Abstract
Preparation and characterization of glass–ceramics based on CaO–Al2O3–B2O3 system, modified by replacing CaO by different alkali and alkaline earth oxides, and In2O3/Al2O3 substitustion were implemented. Different crystalline phases, including β-CaAl2B2O7, Na2Al2B2O7, LiAl5O8, Li4Al4B6O17, Li2AlBO4, SrAl2B2O7, BaAl2B2O7, α-(Ca1-x,Inx)Al2B2O7, and InBO3, were developed from the heat-treated glasses. The incorporation of In3+ in the position of Ca2+ in β-CaAl2B2O7 crystal lattice was responsible for phase transition of β-CaAl2B2O7 to α-CaAl2B2O7 phase. The coefficient of thermal expansion CTE of prepared glass–ceramics was between −65 × 10−7 and 72 × 10−7 K−1 in the temperature range from 25 to 600 °C. The glass–ceramic specimens containing XAl2B2O7 as the principal crystalline phase were characterized by negative CTE values. In contrast, the replacement of CaO in the base glass by alkali oxides like Na2O and Li2O led to a dramatic transformation of the negative CTE to postive values. The complete replacement of calcium oxide in the base glass by various alkali and alkaline earth oxides markedly decreased the chemical durability of the investigated glass–ceramic specimens, while substitution of Al2O3 by In2O3 resulted in improving the chemical stability of the crystalline samples. The density of the glass specimens were found to be within the range 2.35–3.38 g/cm3, while the density of the glass–ceramic samples was in the range of 2.37–3.13 g/cm3.
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García-Moreno, O., Kriven, W.M., Moya, J.S., Torrecillas, R.: Alumina region of the lithium aluminosilicate system: a new window for temperature ultrastable materials design. J. Am. Ceram. Soc. 96, 2039–2041 (2013)
Chen, J.C., Huang, G.C., Hu, C., Weng, J.P.: Synthesis of negative-thermal expansion ZrW2O8 substrates. Scr. Mater. 49, 261–266 (2003)
Petzold, J., Pannhorst, W.: Chemistry and structure of glass-ceramic materials for high precision optical applications. J. Non-Cryst. Solids. 129, 191–198 (1991)
Montazerian, M., Singh, S.P., Zanotto, E.D.: An analysis of glass-ceramic research and commercialization. Am. Ceram. Soc. Bull. 94, 30–35 (2015)
Knickrbocker, S.H., Kumar, A.H., Herron, L.W.: Cordierite glass-ceramics for multilayer ceramic packaging. Am. Ceram. Soc. Bull. 72, 90–95 (1993)
Lin, J.B., Chen, D.M.: Effect of host composition on luminescent properties of activated SrAl2B2O7 phosphors. J. Chin. Soc. Rare Earths. 19, 498–501 (2001)
Hovhannisyan, R.M.: Rafaelites-new kind of glass ceramics with low thermal expansion and low melting temperatures on the basis of alkaline earth aluminium borates. Glass Technol. 44, 96–100 (2003)
MacDowell, J.F.: Aluminoborate glass-ceramics with low thermal Expansivity. J. Am. Ceram. Soc. 73, 2287–2292 (1990)
Li, C., Su, Q.: A new blue phosphorescent glass–ceramic: rare-earth-doped calcium aluminoborate. J. Alloys Compd. 408–412, 875–878 (2006)
Liang, X., Yang, Y., Wang, S., Chen, G.: Luminescence properties of Tb3+/Sm3+ codoped 38B2O3―31Al2O3―31SrO glasses and glass ceramics. J. Non-Cryst. Solids. 357, 2255–2258 (2011)
Salama, S.N., Salman, S.M.: Chemical stability of some manganese glass-ceramics. Mater. Chem. Phys. 37, 338–343 (1994)
Salman, S.M., Salama, S.N., Abo-Mosallam, H.A.: Crystallization of pyroxene phases and physico-chemical properties of glass-ceramics based on Li2O-Cr2O3- SiO2 eutectic glass system. Mater. Chem. Phys. 149-150, 385–392 (2015)
Kuryaeva, R.G., Dmitrieva, N.V.: Effect of the replacement of sodium by calcium on compressibility in the CaO(Na2O)–Al2O3–SiO2 glass system. Phys. Chem. Glasses. 55, 253–260 (2014)
Shannon, R.D.: Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr. A32, 751–767 (1976)
Hill, R.G., Stamboulis, A., Law, R.V., Clifford, A., Towler, M.R., Crowley, C.: The influence of strontium substitution in fluoroapatite glasses and glass–ceramics. J. Non-Cryst. Solids. 336, 223–229 (2004)
Catauro, M., Gargano, S., Laudisio, G.: The non-isothermal devitrifcation of glasses in the CaO-4GeO2-BaO-4GeO2 composition range. Thermochim. Acta. 356, 127–131 (2000)
McMillan, P.W.: Glass Ceramics, 2nd edn. Academic Press, London (1979)
Chang, K.-S., Keszler, D.A.: CaAl2(BO3)2O: crystal structure. Mater. Res. Bull. 33, 299–304 (1998)
Yang, H., Li, C., He, H., Zhang, G., Qi, Z., Su, Q.: Luminescent properties of RE3+-activated CaAl2B2O7 (RE=Tb, Ce) in VUV-visible region. J. Lumin. 124, 235–240 (2007)
Hovhannisyan, R.M., Geodakyan, J.A., Petrosyan, B.V., Toroyan, V.P., Abramyan, Z.M., Knyasyan, N.B., Israelyan, V.R., Mkhitaryan, R.G.: Processes of borate formation taking place in batches of alkaline earth aluminium borate glasses. Glass Technol. 44, 101–104 (2003)
He, M., Chen, X.L., Zhou, T., Hu, B.Q., Xu, Y.P., Xu, T.: Crystal structure and infrared spectra of Na2Al2B2O7. J. Alloys Compd. 327, 210–214 (2001)
Lucas, F., Jaulmes, S., Quarton, M., Le Mercier, T., Guillen, F., Fouassier, C.: Crystal structure of SrAl2B2O7 and Eu2+ luminescence. J. Solid State Chem. 150, 404–409 (2000)
Ye, N., Zeng, R., Wu, B.C., Huang, X.Y., Chen, C.T.: Crystal structure of barium aluminium borate, BaAl2B2O7. Z. Kristallogr. NCS. 213, 452 (1998)
Barth, T.F.: Theoretical Petrology, 2nd edn. John Wiley & Sons, Inc, New York (1962)
Thakur, J., Dutta, D.P., Bagla, H., Tyagi, A.K.: Effect of host structure and concentration on the luminescence of Eu3+ and Tb3+ in borate phosphors. J. Am. Ceram. Soc. 95, 696–704 (2012)
Salman, S.M., Salama, S.N., Abo-Mosallam, H.A.: Contribution of some divalent oxides replacing Li2O to crystallization characteristics and properties of magnetic glass–ceramics based on Li2O–Fe2O3–Al2O3–SiO2. Ceram. Int. 42, 8650–8656 (2016)
Tauch, D., Russel, C.: Glass–ceramics with zero thermal expansion in the system BaO/Al2O3/B2O3. J. Non-Cryst. Solids. 351, 2294–2298 (2005)
Satyanarayana Murthy, K., Krishna Rao, K.V.: Thermal expansion of indium borate. J. Mater. Sci. 12, 1054–1055 (1977)
Demirkesen, E., Goller, G.: Effect of Al2O3 additions on the acid durability of a Li2O-ZnO-SiO2 glass and its glass-ceramic. Ceram. Int. 29, 463–469 (2003)
Garkova, R., Vӧlksch, G., Russel, C.: Precipitation of SnO2 nano-crystallites from Na2O/B2O3/SnO2/(Al2O3) glasses. J. Non-Cryst. Solids. 351, 2287–2293 (2005)
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Salman, S.M., Salama, S.N. & Abo-Mosallam, H.A. Crystallization features and physico-chemical properties of alkali and alkaline aluminoborate glass–ceramics. J Aust Ceram Soc 53, 953–961 (2017). https://doi.org/10.1007/s41779-017-0111-1
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DOI: https://doi.org/10.1007/s41779-017-0111-1