Skip to main content
Log in

Additive poly[3-(trimethylsilyl)tricyclononene-7]: Molecular properties and chain rigidity

  • Structure and Properties
  • Published:
Polymer Science Series A Aims and scope Submit manuscript

Abstract

With the use of the methods of hydrodynamics, the Kerr electrooptical effect, and dielectric polarization in solution, the molecular properties of a homologous series of poly[3-(trimethylsilyl)tricyclononene-7] samples synthesized via additive polymerization have been studied. Scaling relationships that describe how the intrinsic viscosities, diffusion coefficients, and sedimentation coefficients of macromolecules depend on their molecular masses in toluene at 298 K have been obtained. It has been shown that the additive poly[3-(trimethylsilyl)tricyclononene-7] has enhanced kinetic chain rigidity. According to hydrodynamic data, the length of the Kuhn segment for this polymer does not exceed 6.0 ± 0.6 nm, while the kinetic fragment estimated from electrooptical data is 4.3 nm. In terms of kinetic properties, the studied polymer is similar to wellknown poly[1-(trimethylsilyl)-1-propyne], with the specific morphology of its highly permeable films being determined by the large-scale mechanism of chain orientation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Polymer Membranes for Gas and Vapor Separation: Chemistry and Materials Science, Ed. by B. D. Freeman and I. Pinnau (ACS Symp. Ser., New York, 1999).

  2. Materials Science of Membranes for Gas and Vapor Separation, Ed. by Yu. Yampolskii, I. Pinnau, and B. D. Freeman (Wiley, Chichester, 2006).

  3. K. Nagai, T. Masuda, T. Nakagawa, B. D. Freeman, and I. Pinnau, Prog. Polym. Sci. 26, 721 (2001).

    Article  CAS  Google Scholar 

  4. E. Finkelshtein, K. Makovetskii, M. Gringolts, Yu. Rogan, T. Golenko, L. Starannikova, Yu. Yampolskii, V. Shantarovich, and T. Suzuki, Macromolecules 39, 7022 (2006).

    Article  CAS  Google Scholar 

  5. L. Starannikova, M. Pilipenko, N. Belov, Yu. Yampolskii, M. Gringolts, and E. Finkelshtein, J. Membr. Sci. 323, 134 (2008).

    Article  CAS  Google Scholar 

  6. M. Gringolts, M. Bermeshev, Yu. Yampolskii, L. Starannikova, V. Shantarovich, and E. Finkelshtein, Macromolecules 43, 7165 (2010).

    Article  CAS  Google Scholar 

  7. E. Sh. Finkel’shtein, K. L. Makovetskii, M. L. Gringol’ts, Yu. V. Rogan, T. G. Golenko, Yu. P. Yampol’skii, and L. E. Starannikova, Dokl. Phys. Chem. 407 (2), 88 (2006).

    Article  Google Scholar 

  8. N. P. Yevlampieva, M. L. Gringo’lts, I. I. Zaitseva, and E. I. Ryumtsev, Polym. Sci., Ser. C 52 (1), 83 (2010).

    Article  Google Scholar 

  9. P. P. Chapala, M. V. Bermeshev, L. E. Starannikova, V. P. Shantarovich, N. N. Gavrilova, V. G. Avakyan, M. P. Filatova, Yu. P. Yampolskii, and E. Sh. Finkelshtein, J. Membr. Sci. 474, 83 (2015).

    Article  CAS  Google Scholar 

  10. M. L. Gringol’ts, M. V. Bermeshev, A. V. Syromolotov, L. E. Starannikova, M. P. Filatova, K. L. Makovetskii, and E. Sh. Finkel’shtein, Pet. Chem. 50 (5), 352 (2010).

    Article  Google Scholar 

  11. V. N. Tsvetkov, Rigid-Chain Polymers (Nauka, Leningrad, 1986) [in Russian].

    Google Scholar 

  12. P. P. Nefedov and P. N. Lavrenko, Transport Methods in Analytical Chemistry of Polymers (Khimiya, Leningrad, 1979) [in Russian].

    Google Scholar 

  13. V. P. Lavrenko, A. S. Gubarev, P. N. Lavrenko, O. V. Okatova, G. M. Pavlov, and E. F. Panarin, Ind. Lab., Diagn. Mater. 79 (7–1), 33 (2013).

    Google Scholar 

  14. P. Schuck, Biophys. J. 78 (3), 1606 (2000).

    Article  CAS  Google Scholar 

  15. Sh. V. Nad’, Dielectrometry (Nauka, Moscow, 1976) [in Russian].

    Google Scholar 

  16. J. L. Halary, F. Laupretre, and L. Monnerie, Polymer Materials: Macroscopic Properties and Molecular Interpretations (Wiley, London; New York, 2011).

    Google Scholar 

  17. A. V. Finkel’shtein and O. B. Ptitsin, Protein Physics (Knizhnyi dom “Universitet”, Moscow, 2002) [in Russian].

    Google Scholar 

  18. G. M. Pavlov, E. V. Korneeva, S. A. Nepogod’ev, K. Jumel, and S. E. Harding, Polym. Sci., Ser. A 40 (12), 1282 (1998).

    Google Scholar 

  19. E. B. Tarabukina, A. A. Shpyrkov, E. V. Tarasova, A. I. Amirova, A. P. Filippov, and N. A. Sheremet’eva, Polym. Sci., Ser. A 51 (2), 150 (2009).

    Article  Google Scholar 

  20. Polymer Handbook, Ed. by J. Brandrup, E. H. Immergut, and E. A. Grulke (Wiley, New York, 1999).

  21. N. P. Yevlampieva, I. I. Zaitseva, M. L. Gringolts, P. P. Khlyabich, Yu. V. Rogan, and E. I. Ryumtsev, Polym. Sci., Ser. A 50 (10), 1082 (2008).

    Article  Google Scholar 

  22. V. N. Tsvetkov, V. E. Eskin, and S. Ya. Frenkel’, Structure of Macromolecules in Solution (Nauka, Moscow, 1964) [in Russian].

    Google Scholar 

  23. G. Gray, V. Bloomfield, and J. Hearst, J. Chem. Phys. 46 (4), 1493 (1967).

    Article  CAS  Google Scholar 

  24. M. L. Caffery, P. A. Dobosh, and D. M. Richardson, Laboratory Exercises Using Hyperchem (Hypercube Inc., Dainesville, USA, 1998).

    Google Scholar 

  25. H. Yamakawa and M. Fudjii, Macromolecules 6 (3), 407 (1973).

    Article  CAS  Google Scholar 

  26. BIOVIA Materials Studio. http://accelryscom/ products/materials-studio/

  27. N. P. Evlampieva, A. V. Yakimanskii, G. M. Pavlov, I. I. Zaitseva, and E. I. Ryumtsev, Russ. J. Appl. Chem. 75 (10), 1665 (2002).

    Article  CAS  Google Scholar 

  28. N. P. Evlampieva, G. M. Pavlov, I. I. Zaitseva, M. V. Chirkova, E. G. Litvinova, V. S. Khotimskii, and E. I. Ryumtsev, Russ. J. Gen. Chem. 73 (3), 344 (2003).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. P. Yevlampieva.

Additional information

Original Russian Text © N.P. Yevlampieva, M.V. Bermeshev, A.S. Gubarev, P.P. Chapala, M.A. Antipov, 2016, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2016, Vol. 58, No. 3, pp. 233–245.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yevlampieva, N.P., Bermeshev, M.V., Gubarev, A.S. et al. Additive poly[3-(trimethylsilyl)tricyclononene-7]: Molecular properties and chain rigidity. Polym. Sci. Ser. A 58, 324–335 (2016). https://doi.org/10.1134/S0965545X1603007X

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965545X1603007X

Navigation