Abstract
In recent days, there is an increased interest in using alternative materials in cement to produce concrete with improved properties. Supplementary cementitious materials (SCMs), which are the alternative materials used in the production of cement, are mainly industrial wastes like fly ash (FA), ground-granulated blast furnace slag (GGBS) and silica fume, giving rise to sustainable construction practices. Numerous investigations have been performed on the utilisation of alternate materials in the production of cement that is used in concrete, and an enhancement in the performance of concrete has been reported. Composite cement, a novel material, finds application in construction in which a certain percentage of cement clinker is replaced by GGBS, FA and silica fume during its production. The drawback of the composite cement containing GGBS and FA is that it attains a lower strength at earlier ages. Alccofine, an ultrafine slag-based material collected as a residue from the iron industry, has also been utilised as an SCM in the production of cement. In this study, the effect of a partial replacement of composite cement (COC) with alccofine is examined. It was observed that 10% replacement of COC by alccofine increases the maximum compressive strength (CS), modulus of elasticity (MOE), split tensile strength (STS) and flexural strength (FS) of concrete, respectively, by 12.67%, 16.95%, 11.4% and 21.42% at 28 days. The formation of closely packed structure due to the finer particles of alccofine contributes to an improvement in the strength of concrete.
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References
Venkatakrishnaiah R, Sakthivel G (2015) Bulk utilization of flyash in self compacting concrete. KSCE J Civ Eng 19:2116–2120
Assi LN, Carter K, Deaver E, Ziehl P (2020) Review of availability of source materials for geopolymer/sustainable concrete. J Clean Prod 263:121477
Worrell E, Price L, Martin N et al (2001) Carbon dioxide emissions from the global cement industry. Annu Rev Energy Environ 26:303–329
Khozin V, Khokhryakov O, Nizamov R (2020) A «carbon footprint» of low water demand cements and cement-based concrete. In: IOP conference series: materials science and engineering. IOP Publishing, p 12105
Imbabi MS, Carrigan C, McKenna S (2012) Trends and developments in green cement and concrete technology. Int J Sustain Built Environ 1:194–216
Miah MJ, Huaping R, Paul SC et al (2023) Long-term strength and durability performance of eco-friendly concrete with supplementary cementitious materials. Innov Infrastruct Solut 8:255
Astm (2010) Standard specification for coal fly ash and raw or calcined natural pozzolan for use. Annu B ASTM Stand 3–6
Wang H, Liu X, Zhang Z (2023) Pozzolanic activity evaluation methods of solid waste: a review. J Clean Prod 402:136783
Singh GVPB, Subramaniam KVL (2019) Production and characterization of low-energy Portland composite cement from post-industrial waste. J Clean Prod 239:118024
Abdellatief M, Abd Elrahman M, Elgendy G, Bassioni G, Tahwia AM (2023) Response surface methodology-based modelling and optimization of sustainable UHPC containing ultrafine fly ash and metakaolin. Constr Build Mater 388:131696
Abdellatief M, Elemam WE, Alanazi H, Tahwia AM (2023) Production and optimization of sustainable cement brick incorporating clay brick wastes using response surface method. Ceram Int 49(6):9395–9411
Abdellatief M, Al-Tam SM, Elemam WE, Alanazi H, Elgendy GM, Tahwia AM (2023) Development of ultra-high-performance concrete with low environmental impact integrated with metakaolin and industrial wastes. Case Stud Constr Mater 18:e01724
Radwan MKH, Onn CC, Mo KH, et al (2020) Eco-mechanical performance of binary and ternary cement blends containing fly ash and slag. In: Proceedings of the institution of civil engineers-engineering sustainability. Thomas Telford Ltd, pp 23–36
Zou F, Hu C, Wang F et al (2020) Enhancement of early-age strength of the high content fly ash blended cement paste by sodium sulfate and C-S–H seeds towards a greener binder. J Clean Prod 244:118566
Fanghui H, Qiang W, Jingjing F (2015) The differences among the roles of ground fly ash in the paste, mortar and concrete. Constr Build Mater 93:172–179
Mo KH, Ling T-C, Alengaram UJ et al (2017) Overview of supplementary cementitious materials usage in lightweight aggregate concrete. Constr Build Mater 139:403–418
Özbay E, Erdemir M, Durmuş Hİ (2016) Utilization and efficiency of ground granulated blast furnace slag on concrete properties—a review. Constr Build Mater 105:423–434
Łukowski P, Salih A (2015) Durability of mortars containing ground granulated blast-furnace slag in acid and sulphate environment. Procedia Eng 108:47–54
Feiz R, Ammenberg J, Baas L et al (2015) Improving the CO2 performance of cement, part I: utilizing life-cycle assessment and key performance indicators to assess development within the cement industry. J Clean Prod 98:272–281
Sharma P, Sharma SK, Rambabu D, Reddy BSP (2023) A detailed laboratory investigation on evolving the mix design of roller compacted concrete containing RAP aggregates and SCMs. Innov Infrastruct Solut 8:284
Rather SA, Sharma N, Najar IA (2019) Effects of rice husk ash (RHA) and alccofine-1101 on stabilization of clay soil. Int Res J Eng Technol 6:474–478
Dutta RK, Yadav JS (2021) The impact of alccofine inclusion on the engineering properties of bentonite. Clean Eng Technol 5:100301
Srinath BLNS, Patnaikuni CK, Balaji K et al (2021) A prospective review of alccofine as supplementary cementitious material. Mater Today Proc 47:3953–3959
Ramkrishnan R, Abilash B, Trivedi M et al (2018) Effect of mineral admixtures on pervious concrete. Mater Today Proc 5:24014–24023
Jayswal SD, Mungule M (2022) Performance assessment of Alccofine with silica fume, fly ash and slag for development of high strength mortar. Front Struct Civ Eng 16:576–588
Suthar Sunil B, Shah BK (2013) Study on strength development of high strength concrete containing alccofine and fly-ash. Indian J Res 2:102–104
Swaroop AHL, Venkateswararao K, Kodandaramarao P (2013) Durability studies on concrete with fly ash & Ggbs. Int J Eng Res Appl 3:285–289
Rout MKD, Biswas S, Sinha AK (2021) Mechanical and durability properties of alccofine used in reclaimed asphalt concrete pavements (RACP). In: Advances in sustainable construction materials: select proceedings of ASCM 2020. Springer, pp 131–142
Balamuralikrishnan R, Saravanan J (2021) Effect of addition of alccofine on the compressive strength of cement mortar cubes. Emerg Sci J 5:155–170
Srinath BLNS, Patnaikuni CK (2022) Concrete properties evaluated by replacing cement with alccofine. Int J Eng Sci Technol 6(1):91–97
Rajesh Kumar S, Samanta AK, Roy DKS (2015) An experimental study on the mechanical properties of alccofine based high grade concrete. Int J Multidiscip Res Dev 2:218–224
Venkatesan B, Venuga M, Dhevasenaa PR, Kannan V (2021) Experimental study on concrete using partial replacement of cement by Alccofine fine aggregate as iron powder. Mater Today Proc 37:2183–2188
Gautam M, Sood H (2017) Effect of alccofine on strength characteristics of concrete of different grades—a review. Int Res J Eng Technol 4:2854–2857
Srinivasan G (2020) Study on alccofine based high performance concrete. In: IOP conference series: materials science and engineering. IOP Publishing, p 12040
Harish B, Dakshinamurthy NR, Sridhar M, Rao KJ (2022) A study on mechanical properties of high strength concrete with alccofine as partial replacement of cement. Mater Today Proc 52:1201–1210
Chakravarthy PRK, Raj RR (2017) Analysis on compressive strength of concrete with partial replacement of cement with alccofine. ARPN J Eng Appl Sci 12(8):2392–2395
Suthar S, Shah BK, Patel PJ (2013) Study on effect of alccofine & fly ash addition on the mechanical properties of high performance concrete. Int J Sci Res Dev 1:464–467
Kumar R, Muthupriya P, Venkatsubramani R (2013) The experimental investigating on durability characteristics of high performance concrete. Int J Sci Tech Res 3:239–250
Soni D, Kulkarni S, Parekh V (2013) Experimental study on high-performance concrete, with mixing of alccofine and flyash. Indian J Res 3:84–86
Sagar B, Sivakumar MVN (2021) Use of alccofine-1203 in concrete: review on mechanical and durability properties. Int J Sustain Eng 14:2060–2073
Kavitha S, Kala TF (2016) Evaluation of strength behavior of self-compacting concrete using alccofine and GGBS as partial replacement of cement. Indian J Sci Technol 9:1–5
Kavyateja BV, Jawahar JG, Sashidhar C (2020) Effectiveness of alccofine and fly ash on mechanical properties of ternary blended self compacting concrete. Mater Today Proc 33:73–79
Ansari US, Chaudhri IM, Ghuge NP, Phatangre RR (2015) High performance concrete with partial replacement of cement by alccofine and fly ash. Indian Res Trans 5:19–23
Reddy MVS, Ashalatha K, Surendra K (2016) Studies on eco-friendly concrete by partial replacement of cement with Alccofine and fine Fly Ash. ARPN J Eng Appl Sci 11:3445–3448
Sambangi A, Kundeti N, Srimani R, Nadukuditi A (2023) Effect of fly ash and alccofine as cementitious materials on M40 grade concrete. Mater Today Proc
Reddy GGK, Ramadoss P (2020) Influence of alccofine incorporation on the mechanical behavior of ultra-high performance concrete (UHPC). Mater Today Proc 33:789–797
Upadhyay SP, Jamnu MA (2014) Effect on compressive strength of high performance concrete incorporating alccofine and fly ash. Int J Innov Res Dev 3:124–128
Saiya J, Tiwari A, Jagtap S (2018) Experimental investigation on effect of alccofine with flyash and GGBS on high performance concrete. Int Res J Eng Technol 5:2734–2739
Massazza F (1998) Pozzolana and pozzolanic cements. Lea’s Chem Cem Concr 4:471–631
Moranville-Regourd M (1998) Cements made from blast-furnace slag, Lea’s Chemistry of Cement and Concrete Ed. PC 633:674
Desha C, Robinson D, Sproul A (2015) Working in partnership to develop engineering capability in energy efficiency. J Clean Prod 106:283–291
BS 3892 (Part 1) Pulverized-fuel ash part 1: specification for pulverized-fuel ash for use with portland cement
BS: 6699-1992 Ground granulated blastfurnace slag for use with portland cement
BS 12/1996 Specification of ordinary portland cement british standard
IS 16415:2015 BIS certification for composite cement
Teja VP, Brahma Chari KJ, Rao VR (2019) Experimental research on composite cement with glass fibers. Int J Recent Technol Eng 7:278–283
Zajac M, Skocek J, Durdzinski P et al (2020) Effect of carbonated cement paste on composite cement hydration and performance. Cem Concr Res 134:106090
IS-10262:2019 Concrete mix proportioning—guidelines
Khan AA, Al Kheraif AAA, Jamaluddin S, et al (2017) Recent trends in surface treatment methods for bonding composite cement to zirconia: a review. J Adhes Dent 19
Türkel S, Alabas V (2005) The effect of excessive steam curing on portland composite cement concrete. Cem Concr Res 35:405–411
IS: 12269-1987 Ordinary portland cement, 53 grade—specification
Jamenraja MCK, Ravichandran K (2023) Structural performance of polypropylene fibre-reinforced concrete beams incorporating nanosilica and alccofine. Innov Infrastruct Solut 8:191
ASTM C989-99 Standard specification for ground granulated blast-furnace slag for use in concrete and mortars
IS:383 (1970) Specification for coarse and fine aggregates from natural sources for concrete. Indian Stand 1–24
IS-1199-1959 Slump test of fresh concrete to measure workability
IS 516 (2021) Method of tests for strength of concrete. Bur Indian Stand 1–30
IS 456 (2000) Plain concrete and reinforced. Bur Indian Stand Dehli 1–114
IS-5816:1959 Splitting tensile strength of concrete—method of test
Amarkhail N (2015) Effects of silica fume on properties of high-strength concrete. Int J Tech Res Appl 32:13–19
Srinath BLNS, Patnaikuni CK, Santhosh KB et al (2022) Strength effect of alccofine on ordinary and standard grade concrete mixes. Int J Adv Technol Eng Explor 9:47
Vijayan DS, Arvindan S, Janarthanan TS (2020) Evaluation of ferrock: a greener substitute to cement. Mater Today Proc 22:781–787
Reddy AN, Meena T (2018) A study on compressive behavior of ternary blended concrete incorporating alccofine. Mater Today Proc 5:11356–11363
Reddy PN, Kavyateja BV, Kunamaneni V (2020) Effect of alccofine on the mechanical and durability performance of concrete. Authorea Preprints
Qureshi M, Tandel Y, Patel B (2013) An experimental study on high strength concrete using fly ash and alccofine. i-manager’s J Struct Eng 2:1
Chithra S, Kumar SRRS, Chinnaraju K (2016) The effect of colloidal nano-silica on workability, mechanical and durability properties of high performance concrete with copper slag as partial fine aggregate. Constr Build Mater 113:794–804
Sagar B, Sivakumar MVN (2020) An experimental and analytical study on alccofine based high strength concrete. Int J Eng 33:530–538
Bınıci H, Durgun MY, Rızaoğlu T, Koluçolak M (2012) Investigation of durability properties of concrete pipes incorporating blast furnace slag and ground basaltic pumice as fine aggregates. Sci Iran 19:366–372
Georget F, Wilson W, Scrivener KL (2021) edxia: microstructure characterisation from quantified SEM-EDS hypermaps. Cem Concr Res 141:106327
Tiecher F, Langoski M, Hasparyk N (2021) Behavior of mortars with different types of cement when induced to Delayed Ettringite Formation (DEF). Rev ALCONPAT 11:1–16
Srinath BLNS, Patnaikuni CK, Raghava Rao EV et al (2021) Microstructure analysis of M30 grade alccofine concrete. Int J Mech Eng 6(3):2030–2038
Senff L, Labrincha JA, Ferreira VM et al (2009) Effect of nano-silica on rheology and fresh properties of cement pastes and mortars. Constr Build Mater 23:2487–2491
Acknowledgements
We acknowledge SRM Institute of Science and Technology for high-resolution scanning electron microscope (HR-SEM) facility, XRD facility at SRMIST setup with support from The Ministry of New and Renewable Energy (Project No. 31/03/2014-15/PVSE-R&D), Government of India.
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BS contributed to conceptualization; data curation; methodology; investigation; roles/writing—original draft; and writing—review and editing. PRKR contributed to conceptualization; data curation methodology; supervision; validation; and writing—review and editing.
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Suresh, B., Rajkumar, P.R.K. Studies on the concrete with composite cement and alccofine: from use of OPC towards low-carbon quaternary binder. Innov. Infrastruct. Solut. 9, 129 (2024). https://doi.org/10.1007/s41062-024-01432-6
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DOI: https://doi.org/10.1007/s41062-024-01432-6