Abstract
This study experimentally investigated the variations in pore structure, mechanical property and permeability of concrete under sulfate attack exposed to freeze–thaw cycles, and examined the relationship between pore structure, stress, and permeability. The results indicate that before 10 cycles, the original pores in the specimen are filled with the reaction products of sulfate and concrete matrix. Compared with the specimen at 0 cycles, it is denser with a reduction in T2 area, an increase in peak stress, and a decrease in initial permeability. With the increase in the number of cycles, the accumulation and expansion of ettringite and gypsum in the product lead to the subsequent enlargement of pores, more liquid enters the interior of the specimen, and the frost heave effect caused by the freeze–thaw dominates. Therefore, the mesopores and macropores in the specimen are developed, the fractal dimension is reduced, and the T2 area is increased. Macroscopically, the peak stress decreases and the initial permeability increases. Besides, the existence of hydraulic pressure weakens the mechanical properties (peak stress and deformation modulus) of the specimen, increases the lateral deformation and improves the permeability.
Similar content being viewed by others
Data availability
All data generated or used during the study are included in the submitted article.
References
Liu L, Qin SN, Wang XC. Poro-elastic–plastic model for cement-based materials subjected to freeze–thaw cycles. Constr Build Mater. 2018;184:87–99. https://doi.org/10.1016/j.conbuildmat.2018.06.197.
Zhang MH, Li H. Pore structure and chloride permeability of concrete containing nano-particles for pavement. Constr Build Mater. 2011;25(2):608–16. https://doi.org/10.1016/j.conbuildmat.2010.07.032.
Wen DY, Jiang NS, Liu CK, Lv ZQ. Study of the influence of temperature rise on the microstructure of frozen soil based on SEM and MIP. J Mater Civil Eng. 2023;35(5):05023001. https://doi.org/10.1061/(ASCE)MT.1943-5533.0004721.
Tang M, Li JQ. Research on fractal characteristics of cement-based materials by nitrogen adsorption method. Adv Mater. 2012;415:1545–52. https://doi.org/10.4028/www.scientific.net/AMR.415-417.1545.
Chen JH, Li YL, Zhou H, Li Y, Guo HY. NMR study on concrete pore structure evolution under different curing environments. Jom. 2022;74(5):1819–27. https://doi.org/10.1007/s11837-022-05221-3.
Ni HY, Liu JF, Huang BX, Pu H, Meng QB, Wang YG, Sha ZH. Quantitative analysis of pore structure and permeability characteristics of sandstone using SEM and CT images. J Nat Gas Sci Eng. 2021;88: 103861. https://doi.org/10.1016/j.jngse.2021.103861.
LaManna JM, Bothe JV Jr, Zhang FY, Mench MM. Measurement of capillary pressure in fuel cell diffusion media, micro-porous layers, catalyst layers, and interfaces. J Power Sources. 2014;271:180–6. https://doi.org/10.1016/j.jpowsour.2014.07.163.
Clarkson CR, Solano N, Bustin RM, Bustin AMM, Chalmers GRL, He L, Melnichenko YB, Radlinski AP, Blach TP. Pore structure characterization of North American shale gas reservoirs using USANS/SANS, gas adsorption, and mercury intrusion. Fuel. 2013;103:606–16. https://doi.org/10.1016/j.fuel.2012.06.119.
Nakashima Y, Mitsuhata Y, Nishiwaki J, Kawabe Y, Utszawa S, Jinguuji M. Non-destructive analysis of oil-contaminated soil core samples by X-ray computed tomography and low-field nuclear magnetic resonance relaxometry: a case study. Water Air Soil Poll. 2011;21(4):681–98. https://doi.org/10.1007/s11270-010-0473-2.
Tian W, Xie YL, Dang FN. Experimental study of meso-damage mechanism of concrete under freezing-thawing environment based on CT technology. Eng J Wuhan Univ. 2016;49(3):397–401. https://doi.org/10.14188/j.1671-8844.2016-03-013.
Liu L, He Z, Cai XH, Fu SJ. Application of low-field NMR to the pore structure of concrete. Appl Magn Reson. 2021;52:15–31. https://doi.org/10.1007/s00723-020-01229-7.
Han YJ, Zhou CC, Fan YR, Li CL, Chao C, Cong YH. A new permeability calculation method using NMR logging based on pore sizes: a case study of bioclastic limestone reservoirs in the a oilfield of the mid-east. Petrol Explor Dev. 2018;45(1):183–92. https://doi.org/10.1016/S1876-3804(18)30019-3.
Xue HJ, Zheng JT, Zhou CX, Hou YF, Liu X. Fractal characteristics of pore structure of aeolian sand pumice concrete subjected to freeze-thaw cycles. Ind Const. 2022;52(01):187–93+142. https://doi.org/10.13204/j.gyjzg21090911.
Luo X, Cheng YY, Tan CQ. Calculation method of equivalent permeability of dual-porosity media considering fractal characteristics and fracture stress sensitivity. J Pet Explor Prod Te. 2023. https://doi.org/10.1007/S13202-023-01640-3.
Miah MJ, Kallel H, Carré H, Pimienta P, Borderie CL. The effect of compressive loading on the residual gas permeability of concrete. Constr Build Mater. 2019;217:12–9. https://doi.org/10.1016/j.conbuildmat.2019.05.057.
Li D, Liu S. The influence of steel fiber on water permeability of concrete under sustained compressive load. Constr Build Mater. 2020;242: 118058. https://doi.org/10.1016/j.conbuildmat.2020.118058.
Jiang X, Li QH, Yin X, Xu SL. Investigation on triaxial compressive mechanical properties of ultra high toughness cementitious composites with high strain capacity. Cement Concrete Res. 2023;170: 107185. https://doi.org/10.1016/j.cemconres.2023.107185.
Xue WP, Liu XY, Jing W, Yao ZS, Gao C, Li HP. Experimental study and mechanism analysis of permeability sensitivity of mechanically damaged concrete to confining pressure. Cement Concrete Res. 2020;134: 106073. https://doi.org/10.1016/j.cemconres.2020.106073.
Liu XL, Liu SF, Qin BD. Experimental study on strength and deformation feature of hybrid fiber high-strength concrete under conventional triaxial compression. Nat Sci. 2013;32(2):225–9. https://doi.org/10.16186/j.cnki.1673-9787.2013.02.015.
Yuan J, Huang X, Chen X, Ge Q, Zhang ZC. Early-age mechanical properties and hydration degrees of magnesium phosphate cement paste in freezing winter of cold regions. Constr Build Mater. 2022;345: 128337. https://doi.org/10.1016/j.conbuildmat.2022.128337.
Si W, Li N, Ma B, Ren JP, Wang HN. Impact of freeze-thaw cycles on compressive characteristics of asphalt mixture in cold regions. J Wuhan Univ Technol. 2015;30(4):703–9. https://doi.org/10.1007/s11595-015-1215-5.
Cao JR, Ding QJ, Hou DS, Xiong CS, Jin ZQ, Zhang GZ. Influence of hoop restraint on microstructure and phase composite of cement paste filled steel tube under external sulfate attack. J Build Eng. 2023;366: 130195. https://doi.org/10.1016/j.conbuildmat.2022.130195.
Han M, Yang SY, Chen XL, Kong J, Song JJ, Xu PP. Influence of sulfate dry-wet cycle and freeze-thaw compound action on the mechanical properties of concrete. Concrete. 2023;8:66–71. https://doi.org/10.3969/j.issn.1002-3550.2023.08.013.
Yang SY, Han M, Chen XL, Song JJ, Yang JS. Effect of sulfate crystallization on uniaxial compressive behavior of concrete subjected to combined actions of dry–wet and freeze–thaw cycles. J Cold Reg Eng. 2023;37(1):04022015. https://doi.org/10.1061/JCRGEI.CRENG-666.
Sabih G, Tarefder RA, Jamil SM. Optimization of gradation and fineness modulus of naturally fine sands for improved performance as fine aggregate in concrete, Proce. Eng. 2016;145:66–73. https://doi.org/10.1016/j.proeng.2016.04.016.
Xue WP, Yao ZS, Jing W, Tang B, Kong G, Wu H. Experimental study on permeability evolution during deformation and failure of shaft lining concrete. Constr Build Mater. 2019;195:564–73. https://doi.org/10.1016/j.conbuildmat.2018.11.101.
Camarini G. Curing effects on air permeability of concrete. Adv Mat Res. 2011;214:602–6. https://doi.org/10.4028/www.scientific.net/AMR.214.602.
F. Wang, Study on mechanical properties and damage mechanism ofcarbon nanotube concrete under coupling of sulfate attackand freeze-thaw cycles. Xi’an: Chang’an University; 2020.
Rahul K, Verma M, Dev N. Investigation on the effect of seawater condition, sulphate attack, acid attack, freeze–thaw condition, and wetting–drying on the geopolymer concrete IJST-T. Civ Eng. 2022;46:2823–53. https://doi.org/10.1007/s40996-021-00767-9.
Dong JG, Lyu HB, Xu GY. NMR based quantification of pore water distribution in unsaturated soils. Transp Geotech. 2023;38: 100922. https://doi.org/10.1016/j.trgeo.2022.100922.
Gao YL, Li T, Zhang ZG, Yu J, Zhang YK, Li X, Zhao H. Research on fluid mobility in tight-sandstone with a NMR fractal theory pore classification method. Front Earth Sc-Switz. 2023;10:1035702. https://doi.org/10.3389/feart.2022.1035702.
Zhang LM, Jiang SQ, Yu J. Experimental research into the evolution of permeability of sandstone under triaxial compression. Energies. 2020;13(19):5065. https://doi.org/10.3390/en13195065.
Xue WP, Xu LF, Wang ZJ, Tong M, Xu J. Experimental study on seepage evolution and microscopic characteristics of initially damaged concrete under variable confining pressure. Constr Build Mater. 2023;393: 132157. https://doi.org/10.1016/j.conbuildmat.2023.132157.
Ghosh R, Lahoti M, Shah B. A succinct review on the use of NMR spectroscopy in monitoring hydration, strength development, and inspection of concrete. Mater Today: Proc. 2022;61:167–73. https://doi.org/10.1016/j.matpr.2021.07.433.
Wu F, Xi YP, Fan QH, Yao C, Cong LL, Zhang FS, Kuang Y. Influence of spatial distribution of pores on NMR transverse relaxation time in pebbly sandstone. J Magn. 2019;24(4):704–16. https://doi.org/10.4283/JMAG.2019.24.4.704.
Zhao Y, Wang CL, Lin N, Zhao HF, Bi J. Pore and fracture development in coal under stress conditions based on NMR and fractal theory. Fuel. 2022;309: 122112. https://doi.org/10.1016/j.fuel.2021.122112.
Bayraktar Y, Kaplan G, Gencel O, Benli A, Sutcu M. Physico-mechanical, durability and thermal properties of basalt fiber reinforced foamed concrete containing waste marble powder and slag. Constr Build Mater. 2021;288:123128. https://doi.org/10.1016/j.conbuildmat.2021.123128.
Wang CH, Xiao J, Long CY, Zhang QG, Shi JY, Zhang ZD. Influences of the joint action of sulfate erosion and cementitious capillary crystalline waterproofing materials on the hydration products and properties of cement-based materials: a review. J Build Eng. 2023. https://doi.org/10.1016/j.jobe.2023.106061.
Horpibulsuk S, Rachan R, Raksachon Y. Role of fly ash on strength and microstructure development in blended cement stabilized silty clay. Soils Found. 2009;49(1):85–98. https://doi.org/10.3208/sandf.49.85.
Yao YZ, Liu C, Liu HW, Zhang W, Hu TF. Deterioration mechanism understanding of recycled powder concrete under coupled sulfate attack and freeze–thaw cycles. Constr Build Mater. 2023;388: 131718. https://doi.org/10.1016/j.conbuildmat.2023.131718.
Liu Z, Wang WY, Cheng WM, Yang H, Zhao DW. Study on the seepage characteristics of coal based on the kozeny-carman equation and NMR experiment. Fuel. 2020;266: 117088. https://doi.org/10.1016/j.fuel.2020.117088.
Hu YB, Guo YH, Zhang JJ, ShangGuan JW, Li M, Quan FK, Li GL. A method to determine NMR T2 cutoff value of tight sandstone reservoir based on multifractal analysis. Energy Sci Eng. 2020;8(4):1135–48. https://doi.org/10.1002/ese3.574.
Liu Y, Deng HW. Study on permeability performance of cemented tailings backfill based on fractal characteristics of pore structure. Constr Build Mater. 2023;365: 130035. https://doi.org/10.1016/j.conbuildmat.2022.130035.
Xue WP, Li HP, Yao ZS, Peng SL, Liu XY. Theoretical solutions to critical water inrush pressure in vertical shaft lining under the influence of brittle damage and hydraulic coupling. Int J Min Eng. 2019;36(3):566.
Chen X, Yu J, Tang CA, Li H, Wang SY. Experimental and numerical investigation of permeability evolution with damage of sandstone under triaxial compression. Rock Mech Rock Eng. 2017;50:1529–49. https://doi.org/10.1007/s00603-017-1169-3.
Zhao YL, Tang JZ, Chen Y, Zhang LY, Wang WJ, Wan W, Liao JP. Hydromechanical coupling tests for mechanical and permeability characteristics of fractured limestone in complete stress–strain process. Environ Earth Sci. 2017;76:1–18. https://doi.org/10.1007/s12665-016-6322-x.
Du YT, Li TC, Li WT, Ren YD, Wang G, He P. Experimental study of mechanical and permeability behaviors during the failure of sandstone conaining two preexisting fissures under triaxial compression. Rock Mech Rock Eng. 2020;53:3673–97. https://doi.org/10.1007/s00603-020-02119-x.
Funding
This study was funded by National Natural Science Foundation of China (52308228), Anhui Provincial Natural Science Foundation (2208085ME146, 2208085QE142), Chunhui Project Foundation of the Education Department of China (HZKY20220204), Research Foundation of the Institute of Environment-friendly Materials and Occupational Health (Wuhu), Anhui University of Science and Technology (ALW2021YF14), Independent Research Fund of the State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal Mines (Anhui University of Science and Technology) (SKLMRDPC20ZZ05), Science and Technology Plan Project of the Housing Urban and Rural Construction in Anhui Province (2021-YF58), The Opening Foundation of Engineering Research Center of Underground Mine Construction, Ministry of Education (Anhui University of Science and Technology) (JYBGCZX2020102), The China Scholarship Council(202108340040).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Ethical approval
This article does not contain any studies with human participants performed by any of the authors.
Informed consent
Informed consent was obtained from all individual participants included in the study.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Xue, W., Peng, X., Alam, M.S. et al. Pore structure, mechanical property and permeability of concrete under sulfate attack exposed to freeze–thaw cycles. Archiv.Civ.Mech.Eng 24, 130 (2024). https://doi.org/10.1007/s43452-024-00944-3
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s43452-024-00944-3