Abstract
Galvanized waste is characterized from a mineralogical point of view in order to investigate the effects of its utilization in sanitary ware bodies. Galvanized waste was added to a sanitary ware body recipe at 1–10% weight in place of albite and kaolin content. In an attempt to investigate the effects of its utilization on the firing temperature of the body, the bodies were sintered at the temperatures 1200 °C and 1250 °C. The physical properties, such as deformation, water absorption, and coloring parameters were investigated. The phase and microstructural development of the selected samples were characterized using XRD and SEM, respectively. Experimental studies have shown that the utilization of galvanized waste at an optimum level, in place of albite and kaolin in sanitary ware bodies sintered at 1200 °C, has similar water absorption (%), lower deformation, and higher whiteness values compared with standard sanitary ware bodies sintered at 1250 °C. It was foreseen that a 4.75% energy saving would be achieved by decreasing the firing temperature from 1250 to 1200 °C.
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References
Bright, M.A., Deem, N.J., Fryatt, J.: The advantages of recycling metallic zinc from the processing wastes of industrial molten zinc applications. In: The Minerals, Metals and Materials Society (ed.) 2007 TMS Annual Meeting & Exhibition, pp. 101–109, Orlando (2007)
Gordon, R.B., Graedel, T.E., Bertram, M., Fuse, K., Lifset, R., Rechberger, H., Spatari, S.: The characterization of technological zinc cycles. Resour Conserv Recycl. 39(2), 107–135 (2003)
Perl, A.S.: Zinc oxide. Am Ceram Soc Bull. 80(8), 106–107 (2001)
Göncü, Y.: Investigation of the usage of wastes containing ZnO in crystal glazes. Master of Science Thesis, Anadolu University, Eskişehir (2006)
Karasu, B.: Macrostructure harmonie of various coloring oxides in soft porcelain zinc oxide crystal glazes. J Ceram Art Sci Tech Turkish Ceram Soc. 14, 33–35 (2001)
Karasu, B., Çakı, M., Turan, S.: The development and characterisation of zinc crystal glazes used for Amakusa-like soft porcelains. J Eur Ceram Soc. 20(12), 2225–2231 (2000)
Karasu, B., Çakı, M., Yeşilbaş, Y.G.: The effect of albite wastes on glaze properties and microstructure of soft porcelain zinc crystal glazes. J Eur Ceram Soc. 21(8), 1131–1138 (2001)
Karasu, B., Turan, S.: Effects of cobalt, copper, manganese and titanium oxide additions on the microstructures of zinc containing soft porcelain glazes. J Eur Ceram Soc. 22(9–10), 1447–1455 (2002)
Öztürk, Z.B., Atay, B., Çakı, M., Ay, N.: An investigation of color development by means of the factorial design in wall tile glazes with ferrochromium fly ash. Indian J Eng Mater S. 22, 215–224 (2015)
Yıldız, B., Ozturk, Z.B., Kara, A.: Effects of alumina and white fused alumina addition on transparent wall and floor tile glazes. Acta Phys Pol A. 127, 1000–1004 (2015)
Tulyaganov, D.U., Agathopoulos, S., Fernandes, H.R., Ferreira, J.M.F.: The influence of incorporation of ZnO-containing glazes on the properties of hard porcelains. J Eur Ceram Soc. 27(2–3), 1665–1670 (2007)
Mondal, A.: Effect of incorporation of ZnO containing glaze on the densification of porcelain. Indoceram. 48(2), 42–45 (2012)
Capoglu, A.: Elimination of discoloration in reformulated bone China bodies. J Eur Ceram Soc. 25(13), 3157–3164 (2005)
Lee, S.-M., Kim, S.-K., Yoo, J.M., Kim, H.-T.: Crystallization behavior and mechanical properties of porcelain bodies containing zinc oxide additions. J Eur Ceram Soc. 25(11), 1829–1834 (2005)
Eren, E.: Investigation of zinc oxide addition into a porcelain body. Master of Science Thesis, Anadolu University, Eskişehir (2006)
http://www.mebmetal.com/hammaddeler/galvaniz-elek-alti-kulu/. Accessed 12 Feb 2017
Güngör, E., Işık, İ., Güngör, F.: A preliminary study for utilization of the galvanized wastes in the vitrified bodies. In: Karasu, B. (ed.) Proceedings of the 1st International Ceramic, Glass, Porcelain, Enamel, Glaze and Pigment Congress (SERES’09), pp. 977–984. Ongar Electronic Print and Photocopy Center, Eskişehir (2009)
Conserva, L.R.D.S., Melchiades, F.G., Nastri, S., Boschi, A.O., Dondi, M., Guarini, G., Raimondo, M., Zanelli, C.: Pyroplastic deformation of porcelain stoneware tiles: wet vs. dry processing. J Eur Ceram Soc. 37(1), 333–342 (2017)
Yekta, B.E., Marghussian, V.K.: Sintering of β. qss and gahnite glass ceramics. J Eur Ceram Soc. 19(16), 2963–2968 (1999)
Güngör, F.: Investigation of pyroplastic deformation of whitewares: effect of crystal phases in the “CaO” based glassy matrix. Ceram Int. 44(11), 13360–13366 (2018)
Tkalcec, E., Kurajica, S., Ivankovic, H.: Crystallization behavior and microstructure of powdered and bulk ZnO-Al2O3-SiO2 glass-ceramics. J Non-Cryst Solids. 351(2), 149–157 (2005)
Richerson, D.W.: Modern Ceramic Engineering, Properties, Processing, and Use in Design. Taylor and Francis Group, Boca Raton, FL (2006)
Sharifzade, S., Clemmensen, L.H., Borggaard, C., Støier, S., Ersbøll, B.K.: Supervised feature selection for linear and non-linear regression of L*a*b* color from multispectral images of meat. Eng Appl Artif Intell. 27, 211–227 (2014)
Tuncel, D.Y., Özel, E.: Evaluation of pyroplastic deformation in sanitaryware porcelain bodies. Ceram Int. 38(2), 1399–1407 (2012)
Lee, W.E., Iqbal, Y.: Influence of mixing on mullite formation in porcelain. J Eur Ceram Soc. 21(14), 2583–2586 (2001)
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Gungor, F., Isik, I., Gungor, E. et al. Usage of ZnO containing wastes in the sanitaryware bodies. J Aust Ceram Soc 55, 857–863 (2019). https://doi.org/10.1007/s41779-018-00300-8
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DOI: https://doi.org/10.1007/s41779-018-00300-8