Skip to main content
SpringerLink
Log in

Eu(III) transfer in single N,N,N’,N’-tetraoctyldiglycolamide-impregnated polymer-coated silica particle using fluorescence microspectroscopy: transfer mechanism and effect of polymer crosslinking degree

  • Original Paper
  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

A microcapillary manipulation system combined with fluorescence microspectroscopy enabled us to analyze mass transfer in a single particle. In this study, we revealed the Eu(III) distribution in a single diglycolamide-derivative extractant (TODGA)-impregnated polymer-coated silica particle. The reaction of Eu(III) with two TODGA molecules in the polymer layer was the rate-limiting process, which was revealed by the relationship between the rate constants (k1 and k-1) and concentrations of Eu(III) and HNO3. The decrease in the crosslinking degree of the polymer layer caused an increase in only k-1. This indicates that hydrophilic environments at lower crosslinking degrees enhance the stability of the charged Eu(III) species such as Eu3+, Eu(NO3)2+, and Eu(NO3)2+.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

Data availability

We do not share the data presented in this paper.

References

  1. W. Piątkowski, D. Antos, K. Kaczmarski, J. Chromatogr. A 988, 219–231 (2003)

    Article  PubMed  Google Scholar 

  2. G. Guichon, J. Chromatogr. A 965, 129–161 (2002)

    Article  Google Scholar 

  3. R. K. Lindsey, J. L. Rafferty, B. L. Eggimann, J. I. Siepmann, M. R. Schure, J Chromatogr. A 1287, 60–82 (2013)

  4. A.M. Dolgonosov, A.G. Prudkovskii, E.A. Zaitseva, N.K. Kolotilina, A.A. Dolgonosov, J. Anal. Chem. 76, 1233–1244 (2021)

    Article  CAS  Google Scholar 

  5. M. Goto, B.J. McCoy, Chem. Eng. Sci. 59, 2105–2111 (2004)

    Article  CAS  Google Scholar 

  6. T. Sato, K. Nakatani, Anal. Sci. 33, 179–183 (2017)

    Article  CAS  PubMed  Google Scholar 

  7. K. Nakatani, T. Sekine, Langmuir 16, 9256–9260 (2000)

    Article  CAS  Google Scholar 

  8. K. Nakatani, E. Matsuta, Anal. Sci. 31, 557–560 (2015)

    Article  CAS  PubMed  Google Scholar 

  9. A. Miyagawa, S. Nagatomo, H. Kazami, T. Terada, K. Nakatani, Langmuir 37, 12697–12704 (2021)

    Article  CAS  PubMed  Google Scholar 

  10. T. Sato, K. Hata, K. Nakatani, Anal. Sci. 33, 647–650 (2017)

    Article  CAS  PubMed  Google Scholar 

  11. F. Xie, T.A. Zhang, D. Dreisinger, F. Doyle, Miner. Eng. 56, 10–28 (2014)

    Article  CAS  Google Scholar 

  12. B.J. Mincher, G. Modolo, S.P. Mezyk, Solvent Extr. Ion Exch. 27, 579–606 (2009)

    Article  CAS  Google Scholar 

  13. A.V. Mudring, S. Tang, Eur. J. Inorg. Chem. 2010, 2569–2581 (2010)

    Article  Google Scholar 

  14. I. Kumari, B.V.R. Kumar, A. Khanna, Nucl. Eng. Design 358, 110410 (2020)

    Article  CAS  Google Scholar 

  15. A. Khayambashi, Q. Shu, Y. Wei, F. Tang, L. He, J. Radioanal. Nucl. Chem. 316, 221–231 (2018)

    Article  CAS  Google Scholar 

  16. M. H. Abdul Rahaman, M. U. Khandaker, Z. R. Khan, M. Z. Kufian, I. S. Noor, A. K. Arof, Phys. Chem. Chem. Phys. 16, 11527–11537 (2014)

  17. T. Otaka, T. Sato, S. Ono, K. Nagoshi, R. Abe, T. Arai, S. Watanabe, Y. Sano, M. Takeuchi, K. Nakatani, Anal. Sci. 35, 1129–1133 (2019)

    Article  CAS  PubMed  Google Scholar 

  18. V. Kumar, A. Kumar, S. Mondal, J.N. Sharma, R.C. Hubli, P.K. Wattal, A.K. Suri, Sep. Purif. Technol. 98, 118–122 (2012)

    Article  CAS  Google Scholar 

  19. S.A. Ansari, P.K. Mohapatra, V.K. Manchanda, Ind. Eng. Chem. Res. 48, 8605–8612 (2009)

    Article  CAS  Google Scholar 

  20. S.A. Ansari, P.N. Pathak, M. Husain, A.K. Prasad, V.S. Parmar, V.K. Manchanda, Radiochim. Acta 94, 307–312 (2006)

    Article  CAS  Google Scholar 

  21. A. Miyagawa, M. Takeuchi, T. Arai, S. Watanabe, Y. Sano, K. Nakatani, Bull. Chem. Soc. Jpn. 95, 566–568 (2022)

    Article  CAS  Google Scholar 

  22. P.N. Pathak, S.A. Ansari, S.V. Godbole, A.R. Dhobale, V.K. Manchanda, Spectrochim. Acta A 73, 348–352 (2009)

    Article  CAS  Google Scholar 

  23. K. Nakatani, T. Uchida, N. Kitamura, H. Masuhara, J. Electroanal. Chem. 375, 383–386 (1994)

    Article  CAS  Google Scholar 

  24. K. Nakatani, M. Wakabayashi, K. Chikama, N. Kitamura, J. Phys. Chem. 100, 6749–6754 (1996)

    Article  CAS  Google Scholar 

  25. T.H. Vu, J.-P. Simonin, A.L. Rollet, R.J.M. Egberink, W. Verboom, M.C. Gullo, A. Casnati, Ind. Eng. Chem. Res. 59, 13477–13490 (2020)

    Article  CAS  Google Scholar 

  26. B. Bujalski, F.F. Cantwell, Langmuir 17, 7710–7711 (2001)

    Article  CAS  Google Scholar 

  27. E.M. Rekin, J. Gen. Physiol. 38, 225–243 (1954)

    Google Scholar 

  28. A. Miyagawa, N. Hayashi, Y. Kuzure, T. Takahashi, H. Iwamoto, T. Arai, S. Nagatomo, Y. Miyazaki, Y. Sano, K. Nakatani, Bull. Chem. Soc. Jpn. (2023). https://doi.org/10.1246/bcsj.20230087

    Article  Google Scholar 

Download references

Acknowledgements

The authors received no financial support for this study. The SEM image was obtained using electron probe micro analyzer at the Chemical Analysis Division and Open Facility, Research Facility Center for Science and Technology, University of Tsukuba.

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki, 305-8571, Japan

    Akihisa Miyagawa, Takumi Takahashi, Yoshiaki Kuzure, Shigenori Nagatomo & Kiyoharu Nakatani

  2. Shibaura Institute of Technology, Toyosu, Tokyo, 135-8548, Japan

    Hibiki Iwamoto & Tsuyoshi Arai

  3. Japan Atomic Energy Agency, Tokai-Mura, Ibaraki, 319-1194, Japan

    Sou Watanabe & Yuichi Sano

Authors
  1. Akihisa Miyagawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Takumi Takahashi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yoshiaki Kuzure
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hibiki Iwamoto
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Tsuyoshi Arai
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Shigenori Nagatomo
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Sou Watanabe
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Yuichi Sano
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Kiyoharu Nakatani
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Kiyoharu Nakatani.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 465 KB)

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Miyagawa, A., Takahashi, T., Kuzure, Y. et al. Eu(III) transfer in single N,N,N’,N’-tetraoctyldiglycolamide-impregnated polymer-coated silica particle using fluorescence microspectroscopy: transfer mechanism and effect of polymer crosslinking degree. ANAL. SCI. 39, 1929–1936 (2023). https://doi.org/10.1007/s44211-023-00402-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s44211-023-00402-9

Keywords

Search

Navigation