Abstract
This article presents a collection of data on approximately 150 copper-based alloys. The data compilation is based on articles published since 1993 and consists of about 1830 records. Each record contains a unique set of descriptors, such as composition and processing route, and targets, including properties such as hardness, yield strength, ultimate tensile strength, and electrical conductivity. The dataset includes information on the composition in mass percent of 20 alloying elements, and hundreds of temperature-time thermal treatments and thermomechanical conditions. The database is continually updated and hosted on an open data repository. Some of the data are presented graphically in the article to aid interpretation. This study intends to promote the identification of more sustainable alternatives to Cu-Be alloys, which is particularly relevant in developing non-toxic and environmentally-friendly alloys.
Similar content being viewed by others
Background & Summary
Copper is a versatile metal with excellent electrical, thermal, formability, and corrosion-resistant properties, making it a popular choice in a wide range of applications requiring high thermal and electrical conductivity1,2,3,4. Applications include pumps, tubing, heat exchangers, electrical wires, and contact materials. Copper is also crucial for developing electric cars and energy transition as it is a highly conductive metal that is used in the production of electric motors, wiring, and other components necessary for the efficient transmission and storage of electricity. However, the mechanical strength of pure copper is relatively low at room temperature, making it unsuitable for specific applications that require both strength and conductivity, such as connectors, electromagnetic relays, and aerospace devices. Copper beryllium (Cu-Be) alloys are the most efficient system due to their exceptional combination of high strength, good electrical and thermal conductivity, good wear, and corrosion resistance. However, due to the hazardous nature of beryllium, there is a need for non-toxic and sustainable alternatives. Given this context, finding credible alternatives to Cu-Be alloys is of great importance in developing non-toxic and more sustainable alloys with high strength and high conductivity. This data article presents a compilation of structural and functional properties from published results from 1993 to 2021 for various copper-based alloys and related materials, focusing on alternative systems to Cu-Be alloys. These systems include Cu-Ti and Cu-Ni-Si, which have shown great potential for achieving both high strength and high conductivity. With the increasing demand for non-toxic and sustainable materials, accurate and high-quality data on these alternatives are crucial for further alloy design and development. The data presented in this article can aid researchers and engineers in identifying gaps in the design space, performing data mining, training machine learning models, and developing more sustainable alloys with desirable properties.
Methods
To locate reliable sources of data on copper alloys, a comprehensive search was conducted on Web of Science and Google Scholar using the keyword “copper-based alloys” in 2022. The search yielded hundreds of potentially useful articles dating from 1993 to 2021, containing experimental data on mechanical properties and conductivity. Bronzes and brasses were excluded as they lie too far from the strength-conductivity Pareto front, as well as Cu-Nb and Cu-Cr composites, to maintain a focus on precipitation-strengthen alloys.
The Data Records section describes the process used to extract relevant mechanical property and conductivity data from the articles’ plots, tables, and text. To extract data from plots, we utilized Plotdigitize (https://plotdigitizer.com). Figure 1 illustrates the structure of our dataset. The keywods and structure are documented in the Data Records section. Figure 2 provides an overview of the data extraction workflow.
Data Records
The complete database on copper-based alloys is available as a csv file via a public online repository at Figshare5. The database contains 1831 records from about 50 articles6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51. An individual record is defined as having a unique set of descriptors (composition, processing route), targets (properties), and reference combinations.
The data provided in the database are intended to reflect the information available in the literature best. For example, despite the importance of the microstructure on properties, this feature is missing or not properly described from most of the articles, so it is not provided in the database. However, thermal and thermomechanical treatments applied to control the microstructure, which in-fine affect the properties, are recorded, including the temporal dependency of the property targets.
The database records consist of the following fields that are not equally populated for every records due to the lack of literature data:
-
Descriptors:
-
Alloy composition: alphabetized nominal alloy composition, in weight percent.
-
Processing method: the conditions under which the alloy was processed after synthesis. They include the temperatures, Tss (K) and Tag (K), and times tss (h) and tag (h) of the solid solutionning and precipitation aging thermal treatments, respectively. Cold reduction is filed in when cold rolling was applied prior or after thermal treatment. The secondary thermo-mechanical treatment is indicated by “Y” (yes) or “N” (no) to denote whether additional treatments were applied after aging. These treatments can involve multiple cold rolling and aging processes, among others.
-
-
Targets:
-
Hardness (HV): experimentally reported room temperature Vickers hardness.
-
Yield strength (MPa): measured room temperature yield strength.
-
Ultimate tensile strength (MPa): measured room temperature ultimate tensile strength.
-
Electrical conductivity (%IACS): stands for International Annealed Copper Standard, which is the percentage of room temperature electrical conductivity a material has relative to copper.
-
-
Reference: to ensure the data quality is upheld, a digital object identifier (DOI) link is provided for each record, which links to the original source.
Figure 3 provides statistics on the descriptors and property targets extracted and included in the database. In addition to boxplots, Fig. 4 shows a correlation analysis to enhance the understanding of the dataset.
Technical Validation
The data presented in this article were carefully collected, processed, and thoroughly verified for accuracy by a team of experienced materials scientists and material engineers who possess a deep understanding of metallurgy, copper alloys, and their properties.
The verification process involved a two-step validation procedure. Firstly, during the data extraction phase, we implemented a double-check system. Each data point was independently extracted by two members of our team. Discrepancies between the two extractions were discussed and resolved by referring back to the original source. This process ensured that the data extraction was accurate and consistent. Secondly, we performed a statistical analysis on the collected data. This allowed us to identify any outliers or data points that deviated significantly from the expected values based on the existing literature and theoretical predictions. These data points were re-checked for accuracy.
Usage Notes
This dataset is intended to guide researcher efforts for future Cu-based alloy design and development. It can be helpful as training data for data mining and machine learning applications (e.g. scikit-learn52) and produce compelling visualizations in conjunction with standard Python data processing packages (e.g. Matplotlib53) as illustrated in Figs. 5–7, where the relationship between hardness and electrical conductivity is displayed. Individual records are shown by symbols with color maps associated with different features. Figure 5 evidences the distinct regions of the property space occupied by different Cu-based alloys classes. The color saturation, corresponding to the density of the data points, highlights the prevalence of low alloyed Cu, Cu-Ni-Si, Cu-Be, and Cu-Ti alloys in specific ranges of (Electrical conductivity, Hardness), namely (80, 120), (30–40, 200–300), (20, 350), and (15, 325) respectively. Figure 6 highlights the region in the upper left corner of the hardness-electrical conductivity space, which is predominantly occupied by Cu-Be alloys. The color map represents the percentage of cold rolling reduction. While a few Cu-Ti and Cu-Ni-Si alloys show potential as competitors to Cu-Be alloys, it is important to note that Cu-Be alloys were not subjected to cold rolling, unlike their counterparts. Additionally, the optimal performance of Cu-Ni-Si alloys overlaps with Cu-Be alloys only when multiple cold rolling and aging treatments are applied. Figure 7 highlights the influence of aging conditions on the properties of a specific alloy composition. It is evident that reducing the aging temperature leads to an increase in hardness, reaching a maximum value at an intermediate aging time. Conversely, the electrical conductivity exhibits an inverse relationship, wherein it increases as both the aging temperature and time increase.
References
Yang, H. et al. High strength and high conductivity Cu alloys: A review. Sci. China Technol. Sci. 63, 2505–2517 (2020).
Li, Z. D., Lin, C. G. & Cui, S. Development of Research and Application of Copper Alloys with High Strength and High Conductivity. Adv. Mater. Res. 1053, 61–68 (2014).
Copper Applications Technology Roadmap, International Copper Association, March 2011.
Gorsse, S., Ouvrard, B., Gouné, M. & Poulon-Quintin, A. Microstructural design of new high conductivity – high strength Cu-based alloy. J. Alloys Compd. 633, 42–47 (2015).
Gorsse, S., Gouné, M., Lin, W-C. & Girard, L. Dataset of mechanical properties and electrical conductivity of copper-based alloys, Figshare, https://doi.org/10.6084/m9.figshare.c.6475600.v1 (2013).
Jia, S. G. et al. Aging properties studies in a Cu–Ag–Cr Alloy. Mater. Sci. Eng. A 419, 8–11 (2006).
Shangina, D. V. et al. Effect of chromium and zirconium content on structure, strength and electrical conductivity of Cu-Cr-Zr alloys after high pressure torsion. Mater. Lett. 199, 46–49 (2017).
Ye, Y. et al. Enhanced strength and electrical conductivity of Cu–Zr–B alloy by double deformation–aging process. J. Alloys Compd. 615, 249–254 (2014).
Lu, D.-P. et al. Study on high-strength and high-conductivity Cu–Fe–P alloys. Mater. Sci. Eng. A 421, 254–259 (2006).
Pang, Y. et al. Effects of Zr and (Ni, Si) additions on properties and microstructure of Cu–Cr alloy. J. Alloys Compd. 582, 786–792 (2014).
Fernee, H., Nairn, J. & Atrens, A. Precipitation hardening of Cu-Fe-Cr alloys part I Mechanical and electrical properties. Journal of Materials Science 36, 2711–2719 (2001).
Gaganov, A., Freudenberger, J., Botcharova, E. & Schultz, L. Effect of Zr additions on the microstructure, and the mechanical and electrical properties of Cu–7 wt.%Ag alloys. Mater. Sci. Eng. A 437, 313–322 (2006).
Li, Z., Pan, Z. Y., Zhao, Y. Y., Xiao, Z. & Wang, M. P. Microstructure and properties of high-conductivity, super-high-strength Cu–8.0Ni–1.8Si–0.6Sn–0.15Mg alloy. J. Mater. Res. 24, 2123–2129 (2009).
Zhang, H., Fu, H., Zhu, S., Yong, W. & Xie, J. Machine learning assisted composition effective design for precipitation strengthened copper alloys. Acta Mater. 215, 117118 (2021).
Han, S. Z. et al. Increasing strength and conductivity of Cu alloy through abnormal plastic deformation of an intermetallic compound. Sci. Rep. 6, 30907 (2016).
Monzen, R. & Watanabe, C. Microstructure and mechanical properties of Cu–Ni–Si alloys. Mater. Sci. Eng. A 483–484, 117–119 (2008).
Rdzawski, Z. & Stobrawa, J. Thermomechanical processing of Cu–Ni–Si–Cr–Mg alloy. 9 (1993).
Xiao, X.-P. et al. Microstructure and properties of Cu–Ni–Si–Zr alloy after thermomechanical treatments. Rare Met. 32, 144–149 (2013).
Lei, Q. et al. Effect of aluminum on microstructure and property of Cu–Ni–Si alloys. Mater. Sci. Eng. A 572, 65–74 (2013).
Lei, Q. et al. A new ultrahigh strength Cu–Ni–Si alloy. Intermetallics 42, 77–84 (2013).
Lei, Q., Li, Z., Gao, Y., Peng, X. & Derby, B. Microstructure and mechanical properties of a high strength Cu-Ni-Si alloy treated by combined aging processes. J. Alloys Compd. 695, 2413–2423 (2017).
Li, R., Zhang, S., Zou, C., Kang, H. & Wang, T. The roles of Hf element in optimizing strength, ductility and electrical conductivity of copper alloys. Mater. Sci. Eng. A 758, 130–138 (2019).
Wang, Z. et al. Effects of Co Addition on the Microstructure and Properties of Elastic Cu-Ni-Si-Based Alloys for Electrical Connectors. Materials 14, 1996 (2021).
Lee, E., Han, S., Euh, K., Lim, S. & Kim, S. Effect of Ti addition on tensile properties of Cu-Ni-Si alloys. Met. Mater. Int. 17, 569–576 (2011).
Lei, Q., Xiao, Z., Hu, W., Derby, B. & Li, Z. Phase transformation behaviors and properties of a high strength Cu-Ni-Si alloy. Mater. Sci. Eng. A 697, 37–47 (2017).
Huang, J. et al. Microstructure and Properties of a Novel Cu–Ni–Co–Si–Mg Alloy with Super-high Strength and Conductivity. Mater. Sci. Eng. A 744, 754–763 (2019).
Li, D. et al. Minor-alloyed Cu-Ni-Si alloys with high hardness and electric conductivity designed by a cluster formula approach. Prog. Nat. Sci. Mater. Int. 27, 467–473 (2017).
Li, J. et al. Effect of Ni/Si Mass Ratio and Thermomechanical Treatment on the Microstructure and Properties of Cu-Ni-Si Alloys. Materials 12, 2076 (2019).
Semboshi, S., Sato, S., Iwase, A. & Takasugi, T. Discontinuous precipitates in age-hardening CuNiSi alloys. Mater. Charact. 115, 39–45 (2016).
Cheng, J. Y., Tang, B. B., Yu, F. X. & Shen, B. Evaluation of nanoscaled precipitates in a Cu–Ni–Si–Cr alloy during aging. J. Alloys Compd. 614, 189–195 (2014).
Wang, W. et al. Effects of Cr and Zr additions on microstructure and properties of Cu-Ni-Si alloys. Mater. Sci. Eng. A 673, 378–390 (2016).
Zhang, X. et al. Review of nano-phase effects in high strength and conductivity copper alloys. Nanotechnol. Rev. 8, 383–395 (2019).
Watanabe, C., Nishijima, F., Monzen, R. & Tazaki, K. Mechanical Properties of Cu-4.0wt%Ni-0.95wt%Si Alloys with and without P and Cr Addition. Mater. Sci. Forum 561–565, 2321–2324 (2007).
Chenna Krishna, S. et al. Microstructure and Properties of a High-Strength Cu-Ni-Si-Co-Zr Alloy. J. Mater. Eng. Perform. 22, 2115–2120 (2013).
Xiao, X., Yi, Z., Chen, T., Liu, R. & Wang, H. Suppressing spinodal decomposition by adding Co into Cu–Ni–Si alloy. J. Alloys Compd. 660, 178–183 (2016).
Suzuki, S., Shibutani, N., Mimura, K., Isshiki, M. & Waseda, Y. Improvement in strength and electrical conductivity of Cu–Ni–Si alloys by aging and cold rolling. J. Alloys Compd. 417, 116–120 (2006).
Ryu, H. J., Baik, H. K. & Hong, S. H. Effect of thermomechanical treatments on microstructure and properties of Cu-base leadframe alloy. Journal of Materials Science 35, 3641–3646 (2000).
Srivastava, V. C., Schneider, A., Uhlenwinkel, V., Ojha, S. N. & Bauckhage, K. Age-hardening characteristics of Cu–2.4Ni–0.6Si alloy produced by the spray forming process. J. Mater. Process. Technol. 147, 174–180 (2004).
Liu, F. et al. Simultaneously enhanced hardness and electrical conductivity in a Cu–Ni–Si alloy by addition of Cobalt. J. Alloys Compd. 862, 158667 (2021).
Liu, Y., Wang, J., Xiao, B. & Shu, J. Accelerated development of hard high-entropy alloys with data-driven high-throughput experiments. J. Mater. Inform. 2, 3 (2022).
Han, S. Z. et al. Effect of V addition on hardness and electrical conductivity in Cu-Ni-Si alloys. Met. Mater. Int. 19, 637–641 (2013).
Huang, F., Ma, J., Ning, H., Cao, Y. & Geng, Z. Precipitation in Cu–Ni–Si–Zn alloy for lead frame. Mater. Lett. 57, 2135–2139 (2003).
Semboshi, S., Orimo, S., Suda, H., Gao, W. & Sugawara, A. Aging of Copper-Titanium Dilute Alloys in Hydrogen Atmosphere: Influence of Prior-Deformation on Strength and Electrical Conductivity. Mater. Trans. 52, 2137–2142 (2011).
Si, L. et al. Microstructure and property of Cu–2.7Ti–0.15Mg–0.1Ce–0.1Zr alloy treated with a combined aging process. Mater. Sci. Eng. A 650, 345–353 (2016).
Nagarjuna, S., Balasubramanian, K. & Sarma, D. S. Effect of prior cold work on mechanical properties, electrical conductivity and microstructure of aged Cu-Ti alloys. Journal of Materials Science 34, 2929–2942 (1999).
Huang, L. et al. Effects of microelements on the microstructure evolution and properties of ultrahigh strength Cu–Ti alloys. Mater. Sci. Eng. A 823, 141581 (2021).
Li, C. et al. Effect of cold rolling and aging treatment on the microstructure and properties of Cu–3Ti–2Mg alloy. J. Alloys Compd. 818, 152915 (2020).
Huang, X. et al. The influence of precipitation transformation on Young’s modulus and strengthening mechanism of a Cu–Be binary alloy. Mater. Sci. Eng. A 772, 138592 (2020).
Zhang, H., Jiang, Y., Xie, J., Li, Y. & Yue, L. Precipitation behavior, microstructure and properties of aged Cu-1.7 wt% Be alloy. J. Alloys Compd. 773, 1121–1130 (2019).
Guoliang, X., Qiangsong, W., Xujun, M., Baiqing, X. & Lijun, P. The precipitation behavior and strengthening of a Cu–2.0wt% Be alloy. Mater. Sci. Eng. A 558, 326–330 (2012).
Islamgaliev, R. K., Nesterov, K. M., Bourgon, J., Champion, Y. & Valiev, R. Z. Nanostructured Cu-Cr alloy with high strength and electrical conductivity. J. Appl. Phys. 115, 194301 (2014).
Pedregosa, F. et al. Scikit-learn: Machine learning in Python. Journal of machine learning research 12, 2825–2830 (2011).
Hunter, J. D. Matplotlib: A 2D Graphics Environment. Computing in Science & Engineering 9(3), 90–95 (2007).
Kluyver, T. et al. Jupyter notebooks – a publishing format for reproducible computational workflows. In Loizides, F. & Schmidt, B. (eds.) Positioning and Power in Academic Publishing: Players, Agents and Agendas, 87–90 (IOS Press, 2016).
Van Rossum, G. & Drake, F. L. Python 3 Reference Manual. (CreateSpace, Scotts Valley, CA, 2009).
Acknowledgements
This work was triggered and supported by AMPCO METAL to promote the identification of new alloys using last developments in AI and machine learning models.
Author information
Authors and Affiliations
Contributions
Stéphane Gorsse performed the database construction, provided technical expertise, and wrote the manuscript. Mohamed Gouné extracted and validated data from research articles, provided technical expertise, and reviewed the manuscript. Wei-Chih Lin extracted and validated data from research articles. Lionel Girard oversaw the construction of the database and reviewed the manuscript.
Corresponding author
Ethics declarations
Competing interests
The authors declare no competing interests.
Additional information
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Gorsse, S., Gouné, M., Lin, WC. et al. Dataset of mechanical properties and electrical conductivity of copper-based alloys. Sci Data 10, 504 (2023). https://doi.org/10.1038/s41597-023-02411-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/s41597-023-02411-9
- Springer Nature Limited