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Highly efficient determination of metal ion in cosmetic samples by reversed-phase liquid–liquid microextraction based on green hydrophobic deep eutectic solvent

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Abstract

In this paper, a green hydrophobic deep eutectic solvent (HDES) composed of menthol and hexanoic acid was employed to dissolve cosmetics containing Cd2+ and Cd2+ was extracted using an EDTA-2Na saturated solution, analyzed by FAAS. The study found that HDES-1 can be recycled and reused well; the stability constants of Cd2+ EDTA chelates play an important role in the extracting process; the optimum conditions were: the solubility of HDES-1 was 20 mL/g for cosmetic sample at an indoor temperature of around 10 °C; the dissolver–extractant ratio was 2:1; the LOD was 0.037 mg/kg; the RSD was 3.5%; and the recovery was 85.5–118.3%. The developed method was successfully applied to actual cosmetic samples with satisfactory results, and it was also applied for the determination of Mg2+, Mn2+, and Cu2+ in cosmetic samples.

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Authors and Affiliations

  1. Hunan Electronic Information Industry Institute, Jiefangdonglu 51, Changsha, 410000, Hunan, People’s Republic of China

    Bangfu Liu

  2. Hunan Prevention and Treatment Institute for Occupational Disease, Changsha, 410007, Hunan, People’s Republic of China

    Le-zhou Zhou

  3. College of Materials and Chemical Engineering, Hunan City University, Yiyang, 413000, Hunan, People’s Republic of China

    Guo-wen He

  4. Department of Pharmacy, Air Force Military Medical University, Xi’an, 710000, Shanxii, People’s Republic of China

    Chaoli Wang

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  1. Bangfu Liu
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  2. Le-zhou Zhou
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Correspondence to Bangfu Liu.

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Liu, B., Zhou, Lz., He, Gw. et al. Highly efficient determination of metal ion in cosmetic samples by reversed-phase liquid–liquid microextraction based on green hydrophobic deep eutectic solvent. ANAL. SCI. 40, 115–121 (2024). https://doi.org/10.1007/s44211-023-00437-y

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