Skip to main content

Advertisement

Log in

Failure Analysis of a Cracked Hydrogen Reformer Tube

  • Original Article
  • Published:
Transactions of the Indian National Academy of Engineering Aims and scope Submit manuscript

Abstract

The paper presents analysis of failure in a reformer tube used for hydrogen generation in a petro-chemical industry. The tube, which was manufactured by centrifugal casting of Nb-modified 25Cr35Ni alloy, developed a longitudinal crack of 200 mm length after 61,500 h of service against a design life of 100,000 h. Microstructural studies on the damaged tube material revealed presence of innumerable number of small planar cracks aligned parallel to the main crack. The damages in the material include formation of voids and cracks around the carbide particles at inter-dendritic regions. The microstructural changes observed in the tube material are typical of creep damage in 25Cr35Ni alloy. Study revealed that coalescence of voids led to the formation of small cracks and these cracks grew predominantly in radial directions in the bulk of the tube-wall. Some of the localized cracks joined to form a major crack in the longitudinal direction of the tube. Through microstructural studies, it was established that the failure in the reformer tube occurred due to exposure to temperatures higher than the safe operating temperature for a prolonged period of time.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  • Abbas B, Peyman T (2019) Creep failure of reformer tubes in a petrochemical plant. Metals. https://doi.org/10.3390/met9101026:1-8

    Article  Google Scholar 

  • Andrade AR, Bolfarini C, Ferreira LAM, Vilar AAA, Souza Filho CD, Bonazzi LHC (2015) Influence of niobium addition on the high temperature mechanical properties of a centrifugally cast HP alloy. Mater Sci Eng A 628:176–180

    Article  Google Scholar 

  • Davis JR (1997) High-alloy cast steels. In: Davis JR (ed) Heat resistant materials. ASM International, Materials Park, pp 201–218

    Google Scholar 

  • De Almeida LH, Ribeira AF, May IL (2003) Microstructural characterization of modified 25Cr–35Ni centrifugally cast steel furnace tubes. Mater Charact 49:219–229

    Article  Google Scholar 

  • Huber J, Jacobi D (2011) Centricast materials for high-temperature service. In: International conference and exhibition on (nitrogen + syngas) 2011, pp 117–121

  • Jian-hua P, Zeng C, Zhi-cao F, Yu-cheng W (2018) AN experimental investigation on manifold failure and material deterioration. Int J Press Vessels Pip 168:1–10

    Article  Google Scholar 

  • Kenik EA, Maziasz PJ, Swindeman RW, Cervenka J, May D (2003) Structure and phase stability in a cast modified-HP austenite after long-term ageing. Script Mater 49:117–122

    Article  Google Scholar 

  • Liu CJ, Chen Y (2011) Variations of the microstructure and mechanical properties of HP40Nb hydrogen reformer tube with time at elevated temperature. Mater Des 32:2507–2512

    Article  Google Scholar 

  • Mikulowski B, Zapala R, Glownia J, Wilk P (2013) Structure and properties of the centrifugally cast high-alloyed (25Cr35NiNb) steel after long-time operation in steam reforming. Arch Metall Mater 58:785–790

    Article  Google Scholar 

  • Mostafaei M, Shamanian M, Purmohamad H, Amini M, Saatchi A (2011) Microstructural degradation of two cast heat resistant reformer tubes after long term service exposure. Eng Fail Anal 18:164–171

    Article  Google Scholar 

  • Qu WuX, Yang YS, Zhan Q, Hu ZQ (1998) Structure degradation of 25Cr35Ni heat-resistant tube associated with surface coking and internal carburization. J Mater Eng Perfom 7:667–672

    Article  Google Scholar 

  • Vache N, Steyer P, Duret-Thual C, Perez M, Douillard T, Rauch E, Veron M, Renou G, Dupoiron F, Augustin C, Cazottes S (2020) Microstructural study of the NbC to G-phase transformation in HP–Nb alloys. Materialia 9:100593

    Article  Google Scholar 

  • Wang WZ, Xuan FZ, Wang ZD, Wang B, Liu CJ (2011) Effect of overheating temperature on the microstructure and creep behaviour of HP40Nb alloy. Mater Des 32:4010–4016

    Article  Google Scholar 

Download references

Funding

This study was funded by csir-nal (Grant number M-1-298).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Sujata.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Raghavendra, K., Venkatesh, V., Madan, M. et al. Failure Analysis of a Cracked Hydrogen Reformer Tube. Trans Indian Natl. Acad. Eng. 7, 689–697 (2022). https://doi.org/10.1007/s41403-022-00323-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s41403-022-00323-5

Keywords

Navigation