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Alkylation of 1-Dodecene with Benzene over H3PW12O40 Supported on Mesoporous Silica SBA-15

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Abstract

The SBA-15 supported 12-phosphotungstic acid catalysts were prepared and measured in the alkylation of benzene with 1-dodecene at the atmospheric batch reactor. It is found that the catalysts exhibit much higher catalytic activity, selectivity and stability than HY zeolite in this reaction at the reaction temperature of 80 °C, with the 1-dodecene conversion of nearly 90%, 2-phenyldodecane selectivity of nearly 40%, and monoalkylbenzene selectivity of 100%.

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References

  1. J.A. Kocal, B.V. Vora and T. Imai, Appl. Catal. A: Gen. 221 (2001) 295.

    Google Scholar 

  2. C. Perego and P. Ingallina, Catal. Today 73 (2002) 3.

    Google Scholar 

  3. S. Sivasanker and A. Thangaraj, J. Catal. 138 (1992) 386.

    Google Scholar 

  4. Y. Cao, R. Kessas, C. Naccache and Y. Ben Taarit, Appl. Catal. A: Gen. 184 (1999) 231.

    Google Scholar 

  5. X.D. Yuan, J.N. Park, J. Wang, C.W. Lee and S.E. Park, Korean J. Chem. Eng. 19 (2002) 607.

    Google Scholar 

  6. N. Mizuno and M. Misono, Chem. Rev. 98 (1998) 199.

    Google Scholar 

  7. J. Kaur and I.V. Kozhevnikov, Chem. Commun. (2002) 2508.

  8. A. Ghanbari-Siahkali, A. Philippou, J. Dwyer and M.W. Anderson, Appl. Catal. A: General 192 (2000) 57.

    Google Scholar 

  9. C. Trolliet, G. Coudurier and J.C. Védrine, Top. Catal. 15 (2001) 73.

    Google Scholar 

  10. R.T. Sebulsky and A.M. Henke, Ind. Eng. Chem. Process Des. Dev. 10 (1971) 272.

    Google Scholar 

  11. D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka and G.D. Stucky, Science 279 (1998) 548.

    Google Scholar 

  12. P.B. Venuto, L.A. Hamilton and P.S. Landis, J. Catal. 5 (1960) 21.

    Google Scholar 

  13. A.C. Olson, Ind. Eng. Chem. 52 (1960)833.

    Google Scholar 

  14. W. Liang, Y. Jin, Z. Yu, Z. Wang, B. Han, M. He and E. Min, Zeolites 17 (1996) 297.

    Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing, 210009, P.R. China

    Jun Wang & Hai-Ou Zhu

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  1. Jun Wang
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  2. Hai-Ou Zhu
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Correspondence to Jun Wang.

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Wang, J., Zhu, HO. Alkylation of 1-Dodecene with Benzene over H3PW12O40 Supported on Mesoporous Silica SBA-15. Catalysis Letters 93, 209–212 (2004). https://doi.org/10.1023/B:CATL.0000017078.26948.b4

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  • DOI: https://doi.org/10.1023/B:CATL.0000017078.26948.b4

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