Abstract
Recovering valuable metals from tailings not only provides a source of income but also helps conserve natural resources, thus reducing the environmental impact of mining activities. This study aimed to recover cobalt using tailings of the Küre flotation plant, which were determined to contain 0.17% Co. Flotation tests were conducted on samples taken from the tailings to investigate the effects of pH and pH conditioning time, as well as types and amounts of depressant, collector, and frother on the grade and recovery of Co in rougher flotation tests. Optimal flotation conditions were determined to be pH 6, a pH conditioning time of 7 min, and dosages of 50 g/t, 100 g/t, and 20 g/t of sodium hexametaphosphate, X-231, and DF250, respectively. According to the rougher flotation test results, a concentrate with a Co grade of 0.46% and a Co recovery of 84.15% was obtained. In the concentrate obtained using cleaner flotation tests, the Co grade increased to 0.49% and Co recovery increased to 90.56%. These results show that froth flotation, carried out with the appropriate reagents, is a successful method for recovering Co by enriching the flotation plant tailings.
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References
Beşe AV (2017) The recovery of metals from copper slags. Sinop Uni J Nat Sci 2(1):140–149
Brest KK, Henock MM, Guellord N, Kimpiab M, Kapiamba KF (2021) Statistical investigation of flotation parameters for copper recovery from sulfide flotation tailings. Results Eng 9:100207
COM (2020) Critical raw materials resilience: charting a path towards greater security and sustainability. https://eur-lex.europa.eu/legal-content/EN/TXT/?uri=CELEX:52020DC0474. Accessed 12 November 2022
Mandys F (2021) Electric vehicles and consumer choices. Renew Sustain Energy Rev 142:110874
Cobalt Institute (2022) Cobalt use. https://www.cobaltinstitute.org/about-cobalt/cobalt-life-cycle/cobalt-use/. Accessed 19 December 2022
USGS (2017) Mineral Commodity Summaries. https://d9-wret.s3.us-west-2.amazonaws.com/assets/palladium/production/mineral-pubs/mcs/mcs2017.pdf. Accessed 7 August 2022
Okudan MD (2009) Acidic and alkaline leaching application to spent hydrodesulfurization (hds) catalysts including cobalt and molybdenum. Dissertation, Süleyman Demirel University
Crundwell FK, Du Preez NB, Knights BDH (2020) Production of cobalt from copper-cobalt ores on the African Copperbelt–an overview. Miner Eng 156:106450
Yaylalı B (2017) Recovery of cobalt from pyritic tailings. Dissertation, Karadeniz Technical University
Tsurukawa N, Prakash S, Manhart A (2011) Social impacts of artisanal cobalt mining in Katanga, Democratic Republic of Congo. Öko-Institut eV, Freiburg
USGS (2020) Mineral commodity summaries. https://pubs.usgs.gov/periodicals/mcs2020/mcs 2020.pdf. Accessed 16 September 2022
Lutandula MS, Maloba B (2013) Recovery of cobalt and copper through reprocessing of tailings from flotation of oxidised ores. J Environ Chem Eng 1(4):1085–1090
Shengo ML, Kime MB, Mambwe MP, Nyembo TK (2019) A review of the beneficiation of copper-cobalt-bearing minerals in the Democratic Republic of Congo. J Sustain Min 18(4):226–246
Yaylali B, Yazici E, Celep O, Deveci H (2016) Extraction of cobalt from a flotation tailings in different mineral acids under oxidative conditions. In: Çelik MS (ed) 15. International Mineral Processing Symposium (IMPS), İstanbul, pp 726–736
Arslan C, Arslan F (2002) Recovery of copper, cobalt, and zinc from copper smelter and converter slags. Hydrometallurgy 67(1–3):1–7. https://doi.org/10.1016/S0304-386X(02)00139-1
Rudnik E, Burzyńska L, Gumowska W (2009) Hydrometallurgical recovery of copper and cobalt from reduction-roasted copper converter slag. Miner Eng 22(1):88–95. https://doi.org/10.1016/j.mineng.2008.04.016
Zhai XJ, Li NJ, Zhang X, Fu Y, Jiang L (2011) Recovery of cobalt from converter slag of Chambishi Copper Smelter using reduction smelting process. Trans Nonferrous Met Soc China 21(9):2117–2121. https://doi.org/10.1016/S1003-6326(11)60982-5
Pryor B, Lunt D (2003) Development of the Kolwezi tailings copper/cobalt flowsheet. In: ALTA Conference, Perth, pp 1–9
Dehaine Q, Tijsseling LT, Glass HJ, Törmänen T, Butcher AR (2021) Geometallurgy of cobalt ores: A review. Miner Eng 160:106656
Hayat MB, Alagha L, Sannan SM (2017) Flotation behavior of complex sulfide ores in the presence of biodegradable polymeric depressants. Int J Polym Sci 2017:1–9
Çağatay A, Pehlivanoğlu H, Altun Y (1980) Cobalt-gold minerals in Kure pyritic copper deposits and their economic values. Bull Min Res Exp 93–94:110–117
Uçurum M, Yıldırım M, Köse M (1982) Küre piritli bakır yataklarındaki kobaltın flotasyon yöntemiyle zenginleştirme çalışmaları. MTA Report, Ankara.
Canbazoğlu M, Uzun M, Çelik Ö, Köse M (1985) Extraction of cobalt, copper, gold and silver from cinders of Küre pyritic coppers ores: a hydrometallurgical approach. In: 9. Scientific and Technical Mining Congress of Turkey, Ankara, pp 59–73
Mordoğan H (1989) Kastamonu-Küre-Bakibaba piritli bakır cevherindeki kobalt dağılımı ve kazanılma olanağı. Turkish J Chem 13(1)
Çokgör O, Topkaya YA (1988) Extraction of cobalt and copper from Küre pyrite concentrate. Miner Eng 1(3):213–223
Topkaya YA, Çokgör O (1991) Solvent ekstraksiyon yöntemiyle bakır ve kobalt kazanımının denge ve kinetiği. TUBİTAK Project no:785, Ankara
Yalçın S (1995) Distribution of base, rare and precious metals and their recovery in Kure massive ore. Dissertation, Istanbul Technical University
Perek KT, Arslan F (2003) Extraction of metallic values from Küre massive rich copper ore by pressure leaching. itu dergisi/d 2(3):65–72.
Arslan F, Kangal MO, Bulut G, Gül A (2004) Leaching of massive rich copper ore with acidified ferric chloride. Miner Process Extr Metall Rev 25(2):143–158
Bulut G (2006) Recovery of copper and cobalt from ancient slag. Waste Manag Res 24(2):118–124
Bulut G, Perek KT, Gül A, Arslan F, Önal G (2007) Recovery of metal values from copper slags by flotation and roasting with pyrite. Min Metall Explor 24(1):13–18
Yuksel U, Tegin I, Ziyadanogullari R (2017) Recovery of copper and cobalt from copper slags as selective. J Environ Sci Eng A 6(8):388–394
Xiao J, Zhang Y (2019) Recovering cobalt and sulfur in low grade cobalt-bearing V-Ti magnetite tailings using flotation process. Processes 7(8):536
Zanin M, Lambert H, Du Plessis CA (2019) Lime use and functionality in sulphide mineral flotation: a review. Miner Eng 143:105922
Bulatovic S (2007) Handbook of flotation reagents: chemistry, theory and practice: Vol 1: Flotation of sulfide ores. Elsevier, Boston
Taner HA (2019) The effect of structural properties of clay minerals on flotation performance of metal sulphides. Dissertation, Konya Technical University
Wang XH, Forssberg KSE (1991) Mechanisms of pyrite flotation with xanthates. Int J Miner Process 33(1–4):275–290. https://doi.org/10.1016/0301-7516(91)90058-q
Castellón CI, Toro N, Gálvez E, Robles P, Leiva WH, Jeldres RI (2022) Froth flotation of chalcopyrite/pyrite ore: a critical review. Materials 15(19):6536
Dimou A (1986) The flotation of pyrite using xanthate collectors. Dissertation, University of Cape Town
Chander S, Briceno A (1987) Kinetics of pyrite oxidation. Min Metall Explor 4(3):171–176
Ekmekçi Z, Demirel, H (1997) Effects of pulp potential and galvanic interaction on flotation of chalcopyrite and pyrite. In: Güyagüler T (ed) The 15. Mining Congress of Turkey, Ankara, pp 353–360
Deng W, Xu L, Tian J, Hu Y, Han Y (2017) Flotation and adsorption of a new polysaccharide depressant on pyrite and talc in the presence of a pre-adsorbed xanthate collector. Minerals 7(3):40
Davenport WG, King MJ, Schlesinger ME, Biswas AK (2002) Extractive metallurgy of copper, Elsevier
Molaei N, Hoseinian FS, Rezai B (2018) A study on the effect of active pyrite on flotation of porphyry copper ores. Physicochem Probl Miner 54(3):922–933
Banza AN, Kongolo K (2001) Flotation of a silicated oxide copper-cobalt ore from Fungurume deposit. In: Proceeding of The VI Southern Hemisphere Meeting on Mineral Technology (SHMMT) vol 1, Rio de Janeiro, pp 230–234
Yılmazer BZ (2002) The effects of hydrodynamic parameters on mechanical entrainment in the flotation of Küre rougher concentrate. Dissertation, Süleyman Demirel University
Song S, Lopez-Valdivieso A, Espinoza-Ortega O (2009) Role of sodium hexametaphosphate in the flotation of acanthite fines from finely disseminated ores. Sep Sci Technol 44(12):2971–2982
Wills B (1997) Mineral Processing Technology, 6th edn. Butterworth Heinemann, London
Bell DT (2012) Flotation of cobalt bearing minerals from a mixed copper-cobalt oxidized ore. Dissertation, University of Johannesburg
Shahcheraghi SH, Abdollahy M, Khalesi MR, Hossein SM (2012) A study on the effect of some operating parameters on the flotation kinetics of copper sulfide minerals. In: Proceedings of the XXVI International Mineral Processing Congress (IMPC), New Delhi, pp 24–28
Khoshdast H, Sam A (2011) Flotation frothers: review of their classifications, properties and preparation. The Open Miner Process J 4(1):25–44
Mordogan H (1985) Karadeniz bölgesi kompleks bakırlı cevherlerden bazı metallerin kazanılmasında optimal koşulların saptanması. Dissertation, Ege University
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Aras, A., Rasa, M.H. Investigation of Flotation Conditions for Cobalt Recovery from Mine Tailings. Mining, Metallurgy & Exploration 40, 939–948 (2023). https://doi.org/10.1007/s42461-023-00769-3
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DOI: https://doi.org/10.1007/s42461-023-00769-3