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Conversion of triglycerides to fuel hydrocarbons over a Pt–Pd–Al–HMS catalyst

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Abstract

The hydroconversion of rapeseed oil fatty acid triglycerides (TGs) over a mesoporous platinum–palladium aluminosilicate catalyst has been studied. It has been shown that, in a temperature range of 250–375°C at a hydrogen pressure of 60 atm, the TGs undergo complete deoxygenation and the resulting products undergo isomerization. Under optimum process conditions, the diesel fraction yield is 94%. The resulting fraction can be used as an environmentally safe fuel component.

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References

  1. G. W. Huber, S. Iborra, and A. Corma, Chem. Rev. 106, 4044 (2006).

    Article  CAS  Google Scholar 

  2. RF State Program “Energy Efficiency and Development of Energy Economics.” Approved by the RF Government, decree no. 321 of April 15, 2014

  3. N. R. Al’myasheva, D. A. Sharipova, A. V. Barkov, et al., Chem. Technol. Fuels Oils 51, 411 (2015).

    Article  Google Scholar 

  4. R. Sotelo-Boyás, F. Trejo-Zarraga, and F. de Jesús Hernández-Loyo, Hydrogenation, Ed. by I. Karamé (InTech, Rijeka, 2012), p. 187.

  5. S. Kovács, T. Kasza, A. Thernesz, et al., Chem. Ing. J. 176, 237 (2011).

    Google Scholar 

  6. J. O. Olusola, M. M. Adediran, A. K. Oluseyi, and U. L. Ajao, Energy Environ. 20/21, 1325 (2009/2010).

    Article  Google Scholar 

  7. V. A. Yakovlev, S. A. Khromova, and V. I. Bukhtiyarov, Usp. Khim. 80, 955 (2011).

    Article  Google Scholar 

  8. A. Vonortas and N. Papayannakos, WIREs Energy Environ. 3, 3 (2014).

  9. O. O. James, S. Maity, M. A. Mesubi, et al., J. Energy Res. 36, 691 (2012).

    Article  CAS  Google Scholar 

  10. T. K. Masita, Z. Hari, Y. Yaakob, et al., Renew. Sust. Energy. Rev. 22, 121 (2013).

    Article  Google Scholar 

  11. R. Fréty, M. Rocha, S. Brandao, et al., J. Braz. Chem. Soc. 22, 1206 (2011).

    Article  Google Scholar 

  12. R. Tiwari, B. S. Rana, R. Kumar, et al., Catal. Commun. 12, 559 (2011).

    Article  CAS  Google Scholar 

  13. A. V. Chistyakov, P. A. Zharova, M. V. Tsodikov, et al., Dokl. Chem. 460, 26 (2015).

    Article  CAS  Google Scholar 

  14. K. Murata, Y. Liu, M. Inaba, and I. Takahara, Energy Fuels 24, 2404 (2010).

    Article  CAS  Google Scholar 

  15. M. Herskowitz, M. V. Landau, Y. Reizner, and D. Berger, Fuel 111, 157 (2013).

    Article  CAS  Google Scholar 

  16. O. V. Kikhtyanin, A. E. Rubanov, A. B. Ayupov, and G. V. Echevsky, Fuel. 89, 3085 (2010).

    Article  CAS  Google Scholar 

  17. J. Duan, J. Han, H. Sun, et al., Catal. Commun. 17, 76 (2012).

    Article  CAS  Google Scholar 

  18. V. Meynen, P. Cool, and E. F. Vansant, Microporous Mesoporous Mater. 125, 170 (2009).

    Article  CAS  Google Scholar 

  19. G. Polczmann, J. Valyon, Á. Szegeri, et al., Top. Catal. 54, 1079 (2011).

    Article  Google Scholar 

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    A. B. Kulikov, M. I. Onishchenko, I. A. Sizova & A. L. Maksimov

  2. Faculty of Chemistry, Moscow State University, Moscow, Russia

    A. L. Maksimov, S. V. Lysenko & E. A. Karakhanov

Authors
  1. A. B. Kulikov
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  2. M. I. Onishchenko
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  3. I. A. Sizova
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  4. A. L. Maksimov
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  5. S. V. Lysenko
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  6. E. A. Karakhanov
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Corresponding author

Correspondence to A. B. Kulikov.

Additional information

Original Russian Text © A.B. Kulikov, M.I. Onishchenko, I.A. Sizova, A.L. Maksimov, S.V. Lysenko, E.A. Karakhanov, 2016, published in Neftekhimiya, 2016, Vol. 56, No. 6, pp. 617–621.

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Kulikov, A.B., Onishchenko, M.I., Sizova, I.A. et al. Conversion of triglycerides to fuel hydrocarbons over a Pt–Pd–Al–HMS catalyst. Pet. Chem. 56, 836–840 (2016). https://doi.org/10.1134/S0965544116090140

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  • DOI: https://doi.org/10.1134/S0965544116090140

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