Abstract
With the use of the methods of hydrodynamics, the Kerr electrooptical effect, and dielectric polarization in solution, the molecular properties of a homologous series of poly[3-(trimethylsilyl)tricyclononene-7] samples synthesized via additive polymerization have been studied. Scaling relationships that describe how the intrinsic viscosities, diffusion coefficients, and sedimentation coefficients of macromolecules depend on their molecular masses in toluene at 298 K have been obtained. It has been shown that the additive poly[3-(trimethylsilyl)tricyclononene-7] has enhanced kinetic chain rigidity. According to hydrodynamic data, the length of the Kuhn segment for this polymer does not exceed 6.0 ± 0.6 nm, while the kinetic fragment estimated from electrooptical data is 4.3 nm. In terms of kinetic properties, the studied polymer is similar to wellknown poly[1-(trimethylsilyl)-1-propyne], with the specific morphology of its highly permeable films being determined by the large-scale mechanism of chain orientation.
Similar content being viewed by others
References
Polymer Membranes for Gas and Vapor Separation: Chemistry and Materials Science, Ed. by B. D. Freeman and I. Pinnau (ACS Symp. Ser., New York, 1999).
Materials Science of Membranes for Gas and Vapor Separation, Ed. by Yu. Yampolskii, I. Pinnau, and B. D. Freeman (Wiley, Chichester, 2006).
K. Nagai, T. Masuda, T. Nakagawa, B. D. Freeman, and I. Pinnau, Prog. Polym. Sci. 26, 721 (2001).
E. Finkelshtein, K. Makovetskii, M. Gringolts, Yu. Rogan, T. Golenko, L. Starannikova, Yu. Yampolskii, V. Shantarovich, and T. Suzuki, Macromolecules 39, 7022 (2006).
L. Starannikova, M. Pilipenko, N. Belov, Yu. Yampolskii, M. Gringolts, and E. Finkelshtein, J. Membr. Sci. 323, 134 (2008).
M. Gringolts, M. Bermeshev, Yu. Yampolskii, L. Starannikova, V. Shantarovich, and E. Finkelshtein, Macromolecules 43, 7165 (2010).
E. Sh. Finkel’shtein, K. L. Makovetskii, M. L. Gringol’ts, Yu. V. Rogan, T. G. Golenko, Yu. P. Yampol’skii, and L. E. Starannikova, Dokl. Phys. Chem. 407 (2), 88 (2006).
N. P. Yevlampieva, M. L. Gringo’lts, I. I. Zaitseva, and E. I. Ryumtsev, Polym. Sci., Ser. C 52 (1), 83 (2010).
P. P. Chapala, M. V. Bermeshev, L. E. Starannikova, V. P. Shantarovich, N. N. Gavrilova, V. G. Avakyan, M. P. Filatova, Yu. P. Yampolskii, and E. Sh. Finkelshtein, J. Membr. Sci. 474, 83 (2015).
M. L. Gringol’ts, M. V. Bermeshev, A. V. Syromolotov, L. E. Starannikova, M. P. Filatova, K. L. Makovetskii, and E. Sh. Finkel’shtein, Pet. Chem. 50 (5), 352 (2010).
V. N. Tsvetkov, Rigid-Chain Polymers (Nauka, Leningrad, 1986) [in Russian].
P. P. Nefedov and P. N. Lavrenko, Transport Methods in Analytical Chemistry of Polymers (Khimiya, Leningrad, 1979) [in Russian].
V. P. Lavrenko, A. S. Gubarev, P. N. Lavrenko, O. V. Okatova, G. M. Pavlov, and E. F. Panarin, Ind. Lab., Diagn. Mater. 79 (7–1), 33 (2013).
P. Schuck, Biophys. J. 78 (3), 1606 (2000).
Sh. V. Nad’, Dielectrometry (Nauka, Moscow, 1976) [in Russian].
J. L. Halary, F. Laupretre, and L. Monnerie, Polymer Materials: Macroscopic Properties and Molecular Interpretations (Wiley, London; New York, 2011).
A. V. Finkel’shtein and O. B. Ptitsin, Protein Physics (Knizhnyi dom “Universitet”, Moscow, 2002) [in Russian].
G. M. Pavlov, E. V. Korneeva, S. A. Nepogod’ev, K. Jumel, and S. E. Harding, Polym. Sci., Ser. A 40 (12), 1282 (1998).
E. B. Tarabukina, A. A. Shpyrkov, E. V. Tarasova, A. I. Amirova, A. P. Filippov, and N. A. Sheremet’eva, Polym. Sci., Ser. A 51 (2), 150 (2009).
Polymer Handbook, Ed. by J. Brandrup, E. H. Immergut, and E. A. Grulke (Wiley, New York, 1999).
N. P. Yevlampieva, I. I. Zaitseva, M. L. Gringolts, P. P. Khlyabich, Yu. V. Rogan, and E. I. Ryumtsev, Polym. Sci., Ser. A 50 (10), 1082 (2008).
V. N. Tsvetkov, V. E. Eskin, and S. Ya. Frenkel’, Structure of Macromolecules in Solution (Nauka, Moscow, 1964) [in Russian].
G. Gray, V. Bloomfield, and J. Hearst, J. Chem. Phys. 46 (4), 1493 (1967).
M. L. Caffery, P. A. Dobosh, and D. M. Richardson, Laboratory Exercises Using Hyperchem (Hypercube Inc., Dainesville, USA, 1998).
H. Yamakawa and M. Fudjii, Macromolecules 6 (3), 407 (1973).
BIOVIA Materials Studio. http://accelryscom/ products/materials-studio/
N. P. Evlampieva, A. V. Yakimanskii, G. M. Pavlov, I. I. Zaitseva, and E. I. Ryumtsev, Russ. J. Appl. Chem. 75 (10), 1665 (2002).
N. P. Evlampieva, G. M. Pavlov, I. I. Zaitseva, M. V. Chirkova, E. G. Litvinova, V. S. Khotimskii, and E. I. Ryumtsev, Russ. J. Gen. Chem. 73 (3), 344 (2003).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.P. Yevlampieva, M.V. Bermeshev, A.S. Gubarev, P.P. Chapala, M.A. Antipov, 2016, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2016, Vol. 58, No. 3, pp. 233–245.
Rights and permissions
About this article
Cite this article
Yevlampieva, N.P., Bermeshev, M.V., Gubarev, A.S. et al. Additive poly[3-(trimethylsilyl)tricyclononene-7]: Molecular properties and chain rigidity. Polym. Sci. Ser. A 58, 324–335 (2016). https://doi.org/10.1134/S0965545X1603007X
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0965545X1603007X