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Corrosion Resistance and Semiconducting Properties of Passive Films Formed on 00Cr13Ni5Mo2 Supermartensitic Stainless Steel in Cl− Environment

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Abstract

The semiconducting properties of passive films grown on 00Cr13Ni5Mo2 supermartensitic stainless steel were investigated in comparison with conventional 2Cr13 martensitic stainless steel. Cyclic voltammetry and electrochemical impedance spectroscopy (EIS) were used for the studies. 00Cr13Ni5Mo2 steel exhibited a good corrosion resistance performance, attributing to its passive capability. The results of Mott-Schottky analysis demonstrated n-type semiconductors for the passive films with doping densities of about 1020–1021 cm−3, and the thickness of space-charge layers was also calculated. The experimental results confirmed that Mo plays an important role in improving the corrosion resistance of 00Cr13Ni5Mo2 steel due to its impact on the doping density.

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Authors and Affiliations

  1. School of Metallurgy and Engineering, Xi’an University of Architecture and Technology, Xi’an, Shaanxi, 710055, China

    De-ning Zou (Doctor, Professor), Rong Liu, Jiao Li & Duo Wang

  2. State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an, Shaanxi, 710049, China

    Wei Zhang & Ying Han (Doctor)

  3. Key Laboratory of Advanced Structural Materials of Ministry of Education, Changchun University of Technology, Changchun, Jilin, 130012, China

    Ying Han (Doctor)

Authors
  1. De-ning Zou
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  2. Rong Liu
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  3. Jiao Li
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  4. Wei Zhang
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  5. Duo Wang
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  6. Ying Han
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Correspondence to Ying Han.

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Foundation Item: Item Sponsored by Science and Technology Projects from Xi’an City of China (CX1261➄); Fund of State Key Laboratory of Solidification Processing in NWPU of China (SKLSP201322)

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Zou, Dn., Liu, R., Li, J. et al. Corrosion Resistance and Semiconducting Properties of Passive Films Formed on 00Cr13Ni5Mo2 Supermartensitic Stainless Steel in Cl− Environment. J. Iron Steel Res. Int. 21, 630–636 (2014). https://doi.org/10.1016/S1006-706X(14)60098-4

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  • DOI: https://doi.org/10.1016/S1006-706X(14)60098-4

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