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Multi-component lanthanide hybrids based on zeolite A/L and zeolite A/L-polymers for tunable luminescence

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Abstract

Some multi-component hybrids based on zeolite L/A are prepared. Firstly, zeolite A/L is loaded with lanthanide complexes (Eu-DBM or Tb-AA (acetylacetone = AA, dibenzoylmethane = DBM)) into its channels. Secondly, 3-methacryloyloxypropyltrimethoxysilane (γ-MPS) is used to covalently graft onto the surface of functionalized zeolite A/L (Si-[ZA/L ⊃ Eu-DBM(Tb-AA)]). Thirdly, lanthanide ions (Eu3+/Tb3+) are coordinated to the functionalized zeolite A/L and ligands (phen(1,10-phenanthroline) or bipy (2,2′-bipyridyl)) are introduced by a ship-in-bottle method. The inside-outside double modifications of ZA/L with lanthanide complexes afford the final hybrids and these are characterized by means of XRD, FT-IR, UV-vis DRS, SEM and luminescence spectroscopy, some of which display white or near-white light emission. Furthermore, selected above-mentioned hybrids are incorporated into PEMA/PMMA (poly ethyl methylacryate/poly methyl methacrylate) hosts to prepare luminescent polymer films. These results provide abundant data that these hybrid materials can be expected to have potential application in various practical fields.

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Authors and Affiliations

  1. Department of Chemistry, Tongji University, Shanghai, 200092, China

    Lei Chen & Bing Yan

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  1. Lei Chen
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  2. Bing Yan
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Correspondence to Bing Yan.

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Electronic supplementary information (ESI) available. See DOI: 10.1039/c4pp00364k

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Chen, L., Yan, B. Multi-component lanthanide hybrids based on zeolite A/L and zeolite A/L-polymers for tunable luminescence. Photochem Photobiol Sci 14, 358–365 (2015). https://doi.org/10.1039/c4pp00364k

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