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Structure of A Ni(Ii) Mixed Ligand Complex with 3-Imidazoline Nitroxide, ISO-Propanol, and Water

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Abstract

A mixed ligand complex of Ni(II) with 3-imidazoline nitroxide and iso-propanol [NiL2(i-C3H7OH)2] is sensitive to atmospheric moisture. It is determined that at a high humidity, the air contacts with the mother solution of the compound in iso-propanol with the precipitated [NiL2(i-C3H7OH)2] crystals leads to their spontaneous transformation into [NiL2(H2O)]·i-C3H7OH crystals whose structure is described in the present paper.

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References

  1. V. I. Ovcharenko and R. Z. Sagdeev. Russ. Chem. Rev., 1999, 68(5), 345–363.

    Article  CAS  Google Scholar 

  2. V. I. Ovcharenko, K. E. Vostrikova, G. V. Romanenko, V. N. Ikorskii, and N. V. Podberezskaya. Doklady Akademii nauk SSSR, 1989, 306(3), 660–662.

    CAS  Google Scholar 

  3. V. I. Ovcharenko, K. E. Vostrikova, A. V. Podoplelov, R. Z. Sagdeev, G. V. Romanenko, and V. N. Ikorskii. Polyhedron, 1994, 13, 2781.

    Article  CAS  Google Scholar 

  4. G. V. Romanenko, V. N. Ikorskii, S. V. Fokin, and V. I. Ovcharenko, J. Struct. Chem., 1997, 38(5), 779–791.

    Article  CAS  Google Scholar 

  5. V. N. Ikorskii, V. I. Ovcharenko, Yu. G. Shvedenkov, G. V. Romanenko, S. V. Fokin, and R. Z. Sagdeev. Inorg. Chem., 1998, 37(17), 4360.

    Article  CAS  PubMed  Google Scholar 

  6. R. Z. Sagdeev, V. K. Voronov, A. V. Podoplelov, I. A. Ushakov, A. N. Chemezov, E. Yu. Fursova, S. V. Fokin, V. A. Reznikov, and V. I. Ovcharenko. Russ. Chem. Bull., 2001, 50(11), 2078–2086.

    Article  CAS  Google Scholar 

  7. E. Yu. Fursova, Y. Shvedenkov, G. Romanenko, V. Ikorskii, and V. Ovcharenko. Polyhedron, 2001, 20, 1229.

    Article  CAS  Google Scholar 

  8. E. Yu. Fursova, V. N. Ikorskii, G. V. Romanenko, V. A. Reznikov, Yu. G. Shvedenkov, V. I. Ovcharenko. J. Struct. Chem., 2002, 43(4), 656–663.

    Article  CAS  Google Scholar 

  9. R. Morgunov, S. Gudoshnikov, Yu. Ossypian, V. Ovcharenko, R. Sagdeev, V. Skomarovskii, and Y. Tanimoto. Phys. Status Solidi A, 2005, 202(5), R47.

    Article  CAS  Google Scholar 

  10. Cambridge Structural Database. Ver. 5.38 (November. 2016, update May 2017). University of Cambridge, UK.

  11. V. I. Ovcharenko, K. E. Vostrikova, V. N. Ikorskii, G. V. Romanenko, N. V. Podberezskaya, S. V. Larionov, and R. Z. Sagdeev. Synthesis, Structure, and Magnetic Properties of Low-Temperature Ferromagnets Based on Co(II) and Ni(II) Complexes with Imidazoline Nitroxides [in Russian], Preprint, (89-2), Institute of Inorganic Chemistry, Novosibirsk, 1989.

    Google Scholar 

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Correspondence to G. V. Romanenko.

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Original Russian Text © 2018 G. V. Romanenko, E. Yu. Fursova, G. A. Letyagin, V. I. Ovcharenko.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 2, pp. 398–401, March–April, 2018.

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Romanenko, G.V., Fursova, E.Y., Letyagin, G.A. et al. Structure of A Ni(Ii) Mixed Ligand Complex with 3-Imidazoline Nitroxide, ISO-Propanol, and Water. J Struct Chem 59, 384–387 (2018). https://doi.org/10.1134/S002247661802018X

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  • DOI: https://doi.org/10.1134/S002247661802018X

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