Abstract
In order to conquer the short-channel effects that limit conventional ultra-scale semiconductor devices, two-dimensional materials, as an option of ultimate thin channels, receive wide attention. Graphene, in particular, bears great expectations because of its supreme carrier mobility and saturation velocity. However, its main disadvantage, the lack of bandgap, has not been satisfactorily solved. As a result, maximum oscillation frequency (fmax) which indicates transistors’ power amplification ability has been disappointing. Here, we present submicron field-effect transistors with specially designed low-resistance gate and excellent source/drain contact, and therefore significantly improved fmax. The fabrication was assisted by the advanced 8-inch CMOS back-end-of-line technology. A 200-nm-gate-length GFET achieves fT/fmax = 35.4/50 GHz. All GFET samples with gate lengths ranging from 200 nm to 400 nm possess fmax 31–41% higher than fT, closely resembling Si n-channel MOSFETs at comparable technology nodes. These results re-strengthen the promise of graphene field-effect transistors in next generation semiconductor electronics.
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Introduction
In order to conquer short channel effects, two-dimensional materials receive wide attention nowadays1. Graphene, in particular, bears great expectations because of its supreme carrier transport properties2. However, even though the cutoff frequency (fT) of graphene field-effect transistors (GFETs) exceed Si transistors3,4, the maximum oscillation frequency (fmax), as the most relevant metric to circuit performance, seriously lags behind. Promising circuit applications are limited in passive circuits5,6,7,8,9. Typical fmax values are one order of magnitude lower than fT3,10,11,12,13. For instance, the 46-nm-gate-length GFET in Cheng et al.’s work delivered fT/fmax of 212/8 GHz3. Wu et al. achieved fT/fmax = 300/30 GHz and fT/fmax = 120/44 GHz for GFETs with channel lengths of 40 nm and 120 nm, respectively10. The absence of bandgap is the primary drawback that limits fmax1. Introducing a bandgap by using bilayer or multilayer graphene is a straightforward idea. However, it suffers from synthesis difficulties14,15. On the other hand, reduction of parasitic effects is a practical solution16,17,18. Parasitic effects such as overlapping capacitance, contact resistance and gate resistance influence transistors’ RF performance. Several groups have already increased GFETs’ fmax by lowering the gate resistance16,17,18,19. Heer et al. achieved fmax up to 70 GHz for a 100 nm gate device, using mushroom T-shape top gates to lower the gate resistance16. Han et al. employed T-shape buried gates. Their work delivered fmax 25–43% higher than fT, with the highest fmax of 20 GHz17.
In this work, the modern CMOS back-end-of-line (BEOL) technology has been employed to fabricate deep-submicron GFETs. GFETs with gate lengths ranging from 100 nm to 400 nm have been fabricated on 200 mm wafers by recently reported passive-first-active-last inverted process8,9,20. In particular, buried gates with depth-to-width ratio up to six folds were achieved for the purpose of lowering the gate resistance. These GFETs achieve RF metrics (i.e. fmax and fT) close to Si n-channel MOSFETs at comparable technology nodes. In particular, the 200-nm-gate-length GFET generates fmax/fT = 50/35.4 GHz. The fmax/fT ratio is also among the highest in literature.
Results and Disscussion
Fabrication
Schematic of the fabrication process flow is demonstrated in Fig. 1(a–h). 200 mm Si wafers with high resistivity (>1000 Ω cm) were used for the purpose of reducing substrate losses. 5 μm thick SiO2 layer was first deposited by PECVD method as the insulator layer. Metal structures were formed by Damascene process. For the purpose of increasing the depth-to-width ratio of the buried gates, 100 nm thick α-Si was deposited as the hard mark sacrifice layer. Definition of the deep-submicron gates was enabled by electron-beam lithography (EBL). Reactive ion etching (RIE) was used to realize the trenches. Owing to the large selection ratio between SiO2 and α-Si, the depth-to-width ratio was significant increased up to six, as illustrated in Fig. 1(b,c). After removal of α-Si, source/drain bottom contacts, interconnects and probing pads were defined by stepper lithography and etching. Bottom metals serve as an addition to top metals to ensure good contacts21. Then, tungsten was deposited by CVD method to fill in the trenches, followed by chemical-mechanical-planarization (CMP). Besides removing extra tungsten, it also guarantees the flatness of the wafer, necessary for the successfulness of the following graphene transfer process. HfO2 with equivalent oxide thickness (EOT) of 2 nm was deposited by atomic layer deposition (ALD) as the gate dielectric. The relative dielectric constant was about 20. The dielectric was defined by stepper lithography and removed by inductively coupled plasma (ICP) etching with BCl3 source.
Figure 2(a) shows a photograph of a fabricated 200-mm wafer. Stand-alone submicron gate trenches with widths of 100 nm, 200 nm and 500 nm are displayed in Fig. 2(b). α-Si hard mask about 100 nm thick was indicated. Cross-section view of a 100-nm-gate-length GFET structure is demonstrated in the inset of Fig. 2(c), with the gate trench 100 nm long and 600 nm deep. Graphene in this work was formed by CVD method on Pt foils as previously reported22,23. “Bubbling” method was used to transfer graphene to the patterned wafer on a die-by-die basis, limited by the maximum size of Pt foil22,23. Graphene channels were patterned by contact mode contact lithography and oxygen plasma etching. All GFETs employed two-finger layout with each finger 6 μm wide. The source/drain contacts were defined by EBL, and went through 5 min ultraviolet-ozone (UVO) treatment before sputtering of 40 nm Pt and the following lift-off process. The ungated source/drain-gate spacer was about 200 nm. Stand-alone Hall device with size 36 μm × 8 μm resulted in carrier mobility about 3400 cm2v−1-s−1. Higher mobility is expected in fabricated GFETs, as smaller areas are less prone to defects. The probing pads feature 100 μm pitch in ground-signal-ground (GSG) layout. The GFETs have not gone through the passivation step for convenience. Various dielectrics passivation layers, such as Si3N424, BN25, Al2O326, etc., can be considered to further increase the stability and reliability of the graphene devices.
Stand-alone transfer length measurement (TLM) patterns were fabricated along with the GFETs to measure the contact resistance, RC. It indicates RC of 550 Ω um as well as the sheet resistance of 880 Ω/sqr, as shown in Fig. 2(d) with the inset showing the SEM image of the TLM pattern. Typical metal contact resistance for CVD graphene ranges from few hundreds Ω to few kΩ27,28,29,30. RC in this work is among the lowest, attributed to the high work function of Pt that induces more carriers underneath and UVO treatment that enhances the binding between metal and graphene30,31. Other metal deposition recipes may also be considered as sputtering on graphene causes certain disorders. Figure 2(e) shows the transfer characteristics of the 100-nm-gate-length GFET with on-off ratio of roughly 2 folds. Figure 2(f) displays the output characteristics. It is worth noting that the two-point resistance R2pt is 1.4 kΩμm, indicating the contact resistance is less than 700 Ωμm, consistent with the stand-alone TML measurement. Top view of a fully processed 100-nm-gate-length GFET is shown in the inset of Fig. 2(f). Figure 2(f,g) present the transfer and output characteristics of a 300-nm-gate-length GFET, respectively. As expected, it demonstrates stronger gate modulation (i.e. transconductance) compared to the 100 nm counterpart. The two-point resistance R2pt also slightly increases to 1.5 kΩμm as the drain-to-source distance becomes longer. Figure 2(i,j) show the cross-section views of 200- and 300-nm-gate-length GFETs, respectively.
RF Performance and Discussion
High-frequency S-parameters of the GFETs were measured up to 40 GHz under ambient atmosphere using Agilent N8230C network analyzer. The system was calibrated with short-open-load-through (SOLT) method. Three-step de-embedding procedure was used32, which employed “open”, “through” and “short” structures to de-embed on-wafer parasitic components. (See Supporting Information) h21 and MUG of a 400-nm-gate-length GFET are displayed in Fig. 3(a,b). It delivers fT/fmax of 18.6/28.4 GHz before de-embedding, and fT/fmax of 25.5/35.5 GHz after de-embedding. As a reference, a recently reported 450-nm-gate-length GFET delivered fT/fmax of 11.5/15 GHz17. Five successive GFETs with 400 nm gate length are shown in Fig. 3(c), which indicate excellent performance uniformity. A small-signal model is built which enables the analysis on the role of each parameter. The schematic of the small-signal equivalent circuit is presented in Fig. 3(d). Different from that of a conventional transistor, rg lies in the outer equivalent position on neither of gate-source (Cgs) and gate-drain (Cgd) capacitance branches. It is because GFETs could not effectively pinch off and their behavior resembles linear-region conventional transistors. Fitting of the 400-nm-gate-length GFET with the small-signal model is demonstrated in Fig. 3(b), which delivers a close fT/fmax of 25.2/32.3 GHz. Values for each component of the small-signal model are displayed in Table 1. The raw values extracted from the measured S-parameters are shown in Supporting Information. They are relatively stable in the measurement frequency range, confirming the effectiveness of the small-signal model.
To verify rg’s role in fmax, we varied rg in a range including 5 Ω, 15 Ω, 30 Ω, 50 Ω, 100 Ω and 200 Ω, as depicted in Fig. 3(e). rg = 15 Ω, marked red, generates the closest fitting as shown in Fig. 3(b). fmax increases or decreases with lower or higher rg, respectively. fmax is inversely proportional to the square root of rg, as indicated by the dashed guideline in Fig. 3(e), which is consistent with theoretical derivation as follows. (Derivation in detail is shown in Method section).
Unmodified gate is the primary reason why ordinary GFETs usually generate fmax one to two orders of magnitude lower than fT 3,10,11,12,13. Unlike fmax, fT is independent of rg. It is worth mentioning that Rs and Rd have already been included in the transconductance term, gm, of the small-signal model. Larger contact resistance leads to smaller gm, thus fT and fmax. The influence of Rs and Rd on gm can be addressed by physics-based large-signal compact models33.
The h21 and MUG of a de-embedded 300-nm-gate-length GFET biased at Vds = 1.2 V is shown in Fig. 4(a). It achieves fT/fmax = 34.2/45 GHz. Before de-embedding, fT and fmax are 21.6 and 40 GHz, respectively (Supporting Information). The h21 and MUG of a de-embedded 200-nm-gate-length GFET biased at Vds = 1.0 V is shown in Fig. 4(b). fT/fmax equal 35.4/50 GHz. Prior to de-embedding, fT and fmax are 21.3 and 42 GHz, respectively (Supporting Information). The dash guide lines in these figures are in ideal −20 dB/dec slope for extrapolating fmax34. The fmax values of the 200-, 300- and 400-nm-gate-length GFETs outperform previous works with comparable gate lengths to the best of our knowledge. As parasite effect plays a larger role with shorter gate length, the 100-nm-gate-length GFET is retained for more careful characterization in following works. fT’s dependence on gate length is shown in Supporting Information, revealing a relationship near to 1/L. Limited discrepancy may result from source/drain contact resistances, which play an unignorable role in GFETs33.
A comparison with recently published GFETs and Si n-channel MOSFETs (NMOSs) with similar gate lengths is shown in Fig. 5. fT/fmax of the GFETs is close to that of typical NMOSs at 0.25 μm and 0.35 μm technology nodes. And the fmax/fT ratio largely exceeds previous GFET works.
In summary, the advanced CMOS BEOL process has been employed in deep-submicron GFET fabrication. Thanks to the well-designed buried gate structure and lowered contact resistance, fmax has been increased significantly higher than before, rivaling Si transistor at comparable technology nodes. Considering its 8-inch wafer standard-process fabrication, GFETs are nearer to mass-production than ever. With the inverted process flow, one can also envision that future graphene RF components could be realized on CMOS backbones.
Methods
Graphene Synthesis and Transfer
Large scale monolayer graphene films were grown on 180 μm thick Pt foils (99.9 wt % metal basis, 10 mm × 10 mm) under ambient-pressure chemical vapor deposition (APCVD) method. The temperature was 1000 °C and CH4/H2 flow rate was set as 4.5/500 sccm. After growth, Pt foils are quickly pulled out of the high temperature area. PMMA photoresist was spun on graphene/Pt foil as the scaffold. Electrochemical delamination in NaOH solution was used to peel the graphene/PMMA off and transfer to pre-patterned dies. Raman spectrum of the monolayer graphene is shown in Supporting Information, Fig. S1.
Derivation of fmax-rg relationship
The equivalent circuit of the small-signal model is shown in Fig. 6. Firstly, the input impedance, Zin, and output impedance, Zout, are calculated:
The input and output ports have to be conjugate-matched for maximum power transfer. Therefore, we have Rin = Zin and Rout = Zout. Then, MUG can be expressed as
When MUG = 1,
Additional Information
How to cite this article: Lyu, H. et al. Deep-submicron Graphene Field-Effect Transistors with State-of-Art fmax. Sci. Rep. 6, 35717; doi: 10.1038/srep35717 (2016).
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Acknowledgements
This research was supported by the National Basic Research Program (2011CBA00600, 2013CBA01604), the National Natural Science Foundation (61474072), and the National Science and Technology Major Project (2011ZX02707).
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H.L., Z.Y., H.Q. and H.W. conveiced the project. H.L., X.W., H.Q., H.W., Jinbiao L., Junfeng L. and J.N. designed the fabrication process. H.L., Q.L. and Jinbiao L., fabricated the GFET and performed the electrical measurement. H.L. and J.Z. modeled the device. H.L. wrote the manuscript.
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Lyu, H., Lu, Q., Liu, J. et al. Deep-submicron Graphene Field-Effect Transistors with State-of-Art fmax. Sci Rep 6, 35717 (2016). https://doi.org/10.1038/srep35717
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DOI: https://doi.org/10.1038/srep35717
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