Abstract
Fibrous adsorbents, such as activated carbon fibers (ACF) have acknowledged advantages of rapid adsorption rate and ease of modification compared with granular and powdered adsorbents. Based on the surface modification of lyocell-based ACF, we observed different surface characteristics of ACF samples with variation in the mixing ratio and impregnation time of H3PO4, NaCl, and KMnO4 solution. For an engineering application, we also explored the adsorption characteristics of thus-produced ACF samples onto volatile organic compounds (VOCs). Isothermal adsorption experiments were performed using toluene and benzene as adsorbates. Results indicate that both physical and chemical surface properties have an effect on the adsorption of volatile organic compounds (VOCs).
Similar content being viewed by others
References
Andrews SJ, Hackenberg SC, Carpenter LJ (2015) A fully automated purge and trap GC–MS system for quantification of volatile organic compound (VOC) fluxes between the ocean and atmosphere. Ocean Sci 11(2):313–321
Choi YY et al (2019) The impact of corrosion on marine vapour recovery systems by VOC generated from ships. Int J Nav Architect Ocean Eng 11(1):52–58
Yang C et al (2018) Simultaneous removal of multicomponent VOCs in biofilters. Trends Biotechnol 36(7):673–685
Ahlberg E et al (2017) Secondary organic aerosol from VOC mixtures in an oxidation flow reactor. Atmos Environ 161:210–220
Tang X et al (2009) Formaldehyde in China: production, consumption, exposure levels, and health effects. Environ Int 35(8):1210–1224
Xu T, Hong Z, Pengyi Z (2018) Performance of an innovative VUV-PCO purifier with nanoporous TiO2 film for simultaneous elimination of VOCs and by-product ozone in indoor air. Build Environ 142:379–387
Boycheva S et al (2019) Studies on non-modified and copper-modified coal ash zeolites as heterogeneous catalysts for VOCs oxidation. J Hazard Mater 361:374–382
Chen J et al (2018) Homogeneous introduction of CeOy into MnOx-based catalyst for oxidation of aromatic VOCs. Appl Catal B Environ 224:825–835
Luengas A et al (2015) A review of indoor air treatment technologies. Rev Environ Sci Biotechnol 14(3):499–522
Zhang X et al (2017) Adsorption of VOCs onto engineered carbon materials: a review. J Hazard Mater 338:102–123
Le Cloirec P (2012) Adsorption onto activated carbon fiber cloth and electrothermal desorption of volatile organic compound (VOCs): a specific review. Chin J Chem Eng 20(3):461–468
Oh GY, Ju YW, Jung HR, Lee WJ (2008) Preparation of the novel manganese-embedded PAN-based activated carbon nanofibers by electrospinning and their toluene adsorption. J Anal Appl Pyrolysis 81(2):211–217
Liu ZS, Chen JY, Peng YH (2013) Activated carbon fibers impregnated with Pd and Pt catalysts for toluene removal. J Hazard Mater 256:49–55
Tan IAW, Hameed BH, Ahmad AL (2007) Equilibrium and kinetic studies on basic dye adsorption by oil palm fibre activated carbon. Chem Eng J 127(1–3):111–119
Tsai JH, Chiang HM, Huang GY, Chiang HL (2008) Adsorption characteristics of acetone, chloroform and acetonitrile on sludge-derived adsorbent, commercial granular activated carbon and activated carbon fibers. J Hazard Mater 154(1–3):1183–1191
Yang S, Zhu Z, Wei F, Yang X (2017) Enhancement of formaldehyde removal by activated carbon fiber via in situ growth of carbon nanotubes. Build Environ 126:27–33
Hu Z, Vansant EF (1995) Synthesis and characterization of a controlled-micropore-size carbonaceous adsorbent produced from walnut shell. Microporous Mater 3(6):603–612
Tomków K et al (1977) Formation of porous structures in activated brown-coal chars using O2, CO2 and H2O as activating agents. Fuel 56(2):121–124
Choi B et al (2017) Adsorption characteristics of heavy metals ions by physical activation on coal tar pitch-based activated carbon fibers. Carbon Lett 22:96–100
Bai BC et al (2015) Effects of surface chemical properties of activated carbon fibers modified by liquid oxidation for CO2 adsorption. Appl Surf Sci 353:158–164
Shamsuddin MS, Yusoff NRN, Sulaiman MA (2016) Synthesis and characterization of activated carbon produced from kenaf core fiber using H3PO4 activation. Proc Chem 19:558–565
Girgis BS, El-Hendawy AA (2002) Porosity development in activated carbons obtained from date pits under chemical activation with phosphoric acid. Microporous Mesoporous Mater 52(2):105–117
Baur GB, Igor Y, Lioubov KM (2015) Activated carbon fibers modified by metal oxide as effective structured adsorbents for acetaldehyde. Catal Today 249:252–258
Zhang LL, Zhao XS (2009) Carbon-based materials as supercapacitor electrodes. Chem Soc Rev 38(9):2520–2531
Rodriguez-Reinoso F et al (1986) Hydrogenation of CO on carbon-supported iron catalysts prepared from iron penta-carbonyl. Appl Catal 21(2):251–261
Xu S, Qi J (2018) Surface modification of carbon fiber support by ferrous oxalate for biofilm wastewater treatment system. J Clean Prod 194:416–424
Jeon Y et al (2016) Enhancement of catalytic durability through nitrogen-doping treatment on the CNF-derivatized ACF support for high temperature PEMFC. Int J Hydrog Energy 41(16):6864–6876
Lopez-Ramon MV et al (1999) On the characterization of acidic and basic surface sites on carbons by various techniques. Carbon 37(8):1215–1221
Terzyk AP (2001) The influence of activated carbon surface chemical composition on the adsorption of acetaminophen (paracetamol) in vitro: Part II. TG, FTIR, and XPS analysis of carbons and the temperature dependence of adsorption kinetics at the neutral pH. Colloids Surf A Physicochem Eng Asp 177(1):23–45
Swiatkowski A et al (2004) Influence of the surface chemistry of modified activated carbon on its electrochemical behaviour in the presence of lead (II) ions. Carbon 42(15):3057–3069
Yin CY, Aroua MK, Daud WM (2007) Review of modifications of activated carbon for enhancing contaminant uptakes from aqueous solutions. Sep Purif Technol 52(3):403–415
Díez N et al (2015) N-enriched ACF from coal-based pitch blended with urea-based resin for CO2 capture. Microporous Mesoporous Mater 201:10–16
Frysz CA, Chung DDL (1997) Improving the electrochemical behavior of carbon black and carbon filaments by oxidation. Carbon 35(8):1111–1127
Silva TL et al (2018) Mesoporous activated carbon fibers synthesized from denim fabric waste: efficient adsorbents for removal of textile dye from aqueous solutions. J Clean Prod 171:482–490
Prajapati YN et al (2016) Aqueous phase adsorption of different sized molecules on activated carbon fibers: effect of textural properties. Chemosphere 155:62–69
Zhang X et al (2017) Adsorption of VOCs onto engineered carbon materials: a review. J Hazard Mater 338:102–123
Al-Asheh S et al (2000) Predictions of binary sorption isotherms for the sorption of heavy metals by pine bark using single isotherm data. Chemosphere 41(5):659–665
Duan X et al (2017) Synthesis of activated carbon fibers from cotton by microwave induced H3PO4 activation. J Taiwan Inst Chem Eng 70:374–381
Houshmand A, Daud WM, Shafeeyan MS (2011) Exploring potential methods for anchoring amine groups on the surface of activated carbon for CO2 adsorption. Sep Sci Technol 46(7):1098–1112
Mahmoudian M et al (2017) Investigation of Salt and precipitating agent effect on the specific surface area and compressive strength of alumina catalyst support. Polish J Chem Technol 19(3):35–40
Funding
There are no specific funding.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
There are no specific conflicts of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Choi, S.S., Lee, J.H., Jin, Y.M. et al. Adsorption characteristics of volatile organic compounds onto lyocell-based activated carbon fibers. Carbon Lett. 29, 633–642 (2019). https://doi.org/10.1007/s42823-019-00063-7
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s42823-019-00063-7