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Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2-tert-butyltetrazol-5-yl)pyridine

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Abstract

Iron(II) dicyanamide and isothiocyanate compounds with 2-(2-tert-butyltetrazol-5-yl)pyridine (L) of the composition [FeL2(C2N3)2]•2H2O (I) and [FeL2(NCS)2]H2O (II) are synthesized and studied. The compounds are examined using powder and single crystal XRD (for I), electron (diffuse reflectance spectra) and IR spectroscopy, static magnetic susceptibility. The analysis of the dependence μeff(Т) indicates that the exchange interactions of antiferromagnetic nature appear between the iron(II) ions at temperatures below 50 K.

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Authors and Affiliations

  1. Komsomolsk-on-Amur State Technical University, Komsomolsk-on-Amur, Russia

    O. G. Shakirova

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    L. G. Lavrenova, N. V. Kuratieva & L. A. Sheludyakova

  3. Novosibirsk National Research State University, Novosibirsk, Russia

    L. G. Lavrenova, N. V. Kuratieva, A. S. Bogomyakov & L. A. Sheludyakova

  4. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. S. Bogomyakov

  5. Research Institute for Physical Chemical Problems of the Belarusian State University, Minsk, Belarus

    A. P. Mosalkova & Yu. V. Grigoriev

Authors
  1. O. G. Shakirova
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  2. L. G. Lavrenova
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  3. N. V. Kuratieva
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  4. A. S. Bogomyakov
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  5. L. A. Sheludyakova
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  6. A. P. Mosalkova
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  7. Yu. V. Grigoriev
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Corresponding author

Correspondence to L. G. Lavrenova.

Additional information

Original Russian Text © 2017 O. G. Shakirova, L. G. Lavrenova, N. V. Kuratieva, A. S. Bogomyakov, L. A. Sheludyakova, A. P. Mosalkova, Yu. V. Grigoriev.

Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 5, pp. 958–964, June–July, 2017.

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Shakirova, O.G., Lavrenova, L.G., Kuratieva, N.V. et al. Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2-tert-butyltetrazol-5-yl)pyridine. J Struct Chem 58, 919–925 (2017). https://doi.org/10.1134/S0022476617050092

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  • DOI: https://doi.org/10.1134/S0022476617050092

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