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Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]

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Abstract

The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by π–π interactions between the phenyl rings.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. M. Cheplakova & V. P. Fedin

  2. Novosibirsk State University, Novosibirsk, Russia

    A. M. Cheplakova, I. S. Fedoseev & V. P. Fedin

  3. National Research Center “Kurchatov Institute”, Moscow, Russia

    P. V. Dorovatovskii, V. A. Lazarenko & Ya. V. Zubavichus

  4. Peoples’ Friendship University of Russia, Moscow, Russia

    V. N. Khrustalev

Authors
  1. A. M. Cheplakova
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  2. I. S. Fedoseev
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  3. P. V. Dorovatovskii
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  4. V. A. Lazarenko
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  5. Ya. V. Zubavichus
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  6. V. N. Khrustalev
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  7. V. P. Fedin
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Corresponding author

Correspondence to V. P. Fedin.

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Original Russian Text © 2018 A. M. Cheplakova, I. S. Fedoseev, P. V. Dorovatovskii, V. A. Lazarenko, Ya. V. Zubavichus, V. N. Khrustalev, V. P. Fedin.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 2, pp. 505–508, March–April, 2018.

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Cheplakova, A.M., Fedoseev, I.S., Dorovatovskii, P.V. et al. Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]. J Struct Chem 59, 494–496 (2018). https://doi.org/10.1134/S0022476618020348

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  • DOI: https://doi.org/10.1134/S0022476618020348

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