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Fe3O4@Boehmite-NH2-CoII NPs: An Environment Friendly Nanocatalyst for Solvent Free Synthesis of Coumarin Derivatives Through Pechmann Condensation Reaction

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Abstract

We report herein the synthesis of coumarin derivatives via the Pechmann condensation reaction in the presence of magnetic core–shell-like Fe3O4@Boehmite-NH2-CoII NPs. The aforesaid nanocatalyst which previously reported by our group, was found to be an efficient heterogeneous nanocatalyst in this reaction. Initially, the reaction conditions were optimized with different solvents, catalyst amounts and temperatures. Subsequently, the scope of the reaction was extended and the coumarin derivatives were obtained in reasonable yields. Interestingly, Fe3O4@Boehmite-NH2-CoII NPs was stable under reaction conditions and can be reused at least six times without a significant decrease in its catalytic activity. More importantly, using cobalt as a non-toxic, inexpensive, widely available and high-activity catalyst is great of interest than the most previously reported protocols.

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Acknowledgements

The authors gratefully acknowledge the partial support of this study by Ferdowsi University of Mashhad Research Council (Grant No. p/3/47339).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, Mashhad, 9177948974, Iran

    Somayeh Pakdel, Batool Akhlaghinia & Arezou Mohammadinezhad

Authors
  1. Somayeh Pakdel
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  2. Batool Akhlaghinia
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  3. Arezou Mohammadinezhad
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Corresponding author

Correspondence to Batool Akhlaghinia.

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Pakdel, S., Akhlaghinia, B. & Mohammadinezhad, A. Fe3O4@Boehmite-NH2-CoII NPs: An Environment Friendly Nanocatalyst for Solvent Free Synthesis of Coumarin Derivatives Through Pechmann Condensation Reaction. Chemistry Africa 2, 367–376 (2019). https://doi.org/10.1007/s42250-019-00042-5

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  • DOI: https://doi.org/10.1007/s42250-019-00042-5

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