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Research progress on electromagnetic wave absorption based on magnetic metal oxides and their composites

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Abstract

Recently, great efforts have been made to develop materials based on magnetic metal oxides to realize excellent electromagnetic wave absorption properties. Nevertheless, the use of traditional magnetic metal oxide materials with certain magnetic losses is not only difficult to meet the final requirements, but also limits the thickness of the absorber and their range of use. Therefore, some promising magnetic metal oxide composites with excellent conductive and magnetic losses have been fabricated, which have specific structures having and interfacial polarization and multiple reflections. Here, the theory of electromagnetic microwave absorption is discussed. Afterwards, the accomplishments in the fabrication of magnetic metal oxides and their composites are reviewed. Furthermore, electromagnetic wave absorption performances and relevant influencing factors of magnetic metal oxides and their composites are exhibited in detail. At last, current challenges are exhibited and future prospects of this developing field are discussed.

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Fig. 1
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Fig. 3

Reproduced with permission from Ref. [74] Copyright 2017. Springer. Schematic fabrication process of Fe3O4@NPC@RGO composite and i SEM and j TEM images, k impedance matching plots, and l 3D RL plots of Fe3O4@NPC@RGO composite. Reproduced with permission from Ref. [90] Copyright 2020. The Royal Society of Chemistry

Fig. 4

Reproduced with permission from Ref. [87] Copyright 2017. American Chemical Society. f SEM image, g impedance match plot, h complex permittivity and complex permeability curves plot, i variation of RL with frequency for RGO/Fe3O4/ZnO. Reproduced with permission from Ref. [92] Copyright 2017. Elsevier

Fig. 5

Reproduced with permission from Ref. [37] Copyright 2021. Elsevier. h Schematic fabrication process of the synthesis process of MWCNTs/ZnFe2O4 hybrid composites, i SEM image and j RL plot. Reproduced with permission from Ref. [94] Copyright 2017. Elsevier

Fig. 6
Fig. 7

Reproduced with permission from Ref. [96] Copyright 2016. Wiley–VCH Verlag GmbH & Co. e Schematic fabrication process of porous γ-Fe2O3 nanosheets, f SEM and g TEM images of H-Al-Fe2O3, h real and i imaginary parts of the electromagnetic parameters, g 3D and k frequency dependence of the RL of H-Al-Fe2O3. Reproduced with permission from Ref. [77] Copyright 2021. Elsevier

Fig. 8

Reproduced with permission from Ref. [98] Copyright 2019. Elsevier. h Schematic fabrication process of γ-Fe2O3 nanocubes/graphene (GFC), and the corresponding i SEM image, j TEM image, k complex permittivity and complex permeability, l dielectric and magnetic loss tangents, m 2D plot, and n frequency dependence of RL. Reproduced with permission from Ref. [99] Copyright 2020. Elsevier

Fig. 9

Reproduced with permission from Ref. [100]. Copyright 2020. Elsevier

Fig. 10

Reproduced with permission from Ref. [101] Copyright 2020. Elsevier

Fig. 11

Reproduced with permission from Ref. [103] Copyright 2020. Elsevier. h Schematic fabrication process, i, j SEM images, and k, j dielectric loss and magnetic loss factors of inverse opal of Co3O4@TiO2. From reference [104] Copyright 2021. American Chemical Society

Fig. 12

Reproduced with permission from Ref. [79] Copyright 2017. American Chemical Society. h Schematic preparation process of 3D porous Ni/NiO microspheres, i, j SEM images, k, l 3D plots of dielectric and magnetic loss factors, and m, n RL and frequency dependence of electromagnetic wave absorption. Reproduced with permission from Ref. [105] Copyright 2021. Elsevier

Fig. 13

Reproduced with permission from Ref. [106] Copyright 2019. Elsevier. i Schematic synthesis process, j, k SEM and TEM images, l, m dielectric and magnetic loss factors, n, o frequency dependence of RL of Ni/NiO@C composites. Reproduced with permission from Ref. [107] Copyright 2021. Elsevier

Fig. 14

Reproduced with permission from Ref. [108] Copyright 2019. Elsevier B.V. and Science China Press. f Schematic fabrication process of ALD NiO on the surface of CNTs, g, h TEM images of CNT and CNT@NiO, i elemental mapping images of C, Ni, and O of CNT@NiO, j, k dielectric and magnetic loss factors, and l 2D RL. Reproduced with permission from Ref. [110] Copyright 2021. The Royal Society of Chemistry

Fig. 15

Reproduced with permission from Ref. [80] Copyright 2017. Elsevier. g SEM and h TEM images and corresponding SAED mode and i HRTEM image, j, k dielectric and magnetic loss factors in 2–18 GHz, l electromagnetic wave loss mechanism, m RL of CoFe2O4-HNP/G. Reproduced with permission from Ref. [112] Copyright 2018. The Royal Society of Chemistry

Fig. 16

Reproduced with permission from Ref. [115] Copyright 2019. Elsevier. h Schematic synthesis process, i SEM image, j, k dielectric and magnetic loss factors, l Cole–Cole plot, m impedance matching plot, and n 2D RL of CoFe2O4/RGO composite. Reproduced with permission from Ref. [117] Copyright 2019. American Chemical Society

Fig. 17

Reproduced with permission from Ref. [114] Copyright 2021. Elsevier. h SEM and i TEM images, j, k, l, m real and imaginary parts of dielectric constant and permeability, n, p, o, q 3D RL curves and RLmin versus frequency of CoxFe3-xO4/MoS2 (x = 1.5, 0.75, 0.5) NCs. Reproduced with permission from Ref. [40] Copyright 2019. American Chemical Society

Fig. 18

Reproduced with permission from Ref. [81] Copyright 2019. Elsevier. g Synthesis process, h, i SEM images, j impedance matching plots, k, l RL curves and 3D RL of NiFe2O4/N-GN/ZnO composites. Reproduced with permission from Ref. [38] Copyright 2019. Elsevier

Fig. 19

Reproduced with permission from Ref. [82] Copyright 2021. Elsevier. h Schematic fabrication process, i SEM image and elemental mapping, j, k dielectric and magnetic loss factors, l attenuation constant α, m 2D plot of RL values, n frequency dependence plot, and o 3D plot of 1D NiO/NiCo2O4 microbars. Reproduced with permission from Ref. [124] Copyright 2020. Elsevier

Fig. 20

Reproduced with permission from Ref. [66] Copyright 2020. Elsevier

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Acknowledgements

The author gratitude the environmental and function material team, supported by the Project of Shandong Province Higher Educational Young Innovative Talent Introduction and Cultivation.

Funding

Natural Science Foundation of Shandong,ZR2019BB063

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Authors and Affiliations

  1. School of Material Science and Engineering, Shandong University of Science and Technology, Qingdao, 266590, China

    Haowen Wang, Kangze Zhao, Aolin Nie, Long Chen, Yong Ma & Tingxi Li

  2. Technical Center, Xi’an Aerospace, Sunvalor Chemical Co, Ltd, Xi’an 710086, China

    Hao Zhang

  3. Department of Chemistry, College of Science, Taif University, P.O. Box 11099, Taif, 21944, Saudi Arabia

    Sarah Alharthi & Mohammed A. Amin

  4. Department of Chemistry, Faculty of Science, Al-Azhar University, Nasr City, 11884, Cairo, Egypt

    Zeinhom M. El-Bahy

  5. Mechanical and Construction Engineering, Faculty of Engineering and Environment, Northumbria University, Newcastle Upon Tyne, NE1 8ST, UK

    Handong Li & Ben Bin Xu

  6. College of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan, 030024, China

    Handong Li

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  1. Haowen Wang
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  2. Hao Zhang
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  3. Kangze Zhao
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  9. Long Chen
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  11. Yong Ma
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Contributions

Haowen Wang: data curation, writing—original draft.; Hao Zhang: data curation.; Kangze Zhao, Aolin Nie: writing—review and editing.; Sarah Alharthi: methodology.; Mohammed A. Amin: methodology, review and editing, project administration.; Zeinhom M. El-Bahy: writing—review and editing, project administration.; Handong Li: conceptualization, data curation.; Long Chen: writing—original draft, methodology.; Ben Bin Xu: conceptualization, supervision, project administration, writing—review and editing.; Yong Ma: conceptualization, supervision, project administration, writing—review and editing.; Tingxi Li: supervision, project administration, writing—review and editing.

Corresponding authors

Correspondence to Long Chen, Ben Bin Xu, Yong Ma or Tingxi Li.

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Wang, H., Zhang, H., Zhao, K. et al. Research progress on electromagnetic wave absorption based on magnetic metal oxides and their composites. Adv Compos Hybrid Mater 6, 120 (2023). https://doi.org/10.1007/s42114-023-00694-5

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