Skip to main content
Log in

Constantin Carathéodory and the axiomatic thermodynamics

  • Published:
Journal of Mathematical Chemistry Aims and scope Submit manuscript

Abstract

The birth, raise, development and fortunes of a fundamental theory in thermodynamics, the axiomatic thermodynamics, a creation of Constantin Carathéodory, is thoroughly presented together with a summary of Carathéodory's biography. Axiomatic thermodynamics is centered around some interesting properties of Pfaffian differential equations, which are here introduced and used for some well-known cases in thermodynamics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. O. Perron, Constantin Carathéodory, Jahresbericht der Deutschen Mathematikvereinigung 55 (1952) 39-41.

    Google Scholar 

  2. M. Born, Kritische Betrachtungen zur traditionellen Darstellung der Thermodynamik, Physik Z. 22 (1921) 218-224.

    Google Scholar 

  3. M. Born, Kritische Betrachtungen zur traditionellen Darstellung der Thermodynamik, Physik Z. 22 (1921) 249-254.

    Google Scholar 

  4. M. Born, Kritische Betrachtungen zur traditionellen Darstellung der Thermodynamik, Physik Z. 22 (1921) 282-286.

    Google Scholar 

  5. A. Landé, Handbuch der Physik, Vol. 9 (Springer, Berlin, 1926) chapter 4.

    Google Scholar 

  6. M. Planck, Ñber die Begrundung des zweiten Hauptsatzes der Thermodynamik, S.B. Akad. Wiss. 53 (1926) 453-463.

    Google Scholar 

  7. S. Chandresekhar, An Introduction to Stellar Structure (Chicago, 1939) chapter 1, p. 11.

  8. W. Pauli, Termodinamica e Teoria Cinetica dei Gas (Boringhieri, Torino, 1967) pp. 32-41, Italian version of Vorlesungen über Thermodynamik und Kinetische Gastheorie, Lectures of W. Pauli at the ETH of Zürich collected by E. Jucker (1958).

    Google Scholar 

  9. M.W. Zemansky and R.H. Dittman, Heat and Thermodynamics (McGraw-Hill, Singapore, 1981) pp. 164-181.

    Google Scholar 

  10. H. Margenau and G.M. Murphy, The Mathematics of Physics and Chemistry (Van Nostrand, Princeton, 1968) pp. 26-30.

    Google Scholar 

  11. H.B. Callen, Thermodynamics and Introduction to Thermostatistics (Wiley, New York, 1985) pp. 27 and 48.

    Google Scholar 

  12. B. Bamberg and S. Sternberg, A Course in Mathematics for Students of Physics, Vol. 2 (Cambridge University Press, New York, 1996) chapter 22.

    Google Scholar 

  13. G.N. Lewis and M. Randall Thermodynamics, revised by K.S. Pitzer and L. Brewer) (McGraw-Hill, New York, 1961).

    Google Scholar 

  14. H.A. Buchdahl, On the principle of Carathéodory, Am. J. Phys. 17 (1949) 41-43.

    Google Scholar 

  15. H.A. Buchdahl, On the theorem of Carathéodory, Am. J. Phys. 17 (1949) 44-46.

    Google Scholar 

  16. H.A. Buchdahl, On the unrestricted theorem of Carathéodory and its applications in the treatment of the second law of thermodynamics, Am. J. Phys. 17 (1949) 212-218.

    Google Scholar 

  17. H.A. Buchdahl, Integrability conditions and Carathéodory's theorem, Am. J. Phys. 22 (1954) 182-183.

    Google Scholar 

  18. H.A. Buchdahl, Simplification of a proof of Carathéodory's theorem, Am. J. Phys. 23 (1955) 65-66.

    Google Scholar 

  19. H.A. Buchdahl, The Concepts of Classical Thermodynamics (Cambridge University Press, London, 1966).

    Google Scholar 

  20. H.A. Buchdahl, An Introduction to Hamiltonian Optics (Dover, New York, 1970).

    Google Scholar 

  21. A.B. Pippard, Elements of Classical Thermodynamics (Cambridge University Press, New York, 1957) p. 38.

    Google Scholar 

  22. L.A. Turner, Simplification of Carathéodory's treatment of thermodynamics, Am. J. Phys. 28 (1960) 781-786.

    Google Scholar 

  23. F.W. Sears, A simplified simplification of Carathéodory's treatment of thermodynamics, Am. J. Phys. 31 (1963) 747-752.

    Google Scholar 

  24. P.T. Landsberg, A deduction of Carathéodory's principle from Kelvin's principle, Nature 201 (1964) 485-486.

    Google Scholar 

  25. A.B. Pippard, Response and Stability: An Introduction to the Physical Theory (Cambridge University Press, London, 1985).

    Google Scholar 

  26. P.T. Landsberg, A.N. Tikhonov and P.T. Landberg, Thermodynamics and Statistical Mechanics (Dover, New York, 1991).

    Google Scholar 

  27. P.T. Landsberg, ed., The Enigma of Time (Hilger, London, 1983).

    Google Scholar 

  28. F.W. Sears, An Introduction to Thermodynamics, the Kinetic Theory of Gases, and Statistical Mechanics, 2nd edition (Addison-Wesley, Reading, MA, 1953).

    Google Scholar 

  29. F.W. Sears and G.L. Salinger, Thermodynamics, Kinetic Theory and Statistical Mechanics, 3rd edition (Addison-Wesley, Reading, MA, 1976).

    Google Scholar 

  30. P.T. Landsberg, Foundations of thermodynamics, Rev. Mod. Phys. 28 (1956) 363-392.

    Google Scholar 

  31. T.W. Marshall, A simplified version of Carathéodory thermodynamics, Am. J. Phys. 46 (1978) 136-137.

    Google Scholar 

  32. P.T. Landsberg, The Born Centenary: Remarks about classical thermodynamics, Am. J. Phys. 51 (1983) 842-845.

    Google Scholar 

  33. G. Laufer, Work and heat in the light of (thermal and laser) light, Am. J. Phys. 51 (1983) 42-43.

    Google Scholar 

  34. R. Giles, Mathematical Foundations of Thermodynamics (Pergamon, New York, 1964).

    Google Scholar 

  35. L. Tisza, Generalized Thermodynamics (MIT Press, Cambridge, 1966).

    Google Scholar 

  36. L. Tisza, Thermodynamics in a State of Flux. A Search for New Foundations, A Critical Review of Thermodynamics (Mono Book, Baltimore, 1970).

    Google Scholar 

  37. O. Redlich, The Basis of Thermodynamics, A Critical Review of Thermodynamics (Mono Book, Baltimore, 1970).

    Google Scholar 

  38. J.P. Peixoto, Dualidade em Termodinâmica, Memörias da Academia das Ciências de Lisboa 16 (1972) 311-372 (in Portuguese).

    Google Scholar 

  39. M. Bunge, Philosophy of Physics (Reidel, Dordrecht, 1973).

    Google Scholar 

  40. M. Kline, Mathematics and the Physical World (Dover, New York, 1981).

    Google Scholar 

  41. M.W. Zemansky, Heat and Thermodynamics (McGraw-Hill/Kogakuscha, Tokyo, 1968).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pogliani, L., Berberan-Santos, M.N. Constantin Carathéodory and the axiomatic thermodynamics. Journal of Mathematical Chemistry 28, 313–324 (2000). https://doi.org/10.1023/A:1018834326958

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1018834326958

Navigation