Abstract
It is a useful way to stabilize the elements of heavy metal in the glass-ceramics with the form of ions due to the environmental pollution of heavy metal, such as Cr. The glass-ceramics of excellent combination properties were prepared, and the effect of stabilizing Cr-containing stainless steel slag with different concentrations of nitric acid leaching test were investigated. It was found that the major crystalline phase was diopside or anorthite with or without the amount stainless steel slag. Moreover, the continuous refinement of grains exhibited with the increase of amount of stainless steel slag. The results indicated that the excellent physical and mechanical properties, including density (2.9 g/cm3), hardness (729.27HV0.3), bending strength (222.9 MPa), and the solid solution of Cr in excess of 0.00057% for the glass-ceramics were related to the change of microstructure and phase structure. There showed the potential for reusing and detoxifying stainless steel slag.
Similar content being viewed by others
Introduction
The accumulation of solid waste occupied a large amount of land and made the environmental pollution1. Importantly, the natural resources such as rivers, soil and groundwater were also polluted by the heavy metal elements2,3,4,5,6,7,8,9. Per ton of stainless steel slag, as a kind of solid waste produced during the production of stainless steel, were produced by three tons of stainless steel approximately10 to which the human body can be harmful through contaminated soil groundwater, especially the heavy metal element Cr11,12. The stainless steel slag is considered as high toxic waste because of the carcinogenic, mutagenic and toxic of the element Cr through dermal and oral exposure13. However, the byproduct stainless steel slag was continuously produced and accumulated due to the real demand of society for stainless steel. Therefore, it is urgent to apply a new method of focusing on the preparation of advanced materials using stainless steel slag as raw material and, at this time, the fact that reducing the environmental pollution by stabilizing the heavy metal element, such as Cr, in the crystal is a promising method. The glass-ceramics, as a new material, is composed of a crystalline phase and an amorphous phase so that it has good physical and chemical properties such as mechanics14, thermals15, optics16, electricity17, etc.
As so, the detoxifying treatment in it has been studied by many researchers performed preliminary research on reusing and recycling stainless steel slag. The working performance and mechanical properties of the cement were studied using it and the requirements of use application were met18. In addition, the non-toxic treatment of chromium in stainless steel slag was another important way to reduce the environmental pollution. The wet reduction method was used to reduce the content of exchangeable and carbonic acid bound chromium that was easily leached from the stainless steel slag. The remaining chromium was difficult to be leached19. Unfortunately, the pollution to the environment was caused by a large amount of accumulated pollutants again using this method due to the incomplete detoxification. Nevertheless, most of the heavy metal elements, Cr, Fe, etc. can be recovered as alloys with the high-temperature reduction method to detoxify the stainless steel slag by adding the appropriate amount of reducing agent20,21. And it was found that the method of solidification converted the toxic Cr (VI) into a stable Cr (III) and stabilized in the crystal lattice so as to the stainless steel slag was detoxified. As a result, the product can be reused as a building material with excellent performance22. Ma et al. sintered the stainless steel slag fully sintering, and Cr emitted very little in the emissions during this process within environmental limits23. Furthermore, the influence of the presence of chromium containing the different chemical valence state in the crystalline phase were leached by the ratio of crystallized glass on the solidification of chromium using Cr leaching ratio in glass-ceramics8,11 and, meanwhile, this is better way for studying the solidification mechanism of high performance glass-ceramics for chromium.
In view of the above facts, recycling stainless steel slag to obtain glass-ceramics was a kind of product with excellent performance being not harmful to the environment and human body. Thus, chromium-containing stainless steel slag to prepare glass-ceramics of CMAS system with high performance and, at the same time, curing Cr in the crystal structure were studied by the thermal behaviors, crystalline phase, grain shape and size. And furthermore, it is also expected that the relationship between the physical and mechanical properties of glass-ceramics and their microstructure feature and phase structure can be revealed.
Methods
Materials
Glass-ceramics were prepared from MgO, SiO2, CaO, Na2CO3, Na2B4O7, Al2O3, and Fe2O3 as the main raw material by melting. Afterwards, the mixed specimens with the increased of amount of the stainless steel slag containing 0 wt.%, 5 wt.%, 10 wt.%, 15 wt.%, 20 wt.% were prepared, respectively. The compositions of these specimens with increasing content of Cr2O3 in the stainless steel slag were shown in Table 1. In order to complete the nucleation and crystallization treatment, the five homogeneously mixed specimens were completely melted at a temperature of 1500 °C for 2 hours and then the melts were cast into the preheated stainless steel molds and, finally, were annealed at 600 °C for 3 h. After this, the glass specimens of annealing exhibited the glass-ceramics.
Testing method
The thermal behaviors of the glass specimens were examined by differential scanning calorimetry (DSC, STA449C, NETZSCH), using an empty Al2O3 crucible as a reference material and heating at 10 °C/min from room temperature to 1000 °C. The crystalline phase were determined by X-ray diffraction(XRD, X’pert Pro Powder, PANalytical) using Cu K \({\rm{\alpha }}\) radiation with a wavelength 0.1541 nm, in the 2-theta/° range from 10 to 80 degree, and at a step size of of 0.02° and a scan speed of 0.3 s/min of scanning rate at room temperature, which was operated at 40 KV and 40 mA. The XRD data was subjected to fit profile processing using X’Pert HighScore Plus (version: 3.0), and then the degree of crystallinity of the specimens was obtained by “Constant Background” value. The microstructure was obtained by filed emission scanning electron microscope(FESEM, SUPRA 55 FESEM, Carl Zeiss Jena) which is equipped with an Oxford EDS and HKL EBSD analysis system. The specimens were polished, corroded, and then sprayed with gold. The Raman spectrum system was constructed independently by our laboratory equipped with Andor Sham-rock SR-500i-C-R type Raman spectrometer and Andor iDus series water-air cooled CCD (Charge Coupled Device) detector product by UK ANDOR Company, and a 1200 grove/mm grating with a wavelength resolution about 0.05 nm. In the experiment, 50 times long focus objective lens (parameter: 50×/0.35) was used for focusing on the specimens, adjusting the specimen height to complete the focal point, focusing image collected by SunTime130E CMOS color digital camera, excited at the 355 nm line of semiconductor laser at which ~25 mW was output power each specimen. And then the Raman spectrometer was calibrated with a single crystal silicon prototype. All the signal data of each specimen was gathered at room temperature with 20 seconds exposure time, 5 times accumulation number, 20 s accumulation cycle time, and the scanning range was from 0 to 4000 cm−1. The densities were measured by Archimedes method. The three-point bending strength of rectified parallelepiped bars (3 mm × 4 mm × 40 mm) of glass-ceramics was tested by the CSS-88000 electronic universal testing machine. Each value was the average of five groups of data originated from the same specimens. Indentation experiments were conducted using a Vickers hardness tester (HV-SOA).
Leaching Way
According to the standard “HJ/T 299–2007”, the long-term toxicity leaching test of the prepared glass-ceramics was performed using a mixed solution of sulfuric acid and nitric acid with a pH = 3.20 ± 0.05. The size of specimens was less than 75 mm and the liquid-solid ratio was 10:1. The content of chromium in the leach solution was distinguished by ICP-MS and compared to the standard specified in standard “GB 5085.3-2007” to evaluate the immobilization effect of glass-ceramics on chromium in the stainless steel slag.
In order to quantify the solidification effect of the prepared glass-ceramics on Cr element, a long-time leaching test was performed on the stainless steel slag and the glass-ceramics using a concentration of 5% nitric acid, respectively.
Results and Discussion
Differential thermal analysis
DSC curves depict the thermal behaviors of five specimens, including transition temperature (Tg) and peak temperature (Tp), as shown in Fig. 1. With the addition of stainless steel slag, the glass Tg increases more slowly and around 670 °C while Tp decreases from 959 °C to 874 °C. At present, the conventional method by two-stage heat treatment was employed. The heat treatment with a low temperature that gives a high nucleation rate (around Tn) was the first stage, and there exhibited a high density of nuclei throughout the interior of the glass. The growth of the nuclei at a reasonable rate shown in the second stage showed at a higher temperature around temperature Tg24. The nucleation temperature was selected as 720 °C on the basis of Tn above the transition temperature of 50 °C25. According to the obvious exothermic peak, the crystallization temperatures of S1 to S5 were selected at 950 °C, 950 °C, 930 °C, 900 °C and 870 °C, and then held them for 2 hours, respectively.
Phase analysis
The XRD patterns of crystalline phase are shown in Fig. 2. It is found that the major crystalline phase of glass-ceramics of CMAS system was transformed from anorthite to diopside. The major crystalline phase of specimen 1 is anorthite, (Ca, Na)(Si, Al)4O8 (\({\rm{P}}\bar{1}\)), while diopside, (Ca0.78Na0.18Mg0.04)(Mg0.79Fe0.05Cr0.09Al0.07)(Si1.97Al0.03O6) (C2/c), is the major crystalline phase in the other specimens with the increase of stainless steel slag containing chromium.
It was evident that the phase compositions of all the specimens were very similar except for the specimen 1 due to the absence of the element Cr. However, the crystalline phases produced by them were quite different. The major phase formed was anorthite without the addition of Cr and, to the contrary, was diopside with the amount of Cr2O3. The result indicated that Cr2O3 was a very good nucleating agent in the nucleation and growth of glass-ceramics owing to a strong electric field of Cr3+, which made the disordered phase transitions, namely glass structure, to the ordered phase transitions due to the phase separation, reduced the potential energy barrier for crystal growth. It is accordance with the previous research26,27,28. As for the Specimen 1, there was no nucleation agent if there was no the element Cr. Thus, the anorthite, as the major phase, appeared, including the elements Ca, Mg, etc., and the diopside disappeared due to the inhomogeneity of the matrix and air components during the process of growth.
Micrographs analysis
Figure 3 exhibits the morphology of glass-ceramics with the increase of stainless steel slag containing the amount of Cr2O3. The degree of crystallization of the specimens increased with the increasing stainless steel slag. The major phase of the S1 was anorthite and, moreover, the other four groups were diopside which is accordance with the results of XRD.
In the case of the S1, it contained a large amount of Ca, Al, Si etc. except for the element Cr. It was found that the crystalline grains grew from the surface to the inward and the crystallization occurred in the surface due to the inward proceeded by the small extent of crystalline phase, as shown in Fig. 3a. The formation of the anorthite in the phase boundary, caused by the heterogeneous nucleation, was the primary reason. Moreover, It should be noted that there was a clear boundary between the glass and the anorthite. For the other four groups of specimens, with a small amount of stainless steel slag added, the low content of Cr was enriched by its electric field so that it was not uniformly distributed throughout the S2, resulting in local crystallization, as shown in Fig. 3b. The particle size, near the glass phase, was greater than it in the interior owing to the less nucleating agents for which the crystalline grains to fully grow along the main zone axis and the secondary zone axis to form large dendritic grains were favorable. With the addition of stainless steel slag being up to 9.21 wt.%, the crystalline phase of S3 possessed the large particle size with the microstructure of dendrite, as shown in Fig. 3c, because of atomic migration and dendrite growth favored by the lower viscosity. Afterwards, there were many fine particles to replace the large grains with the content of stainless steel slag from 13.68 wt.% to 18.06 wt.% and, finally, the fine crystalline was evenly distributed, as shown in Fig. 3d,e. There existed limited growth on the crystalline due to the insufficient growth space so as to the fine grains formed.
Figure 4 shows the grain-orientated mapping and pole figure (PF) of electron backscattered diffraction (EBSD). As shown in Fig. 3f, the pink phase with spinel structure, as the minor phase, distinguished by EBSD, in the glass-ceramics specimens to which the stainless steel slag was added. The presence of the spinel structure resulted to the change of grain-orientated mapping, as shown in Fig. 4. There exhibited the crystalline phase and glass phase in the colored and black portions, respectively. And it can be seen that the phases, as the major phase, with different colors grown on the spinel phase, as a nucleation agent, as shown in Fig. 4a,b. And it can be proved by the orientation relationship by PF mapping, as shown in Fig. 4c,d, analyzing it by which the close-packed plane {200} of diopside and the close-packed plane {111} of spinel obtained. Besides, the different orientation relationship with PF mapping can be expressed with the different points overlapped, for instance, diopside one and spinel one as red circles were in the same position, diopside two and spinel two as green circles, and so on. So it can be considered that the presence of the spinel structure can induce the growth of the diopside structure. It is consistent with the previous results29.
The process of converting the glass into the glass-ceramics with the additive stainless steel slag, divided into three stages, occurred during the heat treatment, as shown in Fig. 5. Firstly, a large quantity of crystalline with spinel structure formed in the glass specimens in the stage of nucleation, served as a heterogeneous nucleation zones for the crystallization. Furthermore, as the temperature increased, a great deal of small crystalline with diopside structure grew on the surface of the spinel. In the third stage, while the temperature reached above crystallization temperature and held for the period of time, the small crystalline with diopside structure grew up, and the entire interior of the specimens were filled with the crystalline phase eventually.
Raman Spectroscopy
Figure 6 shows the results of Raman spectra of the glass-ceramics. In the specimen, S1, the strong bands intensity exhibited at 330 cm−1, 502 cm−1, 632 cm−1, 760 cm−1, 968 cm−1 and 1041 cm−1. However, there were a number of bands at 338 cm−1, 390 cm−1, 527 cm−1, 660 cm−1, 766 cm−1, 1000 cm−1, 1331 cm−1, and 1580 cm−1 among S2, S3, S4 and S5 that were close to the Raman spectral band, as shown in the assignment table of pyroxene30. It can be seen that the phase of S1 is not the same as that of the other four groups of specimens.
There existed the band at 338 cm−1 to be related to the bending vibration of alkali metals and oxygen (M-O) and the band at 390 cm−1 to be the deformation vibration of alkali metals and oxygen (M-O). The band at 527 cm−1 and 660 cm−1 was mostly associated with the bending vibration and symmetric bending vibrations of O-Si-O. The symmetrical stretching vibration of Si-O corresponded to the band at 1000 cm−1. In the amorphous phase, the stretching vibration of four non-bridge oxygen bonds was controlled by the peak with a wave number of 766 cm−1. The band 1331 cm−1 and 1581 cm−1 were assigned to the [BO3] group31, deteriorating the performance of the glass. The fact that governed by the content of the [BO3] group decreased with the increased content of chromium. This is of great significance for the excellent performance of glass-ceramics.
Physical and mechanical properties of glass-ceramics
The density and degree of crystallization of the specimens increased with the addition of stainless steel slag apart from the bending strength, increasing primarily and then decreasing, as shown in Table 2. The low density, determined by the low degree of crystallization that was affected by the closeness of the structure accumulation32, were formatted in the S1 and S2, resulting in the glass phase mostly. As shown in Fig. 3a–e, the crystalline size of S5 was smaller and the packing was denser than the others so as to the density of S5 was the largest. Despite there were the microstructure of dendrite in the S3 and S4, as shown in Fig. 3c,d, the better properties were shown in S4 with small particle size than that of S3 possessed the large particle size. Besides, the degree of crystallization was the other important factor deciding hardness and bending strength. As shown in Table 2, the bending strength of S4 reached 222.9 Mpa. Evidently, it was larger than the others. Correspondingly, the high degree of the crystallization reached 7.30% and the fine branches of dendrite, deformed by external forces, were interlocked. Meanwhile, there was remaining glass phase, wrecked continuity of the crystalline phase, to be observed in the glass-ceramics, such as S1 and S2, indicating that the decreasing properties of the glass-ceramics were related to the increase of glass phase32. It has been proved that there was a diameter leads to maximum bending strength values, while smaller or larger diameters produce lower strength values33. Thus, the grain size of dendrite about the S3 was extremely large, resulting in the generation of crack, in which an external force was enforced, and the bending resistance was poor. As for S5, there exhibited the small crystalline size, being far away the optimum crystalline size, to result in the less bending strength compared to the S4.
Immobilization effect of heavy metals
After the leaching test of the glass-ceramics continued 18 hours, the concentration of Cr in the leachate was lower than 0.007 ppm as shown in Table 3, which was much lower than the 5 ppm required by the Chinese standard “GB 5085.3-2007”. It was found that the glass-ceramics showed excellent performance in the Cr curing after the 336 h leaching test and the increasing rate of concentration of Cr in the leachate became slowly. The results indicated that the crystalline phase with diopside structure formed with the addition of stainless steel slag. It was obvious that the oxide Cr2O3, as a nucleating agent, stabilizes in the crystalline phase. Since the atoms in the lattice were in equilibrium, resulting in a long-range order in the crystalline phase, the Gibbs free energy reached the minimum. Therefore, the element Cr stabilized the crystal structure was stably present in the crystalline phase because of the most stable crystalline state34. In addition, the crystalline phases were also surrounded by a layer of glass, as shown in Fig. 4, which prohibited the element Cr for leaching. It is accordance with the previous research6,8.
In order to further quantify the solidification effect of the glass-ceramics on the chromium ions, leaching tests were performed on the stainless steel slag and the glass-ceramics using a nitric acid solution, a concentration of 5%, respectively. The results were shown in Table 4. It was evident that the content of chromium ions from the glass-ceramics by the leaching fell off hundreds and thousands of times, compared to the stainless steel slag. As the increased trend of logarithmic function got slowly, the leaching concentration of Cr will not be much more than the content of Cr, 40.36 ppm, in the leachate. In the case of 5% nitric acid solution, unstable Cr will leach into the leachate.
Therefore, an index, unstable ratio (UR), was introduced, which was expressed as the percentage of the mass of Cr in the leachate to the mass of Cr in the specimen. An equation for calculation of the UR was followed as:
It can be concluded that the degree of crystallinity increased while the percentage of element Cr decreased, indicating that most of the element Cr was cured in the glass-ceramics.
Conclusions
The glass-ceramics with excellent properties were prepared with the addition of Chromium-containing Stainless Steel Slag, as the additive solid waste, and made the heavy metal element, Cr, solidified in the crystal lattice successfully. The results indicated that the crystalline size was continuously refined with the increased additive Stainless Steel Slag. The bending strength exhibited maximum, 222.9 MPA, due to the interlocking phenomenon, caused by the deformed fine branches of dendrite with the external forces, as the amount of Stainless Steel Slag being up to 13.68 wt.%. Afterwards, The hardness reached 721.27 HV in which the degree of crystallinity reached 8.13% as the content of Stainless Steel Slag was 18.06 wt.% and, meanwhile, the amount of chromium, 99.999%, stabilized in the crystal structure of glass-ceramics. This was because the major phase with diopside structure was formed on the basis of the minor phase with the spinel structure, as the nucleating agent of glass crystallization, with the addition of Chromium-containing Stainless Steel. So the environmental pollution for the heavy metal can be reduced by preparing the glass-ceramics using solid waste as raw materials.
References
Hatje, V. et al. The environmental impacts of one of the largest tailing dam failures worldwide. Sci. Rep. UK 7, 10706 (2017).
Mymrin, V. et al. Environmentally clean ceramics from printed circuit board sludge, red mud of bauxite treatment and steel slag. J. Clean Prod. 164, 831–839 (2017).
Lu, X. W. & Shih, K. M. Phase transformation and its role in stabilizing simulated lead-laden sludge in aluminum-rich ceramic. Water Research 45, 5123–5129 (2011).
Peng, F., Liang, K. M., Hu, A. M. & Shao, H. Nano-crystal glass-ceramics obtained by crystallization of vitrified coal fly ash. Fuel 83, 1973–1977 (2004).
Chu, S. et al. Municipal sewage sludge compost promotes Mangifera persiciforma tree growth with no risk of heavy metal contamination of soil. Sci. Rep. UK 7, 13408 (2017).
Peng, F., Liang, K. M., Shao, H. & Hu, A. M. Nano-crystal glass-ceramics obtained by crystallization of vitrified red mud. Chemosphere 59, 899–903 (2005).
Tian, Y., Zuo, W. & Chen, D. D. Crystallization evolution, microstructure and properties of sewage sludge-based glass–ceramics prepared by microwave heating. J. Hazard Mater 196, 370–379 (2011).
Liao, C. Z. et al. Double-Barrier mechanism for chromium immobilization: A quantitative study of crystallization and leachability. J. Hazard Mater 311, 246–253 (2016).
Suanon, F. et al. Assessment of the occurrence, spatiotemporal variations and geoaccumulation of fifty-two inorganic elements in sewage sludge: A sludge management revisit. Sci. Rep. UK 7, 5698 (2017).
Zhang, H. W. & Hong, X. An overview for the utilization of wastes from stainless steel industries. Resources, Conservation and Recycling 55, 745–754 (2011).
Liao, C. Z., Tang, Y. Y. & Lee, P. H. Detoxification and immobilization of chromite ore processing residue in spinel-based glass-ceramics. J Hazard Mater 321, 449–455 (2017).
Kumar, R. et al. Oxidized g-C3N4/polyaniline nanofiber composite for the selective removal of hexavalent chromium. Sci. Rep. UK 7, 12850 (2017).
Wang, T. G., He, M. L. & Pan, Q. A new method for the treatment of chromite ore processing residues. J Hazard Mater 149, 440–444 (2007).
Wolfgang, W. et al. Growing Oriented Layers of Bi4Ti3O12 in Bi2O3/TiO2/SiO2/Nd2O3/Al2O3 Glass-ceramics by Melt Quenching. Sci. Rep. UK 8, 8639 (2018).
Chang, Y. et al. Low-Yellowing Phosphor-in-Glass for High-Power Chip-on-board White LEDs by Optimizing a Low-Melting Sn-P-F-O Glass MatrixHee. Sci. Rep. UK 8, 7412 (2018).
Li, B., Jing, K. & Bian, H. B. Effect of Zn/Zr ratio on mechanical, dielectric, and thermal properties of MgO-Al2O3-SiO2 glass-ceramics. J Non-Cryst Sol. 15, 487–492 (2018).
Zhang, H. X. et al. Influence of rare earth ions om metal ions distribution and corrosion behavior of tailing-derived glass-ceramics. J Non-Cryst Sol. 482, 105–115 (2018).
Tsakiridis, P. E., Papadimitriou, G. D. & Tsivilis, S. Utilization of Steel Slag for Porland Cement Clinker Production. J Hazard Mater 34, 802–806 (2008).
Takano, C. et al. Recovery of Cr, Ni and Fe from dust generated in stainless steelmaking. Mineral Processing & Extractive Metallurgy Imm Transactions 114, 201–206 (2005).
Nakasuga, T., Nakashima, K. & Mori, K. Recovery rate of chromium from stainless slag by iron melts. Isij International 44, 665–672 (2004).
Park, D. et al. Mechanism and kinetics of Cr (VI) reduction by iste slag generated from iron making industry. Hydrometallurgy 93, 72–75 (2008).
Nath, M., Song, S. Q., Garbers-Craig, A. M. & Li, Y. W. Phase evolution with temperature in chromium-containing refractory castables used for waste melting furnaces and Cr(VI) leachability. Resources, Ceramics International 44, 20391–20398 (2018).
Ma, G. J. & Garbers-Craig, A. M. Stabilisation of Cr (VI) in stainless steel plant dust through sintering using silica-rich clay. J. Hazard Mater 169, 210–216 (2009).
Rawlings, R. D., Wu, J. P. & Boccaccini, A. R. Glass-ceramics: Their production from wastes-A Review. J. Mater SCI. 41, 733–761 (2006).
Wang, J., Cheng, J. & Deng, Z. Effect of alkali metal Oxides on viscosity and crystallization of the MgO–Al2O3–SiO2 glasses. Physica B: Condensed Matter 415, 34–37 (2013).
Zhang, X. F. et al. Optimization of Composite Nucleating Agents and Effects on Structure and Properties of CaO-MgO-Al2O3-SiO2 Glass Ceramics. J. Synth Cryst. 44, 1905–1911 (2015).
Zhang, X. F. et al. Effect of Composite Nucleation Agents on Microstructures and Mechanical Properties of CaO-MgO-Al2O3-SiO2 glass ceramics. MaterRev: B 29, 112–115 (2015).
Cheng J. S. et al. Glass-ceramics (Chemical Industry Press, Beijing, China, 2006).
Shi, Y., Li, B. W., Zhao, M. & Zhang, M. X. Growth of diopside crystals in CMAS glass-ceramics using Cr2O3 as a nucleating agent. J Am Ceram Soc. 101, 1–11 (2018).
Mernagh, T. P. & Hoatson, D. M. Raman spectroscopic study of pyroxene structures from the Munni Munni layered intrusion, Western Australia. J. Raman Spectroscopy 28, 647–658 (1997).
Abou Shama, A. A. & El-batal, F. H. Structural Analysis of Glassy Lead Borate Containing MoO3 In Relation to Its Optical Properties. Egypt. J. Solids 29, 49–67 (2006).
Peng, F., Liang, K. M. & Hu, A. M. Nano-crystal glass-ceramics obtained from high alumina coal fly ash. Fuel 84, 341–346 (2005).
Dittmer, M. et al. Phase and microstructure formation and their influence on the strength of two types of glass-ceramics. J. Non-Cryst. Solids 384, 55–60 (2014).
Mao W. M. Structure principles of Crystalline Materials (Metallurgical Industry Press, Beijing, China, 2008).
Acknowledgements
This work is supported by the National Natural Science Foundation of China (Grant Nos 11564031, 51774189), Young Talents of Science and Technology in Universities of Inner Mongolia Autonomous Region, China (No.NJYT-17-B10).
Author information
Authors and Affiliations
Contributions
S.L. OuYang and Y.X. Zhang designed the experiment, analyzed data, and wrote the paper. M.Z. Zhang, Y.X. Chen, M. Wen and S.L. Liu completed the specimen preparation, experiment operation and data acquisition. Y. Shi has contributed to the representation of EBSD. B.W. Li and Z.W. Zhao provided the idea, project funds and the paper modification and improvement work. All the authors reviewed and discussed the manuscript.
Corresponding author
Ethics declarations
Competing Interests
The authors declare no competing interests.
Additional information
Publisher’s note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
OuYang, S., Zhang, Y., Chen, Y. et al. Preparation of Glass-ceramics Using Chromium-containing Stainless Steel Slag: Crystal Structure and Solidification of Heavy Metal Chromium. Sci Rep 9, 1964 (2019). https://doi.org/10.1038/s41598-018-37996-4
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/s41598-018-37996-4
- Springer Nature Limited
This article is cited by
-
Effect of manganese on the structure of CMAS slag glass–ceramics
Journal of the Australian Ceramic Society (2024)
-
Reduction of hexavalent chromium using bacterial isolates and a microbial community enriched from tannery effluent
Scientific Reports (2022)
-
Solidification/stabilization of chromite ore processing residue via co-sintering with hazardous waste incineration residue
Environmental Science and Pollution Research (2022)
-
Cu/Cr co-stabilization mechanisms in a simulated Al2O3-Fe2O3-Cr2O3-CuO waste system
Frontiers of Environmental Science & Engineering (2021)