Abstract
Over the Earth’s evolutionary history, the style of plate subduction has evolved through time due to the secular cooling of the mantle. While continuous subduction is a typical feature of modern plate tectonics, a stagnant-lid tectonic regime with localized episodic subduction likely characterized the early Earth. The timing of the transition between these two subduction styles bears important insights into Earth’s cooling history. Here we apply a statistical analysis to a large geochemical dataset of mafic rocks spanning the last 3.5 Ga, which shows an increasing magnitude of alkali basaltic magmatism beginning at ca. 2.1 Ga. We propose that the rapid rise of continental alkali basalts correlates with an abruptly decreasing degree of mantle melting resulting from the enhanced cooling of the mantle at ca. 2.1 Ga. This might be a consequence of the initiation of continuous subduction, which recycled increasing volumes of cold oceanic crust into the mantle.
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Introduction
Earth’s tectonics evolved through multiple phases coupled with its cooling history. In the early stage, the Earth’s geodynamic model was dominated by a stagnant-lid vertical tectonic regime1,2,3,4,5,6. The recycling of oceanic plates was likely performed by episodic subduction2,4,7,8,9. Such episodic subduction was mainly recognized by numerical modeling as the subducting plate underwent frequent slab break-off in the hot mantle (ca. 175–250 °C hotter than the present mantle)7,9. As a result of the secular cooling of the mantle, the subduction style was later transitioned into the self-sustaining continuous subduction2,9,10. The continuous subduction that dominates at the modern convergent plate boundaries, is characterized by long-lived recycling of oceanic plate into the mantle along the subduction zone7,9,10.
The style of plate subduction has profound influences on orogenic processes, continent evolution, and mass exchange between the shallow and deep Earth. Although the onset of plate tectonics has been highly contested with estimates ranging from >4 Ga to <1 Ga3,5,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25, little is known about the pace of subduction style evolution, particularly the transition from episodic to continuous plate subduction. Based on the abundantly preserved Neoproterozoic and younger ophiolites, the modern-style continuous subduction has been inferred to commence at ca. 1.0 Ga in the Neoproterozoic era11,12. However, the Jormua ophiolite in Finland and Purtuniq ophiolite in Canada support the generation and emplacement of such rocks at ca. 2.0 Ga in the Paleoproterozoic26,27. Furthermore, more recent studies on the newly discovered ~1.83 Ga eclogite in the Trans-Hudson orogen of North America28 and the ~1.82 Ga eclogite xenolith in a Paleoproterozoic carbonatite unit in North China29 imply that local episodes of deep subduction had already occurred before ca. 1.8 Ga. The previously recognized 2.2–2.0 Ga blueschist-facies metamorphic rocks from the West African craton also suggest that modern-style subduction operated, at least locally, as early as the Paleoproterozoic30. A more recent compilation of geochemical and palaeomagnetic data suggests that the change from the pre-plate tectonic stagnant-lid setting to sustained plate tectonics transitioned over a long period from 3.2 to 2.5 Ga4.
An important consequence of continuous subduction is the enhanced cooling of the mantle caused by the increasing volume of subducting oceanic crust31,32,33, which, in turn, would result in lower degrees of mantle partial melting32. The decreasing degree of mantle melting should lead to a reduction of komatiites33 and an increase in continental alkali basalts. Here we apply a statistical analysis to the geochemical data of mafic igneous rocks across two typical modern arc-continent tectonic systems to test the geochemical behaviors of several specific incompatible elements from their magmatic arcs towards their continental interiors. Then we evaluate ~55,000 mafic igneous rocks spanning the last 3.5 Ga to track the initiation and consequence of continuous plate subduction. The start time of continuous plate subduction is estimated as ca. 2.1 Ga.
Results
High-field strength elements systematics
The High-field strength elements (HFSE; e.g. Nb, Ta, Ti), as well as phosphorus (P), are relatively fluid-immobile elements, which are predominantly retained by insoluble minerals (e.g. rutile, apatite, etc.) during the subduction dehydration process34,35,36. This retention process accounts for the relatively low HFSE and P concentrations of arc mafic rocks. By contrast, mafic magmas that erupt in the interior of continents are dominated by sodic alkali basalts with lesser amounts of potassic alkali basalts and tholeiitic basalts37. These intracontinental alkali basalts are predominantly characterized by high HFSE and P concentrations. They have primitive-mantle normalized trace element patterns similar to those of oceanic island basalts (OIB)37.
The magmatic sources of continental alkali basalts are considered to be derived from melting in upwelling sublithospheric mantle or from lithospheric mantle that has been metasomatized by asthenosphere-derived melts37. Whether the mantle melting is induced by actively upwelling high-temperature plumes or by passively upwelling asthenosphere as a consequence of lithospheric extension in both localized continental rifts (e.g. East African Rift, Baikal, etc.) and broader continental regions (e.g. eastern China, southern Argentina, western US, Southeast Asia, south-eastern Australia, etc.)37,38,39,40,41,42, the generation of alkali basaltic magma usually requires low degrees of mantle melting37,43,44.
We chose two typical sites of modern arc-continent tectonic systems, the Southern Andes of South America and East Asia, as examples to illustrate the difference in HFSE and P systematics between arc mafic rocks and continental alkali basalts with the current thermal state of the mantle. Geochemical data for arc and intracontinental mafic rocks were extracted from the EarthChem rock database45. In the Southern Andes as well as the northern tip of the Antarctic Peninsula, arc mafic rocks near the Pacific coastline contain relatively low HFSE and P concentrations, while the intracontinental mafic rocks, dominated by alkali basalts, contain high HFSE and P concentrations (Fig. 1a–c, e, f). It is also noteworthy that the SiO2 concentration in the majority of arc mafic rocks is >49 wt%, while the intracontinental alkali basalts contain variable SiO2 concentrations from 45 to 52 wt% (Fig. 1d, h). We calculated the average HFSE and P concentrations of the combined arc and intracontinental mafic rocks for each 1 wt% SiO2 interval from 45 to 52 wt% (Fig. 1e–g). The combined HFSE-SiO2 and P-SiO2 compositional trends show that the average HFSE and P concentrations in low-silica mafic rocks (45–49 wt% SiO2) are statistically higher than those in high-silica mafic rocks (49–52 wt% SiO2; Fig. 1e–g; Supplementary Table 1). Similarly, in East Asia (Fig. 2), the arc mafic rocks located on the Kamchatka Peninsula, Kuril Islands, Japanese Islands, Ryukyu Islands, and Izu-Bonin-Mariana Arc have relatively low-HFSE, low-P (Fig. 2a–c, e–g), and high-SiO2 concentrations (mostly 49–52 wt% SiO2; Fig. 2d, h), while the intracontinental alkali basalts in eastern China are significantly more HFSE and P-enriched (Fig. 2a–c, e–g) with more variable SiO2 concentrations (Fig. 2d, h). Consequently, from the combined compositional trends (Figs. 1e–g and 2e–g; Supplementary Tables 1 and 2), we may conclude that with the current thermal state of the mantle the low-silica mafic rocks contain statistically higher average HFSE and P concentrations than the high-silica mafic rocks in the arc-continent tectonic systems.
The above two examples show the typical HFSE-SiO2 and P-SiO2 fractionation existing between arc mafic rocks and continental alkali basalts with the present, or the Phanerozoic (541 Ma to the present), thermal state of the mantle. Although the alkali basaltic rocks were commonly considered as the products of low degrees of mantle melting37,43, they were rarely seen in the Archean as the mantle temperature then was much hotter than its temperature during the Phanerozoic13,46, thus favoring higher degrees of mantle melting. In view of this fact, we extracted the relevant geochemical data from the EarthChem database for Phanerozoic and Archean mafic rocks (excluding komatiites and komatiitic basalts) and examined their combined Nb-SiO2, TiO2-SiO2, and P-SiO2 compositional trends. The results show that all the average Nb, Ti, and P concentrations of Phanerozoic mafic rocks decrease as SiO2 concentrations increase from 45 to 52 wt% (Fig. 3; Supplementary Table 3). Again, the average HFSE and P concentrations in low-silica mafic rocks are statistically higher than those in high-silica mafic rocks, which is very similar to the situations in the Southern Andes and East Asia (Figs. 1 and 2). Most likely it is the extensive Phanerozoic continental alkali basalts from those intracontinental regions as well as continental rifts that have significantly elevated the average HFSE and P concentrations in the low-silica mafic rocks. By contrast, all the Nb-SiO2, Ti-SiO2, and P-SiO2 combined compositional trends of the Archean mafic rocks differ significantly from those of the Phanerozoic mafic rocks (Fig. 3; Supplementary Table 3). Here the average HFSE and P concentrations of low-silica mafic rocks are approximately equal to those in high-silica mafic rocks.
Determining the rise of alkali basalts
The different characteristics of Nb-SiO2, Ti-SiO2, and P-SiO2 fractionation between the Archean and the Phanerozoic are attributable to the different mantle temperature46. The relatively cold mantle temperatures in the Phanerozoic were more favorable for low degrees of melting and generation of alkali basaltic magmas with high Nb, Ti, and P concentrations and low-silica contents. The hot mantle in the Archean would facilitate higher degree of melting with the production of more tholeiitic basalts with low Nb, Ti, and P concentrations. Therefore, the magnitude of intracontinental alkali basalt eruptions is likely to have been limited in the Archean. We calculated the proportion of alkali basalts in relation to all mafic rocks for every 0.25-Ga time interval. As shown in Fig. 4b, the proportion of alkali basalts is only ~5% in the Archean, whereas in the Phanerozoic, alkali basalts account for >40% of total mafic rock production (exclusive of oceanic rocks). This result corroborates the assumption that the hot mantle in the Archean, or even subsequently, has not contributed to the formation of extensive continental alkali basalts. Such a small proportion of alkali basalts explains why the average Nb, Ti, and P concentrations in low-silica mafic rocks in the Archean are not elevated (Fig. 1a–c).
We now examine the entire mafic rock database (Supplementary Data 1) to trace the rise of alkali basalts and reconstruct the history of changes in thermal state of the mantle. To quantify the contribution from alkali basalts, we introduce a new geochemical proxy, Diff (HFSE), which reflects the relative enrichments or depletions in HFSE (or P) with increasing SiO2 in mafic rocks:
The ω(HFSE)low-Si is the average HFSE or P concentrations in rocks with 45–49 wt% SiO2, while ω(HFSE)high-Si is the average HFSE or P concentrations in rocks with 49–52 wt% SiO2. The secular variations of Diff (Nb), Diff (Ti), and Diff (P) over time are shown in Fig. 4a and Supplementary Tables 4–6. All the Diff (HFSE) vary over a small range around zero from ca. 3.0 to 2.1 Ga, after which they show an abrupt increase and maintain values above zero through the rest of the Earth’s history. The rapid increase of Diff (HFSE) from zero to positive values over the 2.1–1.8 Ga time range compellingly reveals that the combined Nb-SiO2, Ti-SiO2, and P-SiO2 compositional trends of mafic rocks were changing from an Archean-like style to a Phanerozoic-like style (Fig. 3). After 1.8 Ga, the Diff (HFSE) vary as positive values with relatively small fluctuations until ca. 0.1 Ga. The enhancement of Diff (Nb) and Diff (P) at the last 0.1 Ga time interval are caused by the over sampled alkali basalts (both high-Ti and low Ti) from the continental rifts (especially from the East African Rift) and volcanic cones in the broad continental areas for the most recent 50 Ma, which are much less preserved before 50 Ma (Supplementary Fig. 1). Thus, it may not have a geological significance.
Discussion
The rapid increases of Diff (HFSE) from near zero to positive values during the 2.1–1.8 Ga interval (Fig. 4a) reflect the dramatically increasing contribution from intracontinental alkali basalts to the Earth’s mafic rocks. We propose that this abrupt shift represents an enhanced cooling pace of the mantle, as a consequence of the initiation of Phanerozoic-like continuous subduction.
Previous numerical modeling studies suggested that the postulated subduction style of Archean plate tectonics is episodic47,48 and shallow3,5,10,49. The principal reasoning for an episodic subduction style in the Archean is the higher mantle temperature10,47, which resulted in more extensive partial melting of the mantle9. The higher degree of mantle melting produced a much thicker oceanic crust than today10,50. Consequently, as such crustal material is significantly less dense than the lithospheric mantle, the thicker oceanic crust would have reduced the overall density of the bulk oceanic lithosphere9,47. At the same time, the higher mantle temperature beneath the oceanic crust certainly would have reduced the strength of the subducting slab and formed a weaker oceanic plate. With the thicker and weaker oceanic crust, a greater tensile stress should exist between the buoyant horizontal oceanic plate and the subducted eclogitized slab9,47. In the numerical model provided by van Hunen and van den Berg47, the Archean subduction model exemplifies a discontinuous subduction behavior, as a slab would frequently break off from the trailing oceanic plate and sink down into the mantle transition zone. This loss of slab pull may frequently lead to a temporal cessation or slowdown of the oceanic plate subduction. Such an episodic recycling of oceanic crust would not decrease the mantle temperature efficiently. Herzberg et al.46 proposed that the mantle was warmed to a thermal maximum at ca. 3.0–2.5 Ga (Fig. 4c) based on the observation of secular MgO contents of non-arc basalts, and explained it as internal heating exceeding surface heat loss during the Archean. We suggest that the lack of continuous subduction might have impeded efficient heat loss, which contributed to the mantle warming in the Archean and the subsequent slow decrease of mantle temperature.
Although the thermal history of the Earth is poorly constrained, there are multiple lines of evidence that the mantle temperature during the late Archean (ca. 3.0-2.5 Ga) was ~200–250 °C hotter than its present temperature (i.e. ΔT = 200–250 °C)13,46,51 and experienced a secular cooling process during the Proterozoic and Phanerozoic5,13,46. Numerical modelings suggest that the oceanic plates could underthrust beneath the continental plates along shallow subduction zones when the mantle temperature (TP) was <250 °C above its present temperature10,49. However, because the plates were likely weak and deformed internally, the subducting oceanic plate might break-off frequently at shallow depths7,9,47. Continuous plate subduction could only be established after the upper mantle became cold enough (ΔT = 175–160 °C) and thus the oceanic plates became mechanically strong. The mantle potential temperature (TP) at 2.1 Ga was around 1520–1580 °C as proposed by Korenage13, ~170–230 °C higher than the present-day mantle (Fig. 4c). Before 2.1 Ga, the temperature (TP) had exceeded the threshold temperature (ΔT = 175–160 °C) for triggering continuous plate subduction10. Once the mantle after 2.1 Ga was cold enough to generate a stronger subducting oceanic slab, the oceanic plate was subducted into the mantle along convergent plate boundary in an uninterrupted succession unless terminated by continental collision. Consequently, the transition of plate subduction style could significantly enhance the mantle cooling by recycling increasing volumes of cold oceanic crust into the mantle continuously31,32,33. In this circumstance, heat loss of the mantle largely exceeded the internal heating from radioactive decay, and therefore rapidly decreased the mantle temperature. The accelerated decrease of mantle temperature resulted in a lower degree of partial melting of the sublithospheric mantle away from the subduction zones, which gave rise to increasing amounts of continental alkali basalts with high Nb, Ti, and P concentrations and relatively low-silica contents. Therefore, we conclude that the rapid increase of Diff (HFSE)s at ca. 2.1 Ga (Fig. 4a) is a consequence of the initiation of continuous subduction and enhanced mantle cooling.
The rapid decrease of the mantle temperature around ca. 2.1 Ga was also noticed by previous studies on the changes in geochemical compositions of komatiites32,33. The average MgO contents in komatiites older than 2.4 Ga were >25 wt%, and dropped to around 20–22 wt% in komatiites with ages of 2.2–1.8 Ga (Supplementary Fig. 2). Condie et al.32,33 proposed that the compositional change in komatiites and a decrease of magma generation temperatures (Tg) of basalts derived from depleted mantle between 2.5 and 2.0 Ga reflect an enhanced cooling of the mantle by subduction32. To further verify the drop of mantle temperature around ca. 2.1 Ga, we calculated the secular proportions of those mafic rocks generated by high degrees of mantle melting (e.g. high MgO, low Rittmann Index) in relation to all mafic rocks from 3.0 to 0 Ga (Supplementary Fig. 3; Supplementary Tables 7 and 8). The proportion of high-degree melting rocks is large in the stagnant-lid stage and show a dramatic drop around 2.1 Ga, which is most likely a consequence of the accelerated decrease of mantle temperature caused by the onset of continuous subduction. Although the decrease in degree of mantle melting may be partly due to non-linear melting of the mantle20, the cooling rate should definitely be enhanced by increasing the volume of cold oceanic crusts subducted into the mantle.
An assortment of evidences of magmatic and orogenic activities indicate a tectonic transition in the early Paleoproterozoic. The 2.4–2.2 time interval includes a minimum of magmatic records, which has been previously recognized as a magmatic shutdown52 and recently proposed as a tectono-magmatic lull53 due to the additional evidences of igneous rocks and detrital zircons within this interval54. Spencer et al.53 linked the magmatic flare-up subsequent to this magmatic lull with the dramatic growth of continental crust and the transition from supercraton to supercontinent cycle. Brown and Johnson3 also noticed a rise in thermal gradients of high-temperature/pressure (dT/dP > 775 °C GPa−1) metamorphism ~2.3–2.1 Ga and the spread of metamorphic rocks with ages from 2.1 to 1.5 Ga, and interpreted them as the reconfiguration from supercratons to the first supercontinent. These perspectives are in accord with our proposal because the ongoing plate convergence of the supercontinent cycle is driven by continuous plate subduction that eventually led to continental collisions and supercontinent assembly4,55. The onset of continuous subduction coincided with the start of a ca. 2.1–1.8 Ga global-scale collisional orogeny49,56, which was followed by the formation of Earth’s first large supercontinent, Nuna (also named Columbia)53,56,57.
Our proposal is also consistent with the formation at ca. 2.0 Ga of the Earth’s oldest ophiolites so far discovered26,27, as well as the recently reported Paleoproterozoic low temperature/pressure (dT/dP < 375 °C GPa−1) metamorphic rocks (ca. 2.1–1.8 Ga)3,28,29,30. Although there was no record of ophiolites during the whole Mesoproterozoic, the general paucity of passive margins and the absence of evidence of orogenesis throughout the Mesoproterozoic indicate no significant breakup and reassembly of continental fragments in the transition from Nuna to Rodinia49, which probably also accounts for the lack of ophiolites. The scarcity of blueschists during the Mesoproterozoic implies that the continuous plate subduction identified in the Paleoproterozoic may be somewhat different from the previously defined modern cold plate subduction, which is characterized by the progressive appearances of blueschists typically in the Neoproterozoic and Phanerozoic2,3,12. However, the initiation of continuous subduction and the following collisional orogeny might have contributed to the occasional occurrences of localized cold subduction records and the formations of low temperature/pressure (T/P) metamorphic rocks at ca. 2.1–1.8 Ga3,28,29,30.
In summary, the plate subduction style has changed from the early episodic subduction in the stagnant-lid dominated tectonic regime to the later continuous subduction due to the secular cooling of the mantle. The mantle temperature during the stagnant-lid stage was much higher than its present temperature, thereby accounting for the Archean scarcity of continental alkali basalts due to the higher degree of mantle melting. As the mantle gradually cooled after the Archean, oceanic slab would become strong enough to stabilize a continuous subduction. The mantle cooling was accelerated thereafter due to the continuous recycling of cold oceanic crust. The drop of mantle temperature resulted in a rapidly decreasing degree of mantle melting, which gave rise to increasing amounts of continental alkali basaltic rocks enriched in Nb, Ti, and P. Statistical analysis of igneous geochemical data indicates that the Nb, Ti, and P concentrations in low-silica mafic rocks has increased significantly since ca. 2.1 Ga. The beginning time of continuous subduction is estimated as ca. 2.1 Ga based on this systematic change. This proposal is coincident with the compositional change of komatiites32,33, the decrease of the magma generation temperature (Tg) of basalts derived from depleted mantle31,32, the start of ca. 2.1–1.8 Ga global-scale collisional orogeny56, the transition from the supercraton to the supercontinent cycle3,53, the oldest unequivocal ophiolites26,27, and the earliest records of low temperature/pressure (T/P) metamorphic rocks3,28,29,30.
Methods
Data compilation and filtering
Fortunately, a sufficient quantity of representative rock geochemical data now exists to chronicle the secular evolution of plate tectonics over time58. Thus, geochemical data from previous studies have here been compiled to perform a statistical analysis on the secular variation of global magmatic activities and style changes of plate tectonics. A freely accessed rock geochemistry database, EarthChem45, has integrated geochemical data from abundant publications and some other databases (e.g. GEOROC, PetDB, and USGS), which spans the geological history of the Earth from ca. 3.8 Ga to the present. Although the quantity of Precambrian data is much less than for the Phanerozoic, the collection of random publications is a relatively balanced process for different ages. Specifically, the database is not expected to arbitrarily generate a sampling bias for rocks of a certain age. As such, we considered that the geochemical data of igneous rocks from the EarthChem database are representative of global magmatism throughout Earth’s history.
In this study, we downloaded all the geochemical data for the igneous rocks from the EarthChem database, including the whole-rock major and trace element concentrations, ages, and geographic coordinates. The rock samples come from different continents and island arcs around the world. Samples lacking their SiO2 concentration were omitted. Lithologies of rocks in the downloaded dataset encompass mafic (45–52 wt% SiO2), intermediate (52–63 wt% SiO2), and felsic rocks (>63 wt% SiO2).
In consideration of their distinct geochemical characteristics, we used only arc and continental mafic rocks (45–52 wt% SiO2) in this study. Rocks from the oceanic plateau, floor, and islands were excluded from our dataset to balance these geological settings with oceanic rocks of Precambrian ages, which are scarcely preserved due to plate subduction (Supplementary Fig. 4). Rocks older than 3.5 Ga were not included either, because the plate tectonics regime before 3.5 Ga is still controversial14,20. Rocks in some subduction-unrelated tectonic settings (e.g. continental flood basalts) are included because the proportion of subduction-related to subduction-unrelated rocks is associated with the thermal conditions and plate tectonic styles. Considering that komatiites, lamprophyres, and carbonatite often interest geologists and geochemists and might have been over sampled, we checked the original publications and removed those rock types to avoid the sampling bias. Besides, we also remove the dolerite/diabase dykes from the dataset because most of those dolerite/diabase dykes have undergo significant crustal contamination, which cause the additional gain of incompatible elements59,60. A final dataset containing 55,107 whole-rock geochemical data of mafic igneous rocks (Supplementary Fig. 5; Supplementary Data 1) covering 3.5-0 Ga was prepared for the statistical analysis.
We extracted two subsets of igneous rocks with ages of 5 Ma or less from the Southern Andes of South America and East Asia to characterize the geochemical behaviors of elements across subduction zones. The reason to choose such young rocks is that their current locations most closely represents the geological settings where they formed. The rocks were also subdivided into arc and intracontinental rock groups based on their locations. For instance, in East Asia, rocks from the Kamchatka Peninsula, Kuril Islands, Japanese Islands, Ryukyu Islands, and Izu-Bonin-Mariana Arc were classified into the arc group, while rocks from the eastern China were classified into the continental group.
Statistical analysis
The mean element concentrations corresponding to SiO2 from 45–52 wt% were calculated using the Bootstrap resampling method based on MATLAB (R2014a) encoding. We applied a central moving average smoothing to determine the means. The width of the sample window is set at 2 wt% SiO2, while the step width is set at 1 wt% SiO2. We executed 10,000 iterations for the Bootstrap resampled subsets. Mean value and corresponding standard error for every 1 wt% SiO2 were obtained by calculating the average value and standard deviation of those 10,000 resampled subsets. Diagrams of the combined Nb-SiO2, TiO2-SiO2, and P-SiO2 compositional trends are shown in Figs. 1 and 2, respectively.
We noticed that the mean HFSE and P concentrations in low-silica mafic rocks (45–49 wt% SiO2) in the Phanerozoic are much higher than those in high-silica mafic rocks (49–52 wt% SiO2), whereas the mean HFSE and P concentrations are slightly lower in low-silica mafic rocks in the Archean. Hence, a new geochemical proxy Diff (HFSE) to monitor the HFSE-SiO2 (or P-SiO2) compositional trend of mafic rocks is defined by the following formula:
In Formula (1), the ω(HFSE)low-Si is the mean HFSE (or P) in rocks with 45–49 wt% SiO2, while ω(HFSE)high-Si is the mean HFSE (or P) in rocks with 49–52 wt% SiO2.
The Diff (HFSE) over time (from 3.0 to 0 Ga) are calculated based on MATLAB encoding. The Diff (HFSE) of every 0.2 Ga time bins was obtained (Supplementary Fig. 6; Supplementary Tables 9–11). Because there are a limited number of samples for certain time intervals, we use the moving average method to calculate the value for a specific age. The width of the sample window is set at 0.5 Ga to include an adequate number of samples for the calculation, while the moving step width is set at 0.1 Ga. For instance, the Diff (Nb) for 1.5 Ga is calculated by the rocks formed between 1.5 and 2.0 Ga, while the Diff (Nb) for 1.4 Ga is calculated by the rocks formed between 1.4 and 1.9 Ga. We set the lower boundary of a sample window as the age of this window because what we are concerned with is the variation owing to newly involved younger samples. The means and standard errors of ω(HFSE)low-Si and ω(HFSE)high-Si are calculated by Bootstrap resampling based on the MATLAB (R2014a) function. The Diff (HFSE) and corresponding standard deviation are estimated by Monte Carlo simulation. According to the Central Limit Theorem, regardless of the distribution of a dataset, the means of randomly sampled subsets will naturally tend towards a Gaussian distribution. We created two synthetic Gaussian-distributed datasets for the means of ω(HFSE)low-Si and ω(HFSE)high-Si for every 0.1 Ga. The mean and standard deviation of a synthetic dataset was set at the mean and corresponding standard error of ω(HFSE)low-Si or ω(HFSE)high-Si, respectively. Each synthetic dataset included 10,000 simulated data, for which 10,000 simulated Diff (HFSE)s were obtained through use of formula (1). Finally, the means and standard deviations (1σ) of the Diff (HFSE)s were estimated for all the ages from 3.0 to 0 Ga, calculated at 0.1 Ga intervals.
Code availability
The computer codes used in this study are provided as supplementary information. All the relevant data and codes are freely available in GitHub at https://github.com/CodrIocas/Subduction. The MATLAB codes are provided under a GNU GPL v2.0 open-source license.
References
Bédard, J. H. A catalytic delamination-driven model for coupled genesis of Archaean crust and sub-continental lithospheric mantle. Geochim Cosmochim. Acta 70, 1188–1214 (2006).
Brown, M. The contribution of metamorphic petrology to understanding lithosphere evolution and geodynamics. Geosci. Front. 5, 553–569 (2014).
Brown, M. & Johnson, T. Secular change in metamorphism and the onset of global plate tectonics. Am. Mineral. 103, 181–196 (2018).
Cawood, P. A. et al. Geological archive of the onset of plate tectonics. Philos. Trans. A Math. Phys. Eng. Sci. 376, 20170405 (2018).
Hawkesworth, C. J., Cawood, P. A., Dhuime, B. & Kemp, T. I. S. Earth’s continental lithosphere through time. Annu. Rev. Earth Planet. Sci. 45, 169–198 (2017).
Johnson, T. E., Brown, M., Kaus, B. J. P. & VanTongeren, J. A. Delamination and recycling of Archaean crust caused by gravitational instabilities. Nat. Geosci. 7, 47–52 (2014).
O’Neill, C., Lenardic, A., Moresi, L., Torsvik, T. & Lee, C.-T. Episodic precambrian subduction. Earth Planet. Sci. Lett. 262, 552–562 (2007).
Hawkesworth, C. J., Cawood, P. A. & Dhuime, B. Tectonics and crustal evolution. GSA Today 26, 4–11 (2016).
Moyen, J.-F. & Van Hunen, J. Short-term episodicity of Archaean plate tectonics. Geology 40, 451–454 (2012).
Sizova, E., Gerya, T., Brown, M. & Perchuk, L. Subduction styles in the Precambrian: insight from numerical experiments. Lithos 116, 209–229 (2010).
Stern, R. J. Evidence from ophiolites, blueschists, and ultrahigh-pressure metamorphic terranes that the modern episode of subduction tectonics began in Neoproterozoic time. Geology 33, 557–560 (2005).
Stern, R. J. Modern-style plate tectonics began in Neoproterozoic time: an alternative interpretation of Earth’s tectonic history. Geol. Soc. Am. Spec. Pap. 440, 265–280 (2008).
Korenaga, J. Initiation and evolution of plate tectonics on earth: theories and observations. Annu Rev. Earth Planet. Sci. 41, 117–151 (2013).
Arndt, N. T. The formation and evolution of the continental crust. Geochem. Perspect. 2, 405–405 (2013).
Condie, K. C. & Kroner, A. When did plate tectonics begin? Evidence from the geologic record. Geol. Soc. Am. Spec. Pap. 440, 281–294 (2008).
Lee, C.-T. A. et al. Two-step rise of atmospheric oxygen linked to the growth of continents. Nat. Geosci. 9, 417–424 (2016).
Brown, M. Metamorphic conditions in orogenic belts: a record of secular change. Int. Geol. Rev. 49, 193–234 (2007).
Moyen, J.-F., Stevens, G. & Kisters, A. Record of mid-Archaean subduction from metamorphism in the Barberton terrain, South Africa. Nature 442, 559 (2006).
Shirey, S. B. & Richardson, S. H. Start of the wilson cycle at 3 Ga shown by diamonds from subcontinental mantle. Science 333, 434–436 (2011).
Keller, B. & Schoene, B. Plate tectonics and continental basaltic geochemistry throughout Earth history. Earth Planet. Sci. Lett. 481, 290–304 (2018).
Dhuime, B., Hawkesworth, C. J., Cawood, P. A. & Storey, C. D. A change in the geodynamics of continental growth 3 billion years ago. Science 335, 1334–1336 (2012).
Dhuime, B., Wuestefeld, A. & Hawkesworth, C. J. Emergence of modern continental crust about 3 billion years ago. Nat. Geosci. 8, 552–555 (2015).
Tang, M., Chen, K. & Rudnick, R. L. Archean upper crust transition from mafic to felsic marks the onset of plate tectonics. Science 351, 372–375 (2016).
Smart, K. A., Tappe, S., Stern, R. A., Webb, S. J. & Ashwal, L. D. Early Archaean tectonics and mantle redox recorded in Witwatersrand diamonds. Nat. Geosci. 9, 255–259 (2016).
Greber, N. D. et al. Titanium isotopic evidence for felsic crust and plate tectonics 3.5 billion years ago. Science 357, 1271–1274 (2017).
Scott, D., Helmstaedt, H. & Bickle, M. Purtuniq ophiolite, Cape Smith belt, northern Quebec, Canada: a reconstructed section of Early Proterozoic oceanic crust. Geology 20, 173–176 (1992).
Peltonen, P., Kontinen, A. & Huhma, H. Petrology and geochemistry of metabasalts from the 1.95 Ga Jormua ophiolite, northeastern Finland. J. Petrol. 37, 1359–1383 (1996).
Weller, O. & St-Onge, M. Record of modern-style plate tectonics in the Palaeoproterozoic Trans-Hudson orogen. Nat. Geosci. 10, 305 (2017).
Xu, C. et al. Cold deep subduction recorded by remnants of a Paleoproterozoic carbonated slab. Nat. Commun. 9, 2790 (2018).
Ganne, J. et al. Modern-style plate subduction preserved in the Palaeoproterozoic West African craton. Nat. Geosci. 5, 60–65 (2012).
Condie, K. C. A planet in transition: the onset of plate tectonics on Earth between 3 and 2 Ga? Geosci. Front. 9, 51–60 (2018).
Condie, K. C., Aster, R. C. & van Hunen, J. A great thermal divergence in the mantle beginning 2.5 Ga: geochemical constraints from greenstone basalts and komatiites. Geosci. Front. 7, 543–553 (2016).
Condie, K. C. & O’Neill, C. The Archean-Proterozoic boundary: 500 My of tectonic transition in Earth history. Am. J. Sci. 310, 775–790 (2010).
Hermann, J. & Rubatto, D. Accessory phase control on the trace element signature of sediment melts in subduction zones. Chem. Geol. 265, 512–526 (2009).
Rudnick, R. L., Barth, M., Horn, I. & McDonough, W. F. Rutile-bearing refractory eclogites: missing link between continents and depleted mantle. Science 287, 278–281 (2000).
Xiao, Y. L. et al. Making continental crust through slab melting: constraints from niobium-tantalum fractionation in UHP metamorphic rutile. Geochim. Cosmochim. Acta 70, 4770–4782 (2006).
Farmer, G. L. in Treatise on Geochemistry 2nd edn (eds Heinrich D. Holland & Karl K. Turekian) p. 75–110 (Elsevier, Amsterdam, Netherlands 2014).
Holm, P. M., Søager, N., Alfastsen, M. & Bertotto, G. W. Subduction zone mantle enrichment by fluids and Zr–Hf-depleted crustal melts as indicated by backarc basalts of the Southern Volcanic Zone, Argentina. Lithos 262, 135–152 (2016).
Shaw, J. E., Baker, J. A., Menzies, M. A., Thirlwall, M. F. & Ibrahim, K. M. Petrogenesis of the largest intraplate volcanic field on the Arabian Plate (Jordan): a mixed lithosphere–asthenosphere source activated by lithospheric extension. J. Petrol. 44, 1657–1679 (2003).
Wilson, M. & Patterson, R. Intraplate magmatism related to short-wavelength convective instabilities in the upper mantle: evidence from the Tertiary-Quaternary volcanic province of western and central Europe. Spec. Pap.Geol. Soc. Ame. 352, 37–58 (2001).
Wu, K., Ling, M. X., Sun, W. D., Guo, J. & Zhang, C. C. Major transition of continental basalts in the Early Cretaceous: implications for the destruction of the North China Craton. Chem. Geol. 470, 93–106 (2017).
Zou, H., Zindler, A., Xu, X. & Qi, Q. Major, trace element, and Nd, Sr and Pb isotope studies of Cenozoic basalts in SE China: mantle sources, regional variations, and tectonic significance. Chem. Geol. 171, 33–47 (2000).
Walter, M. J. in Treatise on Geochemistry 2nd edn (eds Heinrich D. Holland & Karl K. Turekian) p. 393–419 (Elsevier, Amsterdam, Netherlands 2014).
Hirschmann, M. M., Kogiso, T., Baker, M. B. & Stolper, E. M. Alkalic magmas generated by partial melting of garnet pyroxenite. Geology 31, 481–484 (2003).
EarthChem. Portal Search www.earthchem.org/portal (2017).
Herzberg, C., Condie, K. & Korenaga, J. Thermal history of the Earth and its petrological expression. Earth Planet. Sci. Lett. 292, 79–88 (2010).
van Hunen, J. & van den Berg, A. P. Plate tectonics on the early Earth: limitations imposed by strength and buoyancy of subducted lithosphere. Lithos 103, 217–235 (2008).
Moyen, J.-F. & Martin, H. Forty years of TTG research. Lithos 148, 312–336 (2012).
Cawood, P. A. & Hawkesworth, C. J. Earth’s middle age. Geology 42, 503–506 (2014).
Foley, S. F., Buhre, S. & Jacob, D. E. Evolution of the Archaean crust by delamination and shallow subduction. Nature 421, 249–252 (2003).
van Hunen, J. & Moyen, J.-F. Archean subduction: fact or fiction? Annu. Rev. Earth Planet. Sci. 40, 195–219 (2012).
Condie, K. C., O’Neill, C. & Aster, R. C. Evidence and implications for a widespread magmatic shutdown for 250 My on Earth. Earth Planet. Sci. Lett. 282, 294–298 (2009).
Spencer, C. J., Murphy, J. B., Kirkland, C. L., Liu, Y. & Mitchell, R. N. A Palaeoproterozoic tectono-magmatic lull as a potential trigger for the supercontinent cycle. Nat. Geosci. 11, 97–101 (2018).
Partin, C. A. et al. Filling in the juvenile magmatic gap: Evidence for uninterrupted Paleoproterozoic plate tectonics. Earth Planet. Sci. Lett. 388, 123–133 (2014).
Cawood, P. A. & Buchan, C. Linking accretionary orogenesis with supercontinent assembly. Earth Sci. Rev. 82, 217–256 (2007).
Zhao, G., Sun, M., Wilde, S. A. & Li, S. A Paleo-Mesoproterozoic supercontinent: assembly, growth and breakup. Earth Sci. Rev. 67, 91–123 (2004).
Zhang, S. et al. Pre-Rodinia supercontinent Nuna shaping up: a global synthesis with new paleomagnetic results from North China. Earth Planet. Sci. Lett. 353–354, 145–155 (2012).
Keller, C. B. & Schoene, B. Statistical geochemistry reveals disruption in secular lithospheric evolution about 2.5 Gyr ago. Nature 485, 490–493 (2012).
Li, X.-H. et al. Petrogenesis and tectonic significance of the ∼850 Ma Gangbian alkaline complex in South China: evidence from in situ zircon U–Pb dating, Hf–O isotopes and whole-rock geochemistry. Lithos 114, 1–15 (2010).
Zhu, W.-G. et al. SHRIMP zircon U–Pb geochronology, elemental, and Nd isotopic geochemistry of the Neoproterozoic mafic dykes in the Yanbian area, SW China. Precambrian Res. 164, 66–85 (2008).
Amante, C. & Eakins, B. W. ETOPO1 arc-minute Global Relief Model: Procedures, Data Sources And Analysis. NOAA Technical Memorandum. Report No. NESDIS NGDC-24, 1–19 (National Geophysical Data Center, NOAA, Boulder, Colorado, 2009).
Yang, X.-M. Using the Rittmann Serial Index to define the alkalinity of igneous rocks. Neues Jahrb. für. Mineral. Abh. 184, 95–103 (2007).
Acknowledgements
C. Langmuir and A. W. Hofmann provided constructive suggestions for the texts and the statistical algorithm used in this paper. This study was supported by Strategic Priority Research Program of the Chinese Academy of Sciences, Grant No. XDB18020102, MOST of China 2016YFC0600408 and NSFC 41473029. H.L. was supported by an IOCAS Postdoctoral Fellowship.
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H.L. conducted the MATLAB coding and interpreted the results. W.D.S. contribute to the interpretation of results. H.L. wrote the manuscript with suggestions from all co-authors. M.T. improved the structure of the manuscript. R.Z. improved the English and contributed to the scientific presentation. All authors participated in further discussions.
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Liu, H., Sun, Wd., Zartman, R. et al. Continuous plate subduction marked by the rise of alkali magmatism 2.1 billion years ago. Nat Commun 10, 3408 (2019). https://doi.org/10.1038/s41467-019-11329-z
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DOI: https://doi.org/10.1038/s41467-019-11329-z
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