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Crystal Structure and Luminescence of a Novel Binuclear Zinc(II) Complex with Di-2-Pyridylamine And 4,4′-Sulfonyldibenzoate

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Abstract

A binuclear Zn(II) complex [Zn2(SDBA)2(DPA)2.2H2O] (1) (DPA = di-2-pyridylamine, H2SDBA = 4,4′- sulfonyldibenzoic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. The single crystal X-ray diffraction analysis reveals that complex 1 is a binuclear zinc(II) complex. The binuclear molecules are further connected by three types of N–H...O, C–H...O, and O–H...O hydrogen bonds, generating a three-dimensional supramolecular structure. Meanwhile, S–O...π interactions further consolidate the three-dimensional supramolecular framework of 1. In addition, the thermal stability and luminescent properties of the title complex are briefly investigated. The luminescence measurements reveal that complex 1 exhibits fluorescent emission in the solid state at room temperature.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Yancheng Teachers University, Yancheng, Jiangsu, P. R. China

    C. Yuan, S. N. Liu & X. J. Xu

Authors
  1. C. Yuan
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  2. S. N. Liu
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  3. X. J. Xu
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Correspondence to X. J. Xu.

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Original Russian Text © 2018 C. Yuan, S. N. Liu, X. J. Xu.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 8, pp. 1986–1991, November-December, 2018.

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Yuan, C., Liu, S.N. & Xu, X.J. Crystal Structure and Luminescence of a Novel Binuclear Zinc(II) Complex with Di-2-Pyridylamine And 4,4′-Sulfonyldibenzoate. J Struct Chem 59, 1922–1927 (2018). https://doi.org/10.1134/S002247661808022X

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  • DOI: https://doi.org/10.1134/S002247661808022X

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