Abstract
Highly reactive ferro-coke has been widely studied due to its contribution to the energy saving and emission reduction in blast furnace ironmaking. To optimize the coking process of ferro-coke and improve its metallurgical properties, it is necessary to clarify the influence of initial iron ore on the strength, micro-morphology and CO2 gasification reaction behavior of formed ferro-coke. The effects of initial iron ore particle size (0.50–1.00, 0.25–0.50 and 0.074–0.125 mm) on the CO2 gasification reaction of ferro-coke were analyzed using thermo-analysis technique. In addition, the effects of initial iron ore particle size on the strength and morphology of ferro-coke were investigated by drum test, digital microscopy and scanning electron microscopy. The results show that iron reduced from iron ore has a great promotion effect on the CO2 gasification reaction of ferro-coke. The smaller the particle size of initial iron ore, the more intense the gasification reaction, and the lower the starting temperature for gasification reaction of ferro-coke. The results of kinetic calculation show that the apparent activation energy of ferro-coke decreases with the decreasing particle size of blended iron ore. The particle size of initial iron ore has a great impact on the strength of ferro-coke. The ferro-coke prepared by 0.25–0.50 mm iron ore presents the best strength in this experiment.
Similar content being viewed by others
References
S. Zhang, E. Worrell, W. Crijns-Graus, F. Wagner, J. Cofala, Energy 78 (2014) 333–345.
R. Xu, L. Xu, B. Xu, J. Clean. Prod. 152 (2017) 259–270.
B. Xu, B. Lin, Appl. Energy 161 (2016) 375–386.
G.P. Lin, J. Dai, Energy for Metallurgical Industry 37 (2018) No. 3, 3–5.
K. Higuchi, S. Nomura, K. Kunitomo, H. Yokoyama, M. Naito, ISIJ Int. 51 (2011) 1308–1315.
H. Wang, Z. Wang, M. Chu, W. Zhao, Z. Liu, in: Proceedings of the 10th CSM Steel Congress and the 6th Baosteel Biennial Academic Conference, Metallurgical Industry Press, Beijing, China, 2015, pp. 1−6.
B. Gao, Jiangxi Metallurgy 37 (2017) No. 5, 13–16.
U. Srivastava, S.K. Kawatra, T.C. Eisele, Int. J. Miner. Process. 119 (2013) 51–57.
D. Fu, G.Tang, Y. Zhao, J. D’Alessio, C.Q. Zhou, Int. J. Heat Mass Transfer 103 (2016) 77–86.
Z.Q. Gu, L.J. Jia, X.Z. Shi, Industrial Furnace 38 (2016) No. 3, 1–4.
M. Naito, A. Okamoto, K. Yamaguchi, T. Yamaguchi, Y. Inoue, Nippon Steel Tech. Rep. 94 (2006) 103–108.
S. Nomura, K. Higuchi, K. Kunitomo, M. Naito, ISIJ Int. 50 (2010) 1388–1395.
A. Kasai, Y. Matsui, ISIJ Int. 44 (2004) 2073–2078.
L. Chen, Blast furnace ironmaking process and calculation, Metallurgical Industry Press, Beijing, China, 1991.
K.J. Li, J.L. Zhang, Y.P. Zhang, Z.J. Liu, X. Jiang, Chin. J. Process Eng. 14 (2014) 162–172.
T. Murakami, E. Kasai, ISIJ Int. 51 (2011) 1220–1226.
J.L. Zhang, J. Guo, G.W. Wang, L.M. Zhang, T. Xu, C.L. Zhang, Iron and Steel 51 (2016) No. 9, 22–29.
H. Wang, W. Zhao, M. Chu, Z. Liu, J. Tang, Z. Ying, Powder Technol. 328 (2018) 318–328.
H. Zhang, The research of reaction mechanism mechanism of ferro-coke gasification, Wuhan University of Science and Technology, Wuhan, China, 2015.
S.Z. Shi, S. Lu, X.G. Bi, P. Li, Y.G. Mao, Q. Zheng, Iron and Steel 50 (2015) No. 7, 15–19.
S.X. Qiu, S.F. Zhang, Q.Y. Zhang, G.B. Qiu, L.Y. Wen, J. Iron Steel Res. Int. 24 (2017) 1169–1176.
A. Uchida, T. Kanai, Y. Yamazaki, K. Hiraki, Y. Saito, H. Aoki, N. Komatsu, N. Okuyama, M. Hamaguchi, ISIJ Int. 53 (2013) 403–410.
A. Uchida, Y. Yamazaki, S. Matsuo, Y. Saito, Y. Matsushita, H. Aoki, M. Hamaguchi, ISIJ Int. 56 (2016) 2132–2139.
A. Uchida, Y. Yamazaki, S. Matsuo, Y. Saito, Y. Matsushita, H. Aoki, M. Hamaguchi, ISIJ Int. 57 (2017) 1524–1530.
H. Wang, M. Chu, Z. Wang, W. Zhao, Z. Liu, J. Tang, Z. Ying, JOM 70 (2018) 1929–1936.
R. Xu, H. Zheng, W. Wang, J. Schenk, Z. Xue, Energy Fuels 32 (2018) 12118–12127.
W. Yu, T. Sun, Z. Liu, J. Kou, C. Xu, ISIJ Int. 54 (2014) 56–62.
H. Zheng, W. Wang, R. Xu, R. Zan, J. Schenk, Z. Xue, Energies 11 (2018) 2595.
R. Xu, B. Dai, W. Wang, J. Schenk, Z. Xue, Fuel Process. Technol. 173 (2018) 11–20.
J. Wei, Q. Guo, H. Chen, X. Chen, G. Yu, Bioresour. Technol. 220 (2016) 509–515.
W. Huo, Z. Zhou, F. Wang, G. Yu, Chem. Eng. J. 244 (2014) 227–233.
R.C. Everson, H.W.J.P. Neomagus, H. Kasaini, D. Njapha, Fuel 85 (2006) 1076–1082.
R. Xu, J. Zhang, G. Wang, H. Zuo, Z. Liu, K. Jiao, Y. Liu, K. Li, Metall. Mater. Trans. B 47 (2016) 2535–2548.
B.K. Sarkar, S. Samanta, R. Dey, G.C. Das, Int. J. Miner. Process.152 (2016) 36–45.
M. Grigore, R. Sakurovs, D. French, V. Sahajwalla, Energy Fuels 23 (2009) 2075–2085.
K. Li, J. Zhang, Z. Liu, X. Ning, T. Wang, Ind. Eng. Chem. Res. 53 (2014) 5737–5748.
K. Guo, J.L. Zhang, G.W. Wang, K.J. Li, J.B. Zhong, H.Y. Wang, China Metallurgy 27 (2017) No. 10, 7–14.
R. Xu, J. Zhang, G. Wang, H. Zuo, P. Li, H. Wang, H. Lin, S. Liu, J. Therm. Anal. Calorim. 123 (2016) 773–783.
L.T. Vlaev, I.G. Markovska, L.A. Lyubchev, Thermochim. Acta 406 (2003) 1–7.
R. Xu, B. Dai, W. Wang, J. Schenk, A. Bhattacharyya, Z. Xue, Energy Fuels 32 (2018) 1188–1195.
W. Wang, J. Wang, R. Xu, Y. Yu, Y. Jin, Z. Xue, Fuel Process. Technol. 159 (2017) 118–127.
G. Domazetis, B.D. James, J. Liesegang, M. Raoarun, M. Kuiper, I.D. Potter, D. Oehme, Fuel 93 (2012) 404–414.
P. Li, X.G. Bi, S.Z. Shi, H.X. Zhang, Q. Dong, Z. Long, J. Iron Steel Res. 27 (2015) No.12, 10–15.
X. He, Coal chemistry, Metallurgical Industry Press, Beijing, China, 2010.
S. Nomura, H. Terashima, E. Sato, M. Naito, ISIJ Int. 47 (2007) 823–830.
Y. Yamazaki, H. Hayashizaki, K. Ueoka, K. Hiraki, Y. Matsushita, H Aoki, T. Miura, Tetsu-to-Hagane 96 (2010) 536–544.
Acknowledgements
The authors acknowledge financial support from the National Natural Science Foundation of China (51704216 and U1760101), National Postdoctoral Program for Innovative Talents Funded Project (BX20180023) and China Postdoctoral Science Foundation Funded Project (2019M650424).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Xu, Rs., Deng, Sl., Zheng, H. et al. Influence of initial iron ore particle size on CO2 gasification behavior and strength of ferro-coke. J. Iron Steel Res. Int. 27, 875–886 (2020). https://doi.org/10.1007/s42243-020-00454-5
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s42243-020-00454-5