Abstract
In the world, the pollution of our environment is a global phenomenon, caused by the increase of industrial effluents discharged into the atmosphere. Moreover, the textile industry, containing a lot of dye, produces troubles, most of which are toxic and non-degradable substances. Therefore, low-cost processes are used to remove these substances, such as adsorption processes. The aim of this research is to study the adsorption of methylene blue dye on powdered activated carbon prepared from spent coffee grounds, in an attempt to prove its potential as a lower cost adsorbent in the treatment of dyed water. Adsorption experiments suggested that the time to equilibrium was influenced by the initial concentration of the dye. Therefore, equilibrium is reached after 10, 20 and 30 min respectively, for methylene blue solutions at 15, 30 and 50 mg/L at pH 5.8. The whole results of the adsorption of methylene blue dye on activated carbon powder are described pseudo-second-order kinetics. The adsorption data were modeled by Langmuir, Freundlich, Temkin and Dubinin–Radushkevich adsorption isotherms. The thermodynamic parameters of the adsorbent/adsorbate system under study reveal that the adsorption process is spontaneous and endothermic in character.
Similar content being viewed by others
References
Aarfane A, Salhi A, El Krati M, Tahiri S, Monkade M, Lhadi EK, Bensitel M (2014) Kinetic and thermodynamic study of the adsorption of Red195 and methylene blue dyes on fly ash and bottom ash in aqueous medium. J Mater Environ Sci 5(6):1927–1939
Ahmad AL, Loh MM, Aziz JA (2007) Preparation and characterization of activated carbon from oil palm wood and its evaluation on methylene blue adsorption. Dyes Pigm 75(2):263–272
Ahmed MJ, Dhedan SK (2012) Equilibrium isotherms and kinetics modeling of methylene blue adsorption on agricultural wastes-based activated carbons. Fluid Phase Equilib 317:9–14
Amuda OS, Amoo IA (2007) Coagulation/flocculationprocess and sludgeconditioning in beverageindustrial wastewater treatment. J Hazard Mater 141(3):778–783
Attia AA, Girgis BS, Fathy NA (2008) Élimination du bleu de méthylène par les charbons dérivés des noyaux de pêche par activation H3PO4: études en batch et en colonne. Colorants Et Pigments 76(1):282–289
Baquero MC, Giraldo L, Moreno JC, Suarez-Garcıa F, Martınez-Alonso A, Tascon JMD (2003) Activated carbons by pyrolysis of coffee bean husks in presence of phosphoric acid. J Anal Appl Pyrol 70(2):779–784
Batchelor-McAuley C, Dickinson EJ, Rees NV, Toghill KE, Compton RG (2012) New electrochemical methods. Anal Chem 84(2):669–684
Benhafsa FM, Kacha S, Leboukh A, Belaid KD (2018) Comparative study of Victoria Blue Basic dye adsorption from aqueous solutions using used cardboard and sawdust. Revue des sciences de l’eau: J Water Sci 31(2):109–126
Benyaba A, Alioua M, Chergui Y (2020) Adsorption isotherme et thermodynamique du colorant organique (Rhodamine B). Doctoral dissertation, universite Ahmed Draia-ADRAR
Berrios M, Martin MA, Martin A (2012) Treatment of pollutants in wastewater: adsorption of methylene blue onto olive-based activated carbon. J Ind Eng Chem 18(2):780–784
Bouhamed F, Elouear Z, Bouzid J (2012) Adsorptive removal of copper(II) from aqueous solutions on activated carbon prepared from Tunisian date stones: equilibrium, kinetics and thermodynamics. J Taiwan Inst Chem Eng 43(5):741–749
Cazetta AL, Vargas AM, Nogami EM, Kunita MH, Guilherme MR, Martins AC et al (2011) NaOH-activated carbon of high surface area produced from coconutshell: Kinetics and equilibriumstudies from the methyleneblue adsorption. Chem Eng J 174(1):117–125
Dada AO, Olalekan AP, Olatunya AM, Dada OJIJC (2012) Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk. IOSR J Appl Chem 3(1):38–45
Dubinin MV, Starinets VS, Talanov EY, Mikheeva IB, Belosludtseva NV, Belosludtsev KN (2021) Alisporivir improves mitochondrial function in skeletal muscle of mdx mice but suppresses mitochondrial dynamics and biogenesis. Int J Molec Sci 22(18):9780
El-Hendawy ANA, Samra SE, Girgis BS (2001) Adsorption characteristics of activated carbons obtained from corncobs. Colloids Surf, A 180(3):209–221
Eskander S, Saleh HED (2017) Biodegradation: process mechanism. Environ Sci Eng 8(8):1–31
Forgacs E, Cserháti T, Oros G (2004) Removal of synthetic dyes from wastewaters: a review. Environ Int 30(7):953–971
Galanakis CM (ed) (2017) Handbook of coffee processing by-products: sustainable applications. Academic Press, New York
Gupta VK (2009) Application of low-cost adsorbents for dye removal–a review. J Environ Manag 90(8):2313–2342
Hamdaoui O (2006) Batch study of liquid-phase adsorption of methylene blue using cedar sawdust and crushed brick. J Hazard Mater 135(1–3):264–273
Ho YS, McKay G (1998) A comparison of chemisorption kinetic modelsapplied to pollutantremoval on varioussorbents. Process Saf Environ Prot 76(4):332–340
Hu Z, Chen H, Ji F, Yuan S (2010) Removal of Congo red from aqueous solution by cattail root. J Hazard Mater 173(1–3):292–297
Kansara N, Bhati L, Narang M, Vaishnavi R (2016) Wastewater treatment by ion exchange method: a review of past and recent researches. ESAIJ Environ Sci Indian J 12(4):143–150
Kaykhaii M, Sasani M, Marghzari S (2018) Removal of dyes from the environment by adsorption process. Chem Mater Eng 6(2):31–35
Krapivin VF, Varotsos CA (2016) Modelling the CO2 atmosphere-ocean flux in the upwelling zones using radiative transfer tools. J Atmos Solar Terr Phys 150:47–54
Kumar A, Prasad B, Mishra IM (2008) Adsorptiveremoval of acrylonitrile by commercial grade activatedcarbon: kinetics, equilibrium and thermodynamics. J Hazard Mater 152(2):589–600
Kyzas GZ, Lazaridis NK, Mitropoulos AC (2012) Removal of dyes from aqueous solutions with untreated coffee residues as potential low-cost adsorbents: equilibrium, reuse and thermodynamic approach. Chem Eng J 189:148–159
Laine J, Calafat A (1989) Preparation and characterization of activated carbons from coconut shell impregnated with phosphoric acid. Carbon 27(2):191–195
Malik SN, Ghosh PC, Vaidya AN, Mudliar SN (2020) Hybrid ozonation process for industrial wastewater treatment: principles and applications: a review. J Water Process Eng 35:101193
Mallevialle J, Odendaal PE, Wiesner MR (eds) (1996) Water treatment membrane processes. American Water Works Association, Denver
Namane A, Mekarzia A, Benrachedi K, Belhaneche-Bensemra N, Hellal A (2005) Determination of the adsorption capacity of activated carbon made from coffee grounds by chemical activation with ZnCl2 and H3PO4. J Hazard Mater 119(1–3):189–194
Önal Y (2006) Kinetics of adsorption of dyes from aqueous solution using activated carbon prepared from waste apricot. J Hazard Mater 137(3):1719–1728
Rai HS, Bhattacharyya MS, Singh J, Bansal TK, Vats P, Banerjee UC (2005) Removal of dyes from the effluent of textile and dyestuff manufacturing industry: a review of emerging techniques with reference to biological treatment. Crit Rev Environ Sci Technol 35(3):219–238
Rangabhashiyam S, Anu N, Selvaraju N (2013) Sequestration of dye from textile industry wastewater using agricultural waste products as adsorbents. J Environ Chem Eng 1(4):629–641
Rivas FJ, Beltrán F, Carvalho F, Acedo B, Gimeno O (2004) Stabilized leachates: sequential coagulation–flocculation+ chemical oxidation process. J Hazard Mater 116(1–2):95–102
Rosson E, Sgarbossa P, Mozzon M, Venturino F, Bogialli S, Glisenti A et al (2021) Novel correlations between spectroscopic and morphological properties of activated carbons from waste coffee grounds. Processes 9(9):1637
Suárez-Garcıa F, Martınez-Alonso A, Tascón J (2001) Porous texture of activated carbons prepared by phosphoric acid activation of apple pulp. Carbon 7(39):1111–1115
Tavlieva MP, Genieva SD, Georgieva VG, Vlaev LT (2013) Kinetic study of brilliant green adsorption from aqueous solution onto white rice husk ash. J Colloid Interface Sci 409:112–122
Ubago-Pérez R, Carrasco-Marín F, Fairén-Jiménez D, Moreno-Castilla C (2006) Granular and monolithic activated carbons from KOH-activation of olive stones. Microporous Mesoporous Mater 92(1–3):64–70
Valix M, Cheung WH, McKay G (2004) Preparation of activated carbon using low temperature carbonisation and physical activation of high ash raw bagasse for acid dye adsorption. Chemosphere 56(5):493–501
Varotsos CA, Krapivin VF (2018) Pollution of Arctic waters has reached a critical point: an innovative approach to this problem. Water Air Soil Pollut 229(11):1–14
Varotsos CA, Zellner R (2010) A new modeling tool for the diffusion of gases in ice or amorphous binary mixture in the polar stratosphere and the upper troposphere. Atmos Chem Phys 10(6):3099–3105
Varotsos CA, Krapivin VF, Mkrtchyan FA (2019) New optical tools for water quality diagnostics. Water Air Soil Pollut 230(8):1–12
Wang CH, Wen WC, Hsu HC, Yao BY (2016) High-capacitance KOH-activated nitrogen-containing porous carbon material from waste coffee grounds in supercapacitor. Adv Powder Technol 27(4):1387–1395
Yagmur E, Ozmak M, Aktas Z (2008) A novel method for production of activated carbon from waste tea by chemical activation with microwave energy. Fuel 87(15–16):3278–3285
Youssef AM, El-Khouly SM, El-Nabarawy TH (2008) Removal of Pb(II) and Cd(II) from aqueous solution using oxidized activated carbons developed from pecan shells. Carbon Lett 9(1):8–16
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of Interest
The authors declare that they have no conflict of interest.
Rights and permissions
Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Azzouni, D., Saoudi Hassani, E.M., Rais, Z. et al. An Excellent Alternative to Industrial Activated Carbons for the Purification of Textile Water Elaborated from Waste Coffee Grounds. Int J Environ Res 16, 89 (2022). https://doi.org/10.1007/s41742-022-00477-8
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s41742-022-00477-8