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Effect of sintering temperature on nonlinearity and surge degradation characteristics of Mn3O4/Nb2O5/Er2O3-doped ZnO–V2O5-based varistors

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Abstract

This study elucidates the effect of sintering temperature on the nonlinearity and surge degradation characteristics of Mn3O4/Nb2O5/Er2O3–doped ZnO–V2O5-based varistors. With increasing sintering temperature, the average grain size increased from 6.3 to 16.6 μm and the ceramic density decreased from 5.51 to 5.41 g/cm3. The highest nonlinearity (α1 = 45.6) was obtained when the sintering temperature reached 900 °C. The sample sintered at 900 °C exhibited the best clamp characteristics, where the clamp voltage ratio was 1.84–2.44 at a surge current of 1–25 A. By contrast, the sample sintered at 925 °C exhibited the highest electrical stability, where \( {{\Delta E_{{1\;{\text{mA/cm}}^{2} }} } \mathord{\left/ {\vphantom {{\Delta E_{{1\;{\text{mA/cm}}^{2} }} } {E_{{1\;{\text{mA/cm}}^{2} }} }}} \right. \kern-0pt} {E_{{1\;{\text{mA/cm}}^{2} }} }} = - 10.6\% \), \( \Delta \alpha_{ 1} /\alpha_{ 1} = - 3 7. 2\% \) and ΔJL/JL = 10.2% after applying a surge current of 200 A.

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References

  1. M. Matsuoka, Nonohmic properties of zinc oxide ceramics. Jpn. J. Appl. Phys. 10(6), 736 (1971)

    Article  CAS  Google Scholar 

  2. L.M. Levinson, H.R. Philipp, Zinc oxide varistor—a review. Am. Ceram. Soc. Bull. 65(4), 639–646 (1986)

    CAS  Google Scholar 

  3. T.K. Gupta, Application of zinc oxide varistor. J. Am. Ceram. Soc. 73(7), 1817–1840 (1990)

    Article  CAS  Google Scholar 

  4. D.R. Clarke, Varistor ceramics. J. Am. Ceram. Soc. 82(3), 485–502 (1999)

    Article  CAS  Google Scholar 

  5. H.R. Pilipp, L.M. Levinson, The physics of metal oxide varistors. J. Appl. Phys. 46(3), 1332–1341 (1976)

    Google Scholar 

  6. K. Mukae, Zinc oxide varistors with praseodymium oxide. Am. Ceram. Bull. 66(10), 1329–1331 (1987)

    CAS  Google Scholar 

  7. C.-W. Nahm, C.-H. Park, Microstucture, electrical properties, and degradation behavior of praseodymium oxides-based zinc oxide varistors doped with Y2O3. J. Mater. Sci. 35(12), 3037–3042 (2000)

    Article  CAS  Google Scholar 

  8. J.-K. Tsai, T.-B. Wu, Non-ohmic characteristics of ZnO–V2O5 ceramics. J. Appl. Phys. 76(8), 4817–4822 (1994)

    Article  CAS  Google Scholar 

  9. J.-K. Tsai, T.-B. Wu, Microstructure and nonohmic properties of binary ZnO–V2O5 ceramics sintered at 900 °C. Mater. Lett. 26(3), 199–203 (1996)

    Article  CAS  Google Scholar 

  10. C.-W. Nahm, Sintering effect on pulse aging behavior of Zn–V–Mn–Co–Nb varistors. J. Am. Ceram. Soc. 94(8), 2269–2272 (2011)

    Article  CAS  Google Scholar 

  11. C.-W. Nahm, DC accelerated aging behavior of Co–Dy–Nb doped Zn–V–M-based varistors with sintering process. J. Mater. Sci. Mater. Electron. 22(4), 444–451 (2011)

    Article  CAS  Google Scholar 

  12. C.-W. Nahm, Aging characteristics of ZnO–V2O5-based varistors for surge protection reliability. Microelectron. Reliab. 54(12), 2836–2842 (2014)

    Article  CAS  Google Scholar 

  13. C.-W. Nahm, Effect of sintering process on electrical properties and ageing behavior of ZnO–V2O5–MnO2–Nb2O5 varistor ceramics. J. Mater. Sci. Mater. Electron. 23(2), 457–463 (2012)

    Article  CAS  Google Scholar 

  14. C.-S. Chen, Effect of dopant valence state of Mn-ions on the microstructures and nonlinear properties of microwave sintered ZnO–V2O5 varistors. J. Mater. Sci. 38(5), 1033–1038 (2003)

    Article  CAS  Google Scholar 

  15. H. Pfeiffer, K.M. Knowles, Effects of vanadium and manganese concentrations on the composition, structure and electrical properties of ZnO-rich MnO2–V2O5–ZnO Varistors. J. Eur. Ceram. Soc. 24(6), 1199–1203 (2004)

    Article  CAS  Google Scholar 

  16. M. Zhao, X.C. Liu, W.M. Wang, F. Gao, C.S. Tian, Two-step method fabricating high nonlinearity ZnVSb based varistors. Ceram. Int. 34(6), 1425–1429 (2008)

    Article  CAS  Google Scholar 

  17. C.-W. Nahm, Microstructure, electrical and dielectric properties, and impulse clamping characteristics of ZnO–V2O5–Mn3O4 semiconducting ceramics modified with Er2O3. J. Mater. Sci. Mater. Electron. 24(10), 4129–4136 (2013)

    Article  CAS  Google Scholar 

  18. J.C. Wurst, J.A. Nelson, Lineal intercept technique for measuring grain size in two-phase polycrystalline ceramics. J. Am. Ceram. Soc. 55(97-12), 109–111 (1972)

    Article  CAS  Google Scholar 

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Nahm, CW. Effect of sintering temperature on nonlinearity and surge degradation characteristics of Mn3O4/Nb2O5/Er2O3-doped ZnO–V2O5-based varistors. J. Korean Ceram. Soc. 57, 65–72 (2020). https://doi.org/10.1007/s43207-019-00009-9

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