Skip to main content
SpringerLink
Log in

Cation-exchange resins in the hydroformylation–acetalization tandem reaction

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

Cation-exchange resins in the acid form (Amberlyst-16, Wofatit KPS 200, Nafion, KU-2) have been tested as the acidic component of a catalyst system for the hydroformylation–acetalization tandem process. It has been shown that the hydroformylation of octene-1 in the presence of ethylene glycol and glycerol using a catalyst system comprising a rhodium complex, a phosphine ligand, and a solid acid leads to the formation of acetals with a yield of up to 99%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Rhodium Catalyzed Hydroformylation, Ed. by P. W. N. M. van Leeuwen and C. Claver (Kluwer Academic, New York, 2002).

  2. D. N. Gorbunov, A. V. Volkov, Yu. S. Kardasheva, et al., Pet. Chem. 55, 587 (2015).

    Article  CAS  Google Scholar 

  3. B. Bondzic, J. Mol. Catal. A.: Chem. 408, 310 (2015).

    Article  Google Scholar 

  4. D. Fogg and E. Santos, Coord. Chem. Rev. 248, 2365 (2004).

    Article  CAS  Google Scholar 

  5. P. Eilbracht, L. Barfacker, C. Buss, et al., Chem. Rev. 99, 3329 (1999).

    Article  CAS  Google Scholar 

  6. B. El Ali, J. Tijani, and M. Fettouhi, J. Mol. Catal. A: Chem. 230, 9 (2005).

    Article  Google Scholar 

  7. S. R. Khan and B. M. Bhanage, Tetrahedron Lett. 54, 5998 (2013).

    Article  CAS  Google Scholar 

  8. O. Diebolt, C. Cruzeuil, C. Miller, and D. Vogt, Adv. Synth. Catal. 354, 670 (2012).

    Article  CAS  Google Scholar 

  9. L. Neubert, E. Paetzold, C. Fischer, et al., Chem. Ing. Tech. 83, 322 (2011).

    Article  CAS  Google Scholar 

  10. A. Behr, J. Eilting, K. Irawadi, et al., Green Chem. 10, 13 (2008).

    Article  CAS  Google Scholar 

  11. E. Oprescu, D. Bombos, I. Bolocan, et al., Rev. Chim. (Bucharest) 65, 1226 (2014).

    CAS  Google Scholar 

  12. P. Sudarsanam, B. Mallesham, A. N. Prasad, et al., Fuel Process. Technol. 106, 539 (2013).

    Article  CAS  Google Scholar 

  13. C. Crotti, E. Farnetti, and N. Guidolin, Green Chem. 12, 2225 (2010).

    Article  CAS  Google Scholar 

  14. G. Vicente, J. A. Melero, G. Morales, et al., Green Chem. 12, 899 (2010).

    Article  CAS  Google Scholar 

  15. P. Silva, V. Goncalves, and C. Mota, Bioresour. Technol. 101, 6225 (2010).

    Article  CAS  Google Scholar 

  16. Yu. S. Varshavskii and T. G. Cherkasova, Zh. Neorg. Chem. 12, 1709 (1967).

    CAS  Google Scholar 

  17. N. V. Kolesnichenko, A. B. Kulikov, A. L. Maksimov, et al., Ftorn. Zamet., No. 1, 74 (2011). http://notes.fluorine1. ru.

    Google Scholar 

  18. D. N. Gorbunov, S. V. Egazar’yants, Yu. S. Kardasheva, et al., Izv. Akad. Nauk, Ser. Khim., No. 4, 943 (2015).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, Russia

    D. N. Gorbunov, Yu. S. Kardasheva, N. A. Sinikova, A. L. Maksimov & E. A. Karakhanov

  2. Graduate School of Innovative Business, Moscow State University, Moscow, Russia

    T. V. Shchukina

Authors
  1. D. N. Gorbunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. V. Shchukina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. S. Kardasheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. A. Sinikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. L. Maksimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. E. A. Karakhanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. V. Shchukina.

Additional information

Original Russian Text © D.N. Gorbunov, T.V. Shchukina, Yu.S. Kardasheva, N.A. Sinikova, A.L. Maksimov, E.A. Karakhanov, 2016, published in Neftekhimiya, 2016, Vol. 56, No. 5, pp. 483–488.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gorbunov, D.N., Shchukina, T.V., Kardasheva, Y.S. et al. Cation-exchange resins in the hydroformylation–acetalization tandem reaction. Pet. Chem. 56, 711–716 (2016). https://doi.org/10.1134/S0965544116080065

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544116080065

Keywords

Search

Navigation