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Effect of Fe2O3 addition on sintering behavior of cordierite ceramic obtained by solid-state sintering method

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Abstract

Cordierite ceramics were prepared by solid-state sintering method and kaolin; silicon dioxide and magnesium oxide were used as the raw materials with Fe2O3 as the sintering addition. The effects of Fe2O3 additive amount on sintering behaviors and main properties were studied in detail. As the results, Fe2O3 promotes the sintering process and the cordierite phase also increases. As the sintering temperature and Fe2O3 additive amount increase, the mechanism of sintering shrinkage process changes. And after 1200 °C, the porosity decreases with the increasing Fe2O3 additive amount while the shrinkage percent and bulk density increase. However, excess Fe2O3 will gather in the pore walls and restrain the transformation from spinel phase to cordierite phase.

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References

  1. Kuscer, D., Bantan, I., Hrovat, M., Malič, B.: The microstructure, coefficient of thermal expansion and flexural strength of cordierite ceramics prepared from alumina with different particle sizes. J Eur Ceram Soc. 37, 739–746 (2017)

    Article  Google Scholar 

  2. Sembiring, S., Simanjuntak, W., Situmeang, R., Riyanto, A., Sebayang, K.: Preparation of refractory cordierite using amorphous rice husk silica for thermal insulation purposes. Ceram Int. 42, 8431–8437 (2016)

    Article  Google Scholar 

  3. Al-Harbi, O.A., Özgür, C., Khan, M.M.: Fabrication and characterization of single phase cordierite honeycomb monolith with porous wall from natural raw materials as catalyst support. Ceram Int. 41, 3526–3532 (2015)

    Article  Google Scholar 

  4. Sandoval, M.L., Talou, M.H., Tomba Martinez, A.G., Camerucci, M.A., Gregorová, E., Pabst, W.: Porous cordierite-based ceramics processed by starch consolidation casting – microstructure and high-temperature mechanical behavior. Ceram Int. 44, 3893–3903 (2018)

    Article  Google Scholar 

  5. Banjuraizah, J., Mohamad, H., Ahmad, Z.A.: Densification and crystallization of nonstoichiometric cordierite glass with excess MgO synthesized from kaolin and talc. J Am Ceram Soc. 94, 687–694 (2011)

    Article  Google Scholar 

  6. Bejjaoui, R., Benhammou, A., Nibou, L., Tanouti, B., Bonnet, J.P., Yaacoubi, A., Ammar, A.: Synthesis and characterization of cordierite ceramic from Moroccan stevensite and andalusite. Appl Clay Sci. 49, 336–340 (2010)

    Article  Google Scholar 

  7. Zhou, J.-e., Dong, Y., Hampshire, S., Meng, G.: Utilization of sepiolite in the synthesis of porous cordierite ceramics. Appl Clay Sci. 52, 328–332 (2011)

    Article  Google Scholar 

  8. Zhang, F., Qi, C.-X., Wang, S., Liu, J.-h., Cao, H.: A study on preparation of cordierite gradient pores porous ceramics from rectorite. Solid State Sci. 13, 929–933 (2011)

    Article  Google Scholar 

  9. Ogiwara, T., Noda, Y., Kimura, O.: Fabrication of high density cordierite ceramics using a coal fly ash. J Ceram Soc Jpn. 118, 231–235 (2010)

    Article  Google Scholar 

  10. Goel, A., Shaaban, E.R., Melo, F.C.L., Ribeiro, M.J., Ferreira, J.M.F.: Non-isothermal crystallization kinetic studies on MgO–Al2O3–SiO2–TiO2 glass. J Non-Cryst Solids. 353, 2383–2391 (2007)

    Article  Google Scholar 

  11. Chen, G.-H., Liu, X.-Y.: Sintering, crystallization and properties of MgO–Al2O3–SiO2 system glass-ceramics containing ZnO. J Alloys Compd. 431, 282–286 (2007)

    Article  Google Scholar 

  12. Chen, G.-h.: Sintering, crystallization, and properties of CaO doped cordierite-based glass–ceramics. J Alloys Compd. 455, 298–302 (2008)

    Article  Google Scholar 

  13. Wang, S.: Effects of Fe on crystallization and properties of a new high infrared radiance glass-ceramics. Environ Sci Technol. 44, 4816–4820 (2010)

    Article  Google Scholar 

  14. Wang, S.-M., Kuang, F.-H., Yan, Q.-Z., Ge, C.-C., Qi, L.-H.: Crystallization and infrared radiation properties of iron ion doped cordierite glass-ceramics. J Alloys Compd. 509, 2819–2823 (2011)

    Article  Google Scholar 

  15. Li, Y., Cheng, X., Zhang, R., Wang, Y., Zhang, H.: Effect of excess MgO on the properties of cordierite ceramic sintered by solid-state method. Int J Appl Ceram Technol. 12, 443–450 (2015)

    Article  Google Scholar 

  16. Genevrier, M., Mocellin, A.: Reaction sintering and mechanical behavior of cordierite containing sapphirine dispersoids. J Am Ceram Soc. 79, 2098–2104 (1996)

    Article  Google Scholar 

  17. Banjuraizah, J., Mohamad, H., Ahmad, Z.A.: Effect of excess MgO mole ratio in a stoichiometric cordierite (2MgO·2Al2O3·5SiO2) composition on the phase transformation and crystallization behavior of magnesium aluminum silicate phases. Int J Appl Ceram Technol. 8, 637–645 (2011)

    Article  Google Scholar 

  18. Dong, Y., Zhou, J.E., Lin, B., Wang, Y., Wang, S., Miao, L., Lang, Y., Liu, X., Meng, G.: Reaction-sintered porous mineral-based mullite ceramic membrane supports made from recycled materials. J Hazard Mater. 172, 180–186 (2009)

    Article  Google Scholar 

  19. Xiangchong, Z., Guangping, L., Chung, H.S., Li, K.P.: Sintering characteristics of Chinese bauxites. Ceram Int. 7, 65–68 (1981)

    Article  Google Scholar 

  20. Mackenzie, J.J.K., Shuttleworth, R.: A phenomenological theory of sintering. Proc Phys Soc Lond. 62, 633–652 (1949)

    Google Scholar 

Download references

Acknowledgements

This work was supported by the Science and technology research project of higher education in Hebei province (QN2017350), and the National Natural Science Foundation of China (Grant No. 51802097).

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Correspondence to Ye Li.

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Li, Y., Zhao, H. Effect of Fe2O3 addition on sintering behavior of cordierite ceramic obtained by solid-state sintering method. J Aust Ceram Soc 55, 567–574 (2019). https://doi.org/10.1007/s41779-018-0263-7

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  • DOI: https://doi.org/10.1007/s41779-018-0263-7

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