binuclear Chloride and Bromide Complexes of Bi(III) with Double-Charged Cations Based on Pyridine: Syntheses and Crystal Structures. Russ J Coord Chem 44, 502–506 (2018). https://doi.org/10.1134/S1070328418080031

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  • DOI: https://doi.org/10.1134/S1070328418080031

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