Abstract
This study elucidates the effect of sintering temperature on the nonlinearity and surge degradation characteristics of Mn3O4/Nb2O5/Er2O3–doped ZnO–V2O5-based varistors. With increasing sintering temperature, the average grain size increased from 6.3 to 16.6 μm and the ceramic density decreased from 5.51 to 5.41 g/cm3. The highest nonlinearity (α1 = 45.6) was obtained when the sintering temperature reached 900 °C. The sample sintered at 900 °C exhibited the best clamp characteristics, where the clamp voltage ratio was 1.84–2.44 at a surge current of 1–25 A. By contrast, the sample sintered at 925 °C exhibited the highest electrical stability, where \( {{\Delta E_{{1\;{\text{mA/cm}}^{2} }} } \mathord{\left/ {\vphantom {{\Delta E_{{1\;{\text{mA/cm}}^{2} }} } {E_{{1\;{\text{mA/cm}}^{2} }} }}} \right. \kern-0pt} {E_{{1\;{\text{mA/cm}}^{2} }} }} = - 10.6\% \), \( \Delta \alpha_{ 1} /\alpha_{ 1} = - 3 7. 2\% \) and ΔJL/JL = 10.2% after applying a surge current of 200 A.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-019-00009-9/MediaObjects/43207_2019_9_Fig1_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-019-00009-9/MediaObjects/43207_2019_9_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-019-00009-9/MediaObjects/43207_2019_9_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-019-00009-9/MediaObjects/43207_2019_9_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-019-00009-9/MediaObjects/43207_2019_9_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-019-00009-9/MediaObjects/43207_2019_9_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-019-00009-9/MediaObjects/43207_2019_9_Fig7_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs43207-019-00009-9/MediaObjects/43207_2019_9_Fig8_HTML.png)
Similar content being viewed by others
References
M. Matsuoka, Nonohmic properties of zinc oxide ceramics. Jpn. J. Appl. Phys. 10(6), 736 (1971)
L.M. Levinson, H.R. Philipp, Zinc oxide varistor—a review. Am. Ceram. Soc. Bull. 65(4), 639–646 (1986)
T.K. Gupta, Application of zinc oxide varistor. J. Am. Ceram. Soc. 73(7), 1817–1840 (1990)
D.R. Clarke, Varistor ceramics. J. Am. Ceram. Soc. 82(3), 485–502 (1999)
H.R. Pilipp, L.M. Levinson, The physics of metal oxide varistors. J. Appl. Phys. 46(3), 1332–1341 (1976)
K. Mukae, Zinc oxide varistors with praseodymium oxide. Am. Ceram. Bull. 66(10), 1329–1331 (1987)
C.-W. Nahm, C.-H. Park, Microstucture, electrical properties, and degradation behavior of praseodymium oxides-based zinc oxide varistors doped with Y2O3. J. Mater. Sci. 35(12), 3037–3042 (2000)
J.-K. Tsai, T.-B. Wu, Non-ohmic characteristics of ZnO–V2O5 ceramics. J. Appl. Phys. 76(8), 4817–4822 (1994)
J.-K. Tsai, T.-B. Wu, Microstructure and nonohmic properties of binary ZnO–V2O5 ceramics sintered at 900 °C. Mater. Lett. 26(3), 199–203 (1996)
C.-W. Nahm, Sintering effect on pulse aging behavior of Zn–V–Mn–Co–Nb varistors. J. Am. Ceram. Soc. 94(8), 2269–2272 (2011)
C.-W. Nahm, DC accelerated aging behavior of Co–Dy–Nb doped Zn–V–M-based varistors with sintering process. J. Mater. Sci. Mater. Electron. 22(4), 444–451 (2011)
C.-W. Nahm, Aging characteristics of ZnO–V2O5-based varistors for surge protection reliability. Microelectron. Reliab. 54(12), 2836–2842 (2014)
C.-W. Nahm, Effect of sintering process on electrical properties and ageing behavior of ZnO–V2O5–MnO2–Nb2O5 varistor ceramics. J. Mater. Sci. Mater. Electron. 23(2), 457–463 (2012)
C.-S. Chen, Effect of dopant valence state of Mn-ions on the microstructures and nonlinear properties of microwave sintered ZnO–V2O5 varistors. J. Mater. Sci. 38(5), 1033–1038 (2003)
H. Pfeiffer, K.M. Knowles, Effects of vanadium and manganese concentrations on the composition, structure and electrical properties of ZnO-rich MnO2–V2O5–ZnO Varistors. J. Eur. Ceram. Soc. 24(6), 1199–1203 (2004)
M. Zhao, X.C. Liu, W.M. Wang, F. Gao, C.S. Tian, Two-step method fabricating high nonlinearity ZnVSb based varistors. Ceram. Int. 34(6), 1425–1429 (2008)
C.-W. Nahm, Microstructure, electrical and dielectric properties, and impulse clamping characteristics of ZnO–V2O5–Mn3O4 semiconducting ceramics modified with Er2O3. J. Mater. Sci. Mater. Electron. 24(10), 4129–4136 (2013)
J.C. Wurst, J.A. Nelson, Lineal intercept technique for measuring grain size in two-phase polycrystalline ceramics. J. Am. Ceram. Soc. 55(97-12), 109–111 (1972)
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Nahm, CW. Effect of sintering temperature on nonlinearity and surge degradation characteristics of Mn3O4/Nb2O5/Er2O3-doped ZnO–V2O5-based varistors. J. Korean Ceram. Soc. 57, 65–72 (2020). https://doi.org/10.1007/s43207-019-00009-9
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s43207-019-00009-9