Abstract
This study presents an in-depth investigation into the utilization of granite waste as a partial replacement for the M-sand in geopolymer concrete in various proportions such as 5, 10, 15, and 20%. Geopolymer in this study is made using GGBS as the precursor material and RHA-based derivative as the activator solution. The experimental research focuses on geopolymer concrete that is activated using a derivative of rice husk ash (RHA). The primary objective is to assess the potential enhancement of mechanical properties and durability characteristics by incorporating granite waste powder. A series of tests were conducted to evaluate the effects of varying levels of granite waste powder and RHA derivative on properties such as compressive, tensile, and flexural strengths, water absorption, chloride penetration resistance, and resistance to acid attack. Followed by the scrupulous discussion part, SEM analysis is performed to determine the morphology of the optimum specimen. The research revealed enhanced mechanical and durability properties at 10% utilization of granite waste due to the improved microstructure with reduced porosity owing to the fine and angular nature of granite waste. Additionally, geopolymer concrete activated with the RHA derivative demonstrates promising potential as a sustainable alternative to conventional alkaline activators. These findings contribute valuable insights to the field, offering a sustainable approach to enhancing geopolymer concrete properties while minimizing environmental impact.
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Abbreviations
- GC:
-
Geopolymer concrete
- GGBS:
-
Ground granulated blast furnace slag
- FA:
-
Fly ash
- SEM:
-
Scanning electron microscopic
- GP:
-
Granite waste powder
- RCC:
-
Reinforced cement concrete
- SSA:
-
Specific surface area
- RHA:
-
Rice hush ash
- CS:
-
Compressive strength
- TS:
-
Tensile strength
- FS:
-
Flexural strength
- SSA:
-
Sugarcane straw ashes
- RCPT:
-
Rapid chloride penetration test
- ITZ:
-
Interfacial transition zone
References
Alex J, Dhanalakshmi J, Ambedkar B (2016) Experimental investigation on rice husk ash as cement replacement on concrete production. Constr Build Mater 127:353–362. https://doi.org/10.1016/j.conbuildmat.2016.09.150
Meyer C (2002) Concrete and sustainable development. ACI Mater J 94:409–416
Heath A, Paine K, McManus M (2014) Minimising the global warming potential of clay based geopolymers. J Clean Prod 78:75–83. https://doi.org/10.1016/j.jclepro.2014.04.046
Mikulčić H, Klemeš JJ, Vujanović M, Urbaniec K, Duić N (2016) Reducing greenhouse gasses emissions by fostering the deployment of alternative raw materials and energy sources in the cleaner cement manufacturing process. J Clean Prod 136:119–132. https://doi.org/10.1016/j.jclepro.2016.04.145
Flower DJM, Sanjayan JG (2007) Green house gas emissions due to concrete manufacture. Int J Life Cycle Assess 12:282–288. https://doi.org/10.1007/s11367-007-0327-3
Kajaste R, Hurme M (2016) Cement industry greenhouse gas emissions—management options and abatement cost. J Clean Prod 112:4041–4052. https://doi.org/10.1016/j.jclepro.2015.07.055
Turner LK, Collins FG (2013) Carbon dioxide equivalent (CO2-e) emissions: a comparison between geopolymer and OPC cement concrete. Constr Build Mater 43:125–130. https://doi.org/10.1016/j.conbuildmat.2013.01.023
Davidovits J (1994) GEOPOLYMERS: man-made rock geosynthesis and the resulting development of very early high strength cement. Mater Eduuc 16:1–25
Chithambar Ganesh MS, Muthukannan M, Rajeswaran M, Uma Shankar T (2018) Comparative study on the behavior of geopolymer concrete using M-sand and conventional concrete exposed to elevated temperature. Int. J. Civ. Eng. Technol. 9:981–989. https://doi.org/10.1021/je60086a034
Ganesh AC, Kumar MV, Mukilan K, Kumar AS (2022) Investigation on the effect of ultra fine rice husk ash over slag based geopolymer concrete. Res Eng Struct Mater. https://doi.org/10.17515/resm2022.501ma0814
Suresh Kumar A, Muthukannan M, Arunkumar K, Chithambar Ganesh A, Kanniga Devi R (2022) Utilisation of waste glass powder to improve the performance of hazardous incinerated biomedical waste ash geopolymer concrete. Innov Infrastruct Solut. https://doi.org/10.1007/s41062-021-00694-8
Suresh Kumar A, Muthukannan M, Irene ADKB, Arunkumar K, Chithambar GA (2022) Flexural behaviour of reinforced geopolymer concrete incorporated with hazardous heavy metal waste ash and glass powder. Mater Sci Forum 1048:345–358. https://doi.org/10.4028/www.scientific.net/MSF.1048.345
Chithambar Ganesh A, Muthukannan M (2019) Investigation on the glass fiber reinforced geopolymer concrete made of M-sand. J Mater Eng Struct 6:501–512
Arunkumar K, Muthukannan M, Kumar AS, Ganesh AC, Devi RK (2022) Cleaner environment approach by the utilization of low calcium wood ash in geopolymer concrete. Appl Sci Eng Prog 15:1–13. https://doi.org/10.14416/j.asep.2021.06.005
Ganesh AC, Mukilan K, Srikar BPV, Teja LVS, Prasad KSV, Kumar AA, Sharath RP (2022) Effect of flyash-rice husk ash blend in the energy efficient geopolymer tiles using industrial wastes. Mater Sci Forum 1048:403–411. https://doi.org/10.4028/www.scientific.net/MSF.1048.403
Ganesh C, Muthukannan M, Suresh Kumar A, Arunkumar K (2021) Influence of bacterial strain combination in hybrid fiber reinforced geopolymer concrete subjected to heavy and very heavy traffic condition. J Adv Concr Technol 19:359–369. https://doi.org/10.3151/jact.19.359
Chithambar Ganesh A, Vinod Kumar M, Kanniga Devi R, Srikar P, Prasad S, Manoj Kumar M, Sarath RP (2021) Pervious geopolymer concrete under ambient curing. Mater Today Proc 46:2737–2741. https://doi.org/10.1016/j.matpr.2021.02.425
Ganesh AC, Deepak N, Deepak V, Ajay S, Pandian A (2020) Utilization of PET bottles and plastic granules in geopolymer concrete. Mater Today Proc 42:444–449. https://doi.org/10.1016/j.matpr.2020.10.170
Mohana R, Bharathi SL (2022) Sustainable utilization of pre-treated and nano fly ash powder for the development of durable geopolymer mortars. Adv Powder Technol 33:103696
Rajendran M, Akasi M (2020) Performance of crumb rubber and nano fly ash based ferro-geopolymer panels under impact load. KSCE J Civ Eng 24:1810–1820. https://doi.org/10.1007/s12205-020-0854-z
Mohana R, Soundarapandian N (2015) Geopolymer ferrocement panels under flexural loading. Sci Eng Compos Mater 22:331–341. https://doi.org/10.1515/secm-2013-0012
Rao AK, Kumar DR (2020) Effect of various alkaline binder ratio on geopolymer concrete under ambient curing condition. Mater Today Proc. https://doi.org/10.1016/j.matpr.2020.03.682
Ghafoor MT, Khan QS, Qazi AU, Sheikh MN, Hadi MNS (2020) Influence of alkaline activators on the mechanical properties of fly ash based geopolymer concrete cured at ambient temperature. Constr Build Mater. https://doi.org/10.1016/j.conbuildmat.2020.121752
Mehta A, Siddique R (2018) Sustainable geopolymer concrete using ground granulated blast furnace slag and rice husk ash: strength and permeability properties. J Clean Prod 205:49–57. https://doi.org/10.1016/j.jclepro.2018.08.313
Saeed A, Najm HM, Hassan A, Sabri MMS, Qaidi S, Mashaan NS, Ansari K (2022) Properties and applications of geopolymer composites: a review study of mechanical and microstructural properties. Materials (Basel). https://doi.org/10.3390/ma15228250
Qaidi S, Najm HM, Abed SM, Ahmed HU, Al Dughaishi H, Al Lawati J, Sabri MM, Alkhatib F, Milad A (2022) Fly ash-based geopolymer composites: a review of the compressive strength and microstructure analysis. Materials (Basel). https://doi.org/10.3390/ma15207098
Ganesh AC, Muthukannan M, Aakassh S, Subramanaian B (2020) Energy efficient production of geopolymer bricks using industrial waste. IOP Conf Ser Mater Sci Eng. https://doi.org/10.1088/1757-899X/872/1/012154
Chithambar Ganesh A, Muthukannan M (2018) A review of recent developments in geopolymer concrete. Int J Eng Technol 7:696–699. https://doi.org/10.14419/ijet.v7i2.29.14000
Özkan I (2016) Production of sodium silicate cullets by using trona. Acta Phys Pol A 129:451–454. https://doi.org/10.12693/APhysPolA.129.451
Luukkonen T, Abdollahnejad Z, Yliniemi J, Kinnunen P, Illikainen M (2018) Comparison of alkali and silica sources in one-part alkali-activated blast furnace slag mortar. J Clean Prod 187:171–179. https://doi.org/10.1016/j.jclepro.2018.03.202
Moraes JCB, Font A, Soriano L, Akasaki JL, Tashima MM, Monzó J, Borrachero MV, Payá J (2018) New use of sugar cane straw ash in alkali-activated materials: a silica source for the preparation of the alkaline activator. Constr Build Mater 171:611–621. https://doi.org/10.1016/j.conbuildmat.2018.03.230
Villaquirán-Caicedo MA, de Gutiérrez RM, Sulekar S, Davis C, Nino JC (2015) Thermal properties of novel binary geopolymers based on metakaolin and alternative silica sources. Appl Clay Sci 118:276–282. https://doi.org/10.1016/j.clay.2015.10.005
Villaquirán-Caicedo MA, de Gutiérrez RM (2018) Synthesis of ceramic materials from ecofriendly geopolymer precursors. Mater Lett 230:300–304. https://doi.org/10.1016/j.matlet.2018.07.128
Tchakouté HK, Rüscher CH, Kong S, Kamseu E, Leonelli C (2016) Comparison of metakaolin-based geopolymer cements from commercial sodium waterglass and sodium waterglass from rice husk ash. J Sol-Gel Sci Technol 78:492–506. https://doi.org/10.1007/s10971-016-3983-6
Rajan HS, Kathirvel P (2021) Sustainable development of geopolymer binder using sodium silicate synthesized from agricultural waste. J Clean Prod 286:124959. https://doi.org/10.1016/j.jclepro.2020.124959
Padmalal D, Maya K, Sreebha S, Sreeja R (2008) Environmental effects of river sand mining: a case from the river catchments of Vembanad lake Southwest coast of India. Environ Geol. https://doi.org/10.1007/s00254-007-0870-z
Anthony EJ, Brunier G, Besset M, Goichot M, Dussouillez P, Nguyen VL (2015) Linking rapid erosion of the Mekong River delta to human activities. Sci Rep 5:1–12. https://doi.org/10.1038/srep14745
Kondolf GM (1997) Hungry water: effects of dams and gravel mining on river channels. Environ Manag 21:533–551. https://doi.org/10.1007/s002679900048
Tangaramvong S, Nuaklong P, Khine MT, Jongvivatsakul P (2021) The influences of granite industry waste on concrete properties with different strength grades. Case Stud Constr Mater 15:e00669. https://doi.org/10.1016/j.cscm.2021.e00669
Chouhan DS, Agrawal Y, Gupta T, Sharma RK (2017) Utilization of granite slurry waste in concrete: a review. Indian J Sci Technol 10:1–9. https://doi.org/10.17485/ijst/2017/v10i6/88279
Qaidi S, Najm HM, Abed SM, Özkılıç YO, Al Dughaishi H, Alosta M, Sabri MMS, Alkhatib F, Milad A (2022) Concrete containing waste glass as an environmentally friendly aggregate: a review on fresh and mechanical characteristics. Materials (Basel) 15:1–16. https://doi.org/10.3390/ma15186222
Singh S, Nagar R (2016) Feasibility as a potential substitute for natural sand : a comparative study between granite cutting waste and marble slurry. Procedia Environ Sci 35:571–582. https://doi.org/10.1016/j.proenv.2016.07.042
Mbengue MTM, Gana AL, Messan A, Pantet A (2022) Geotechnical and mechanical characterization of lateritic soil improved with crushed granite. Civ Eng J 8:843–862. https://doi.org/10.28991/CEJ-2022-08-05-01
Balakrishnan D, John T, Thomas J (2013) Properties of fly ash based geo-polymer concrete. Am J Eng Res 4:21–25
Mary ML, Peter C, Mohan K, Greens S, George S (2018) Energy efficient production of clay bricks using industrial waste. Heliyon 4:e00891. https://doi.org/10.1016/j.heliyon.2018.e00891
Chithambar Ganesh A, Muthukannan M, Dhivya M, Sangeetha CB, Daffodile SP (2020) Structural performance of hybrid fiber geopolymer concrete beams. IOP Conf Ser Mater Sci Eng. https://doi.org/10.1088/1757-899X/872/1/012155
Ganesh AC, Muthukannan M (2021) Development of high performance sustainable optimized fiber reinforced geopolymer concrete and prediction of compressive strength. J Clean Prod 282:124543. https://doi.org/10.1016/j.jclepro.2020.124543
Anuradha R, Sreevidyaa VV, Rangan BV (2011) Modified guidelines for geopolymer concrete mix design using Indian standard. Asian J Civ Eng Build. Housing 13:357–368
I.- 2009 (2009) Guidelines for concrete mix design proportioning. Bur Indian Stand. New Delhi, pp 1–14
IS:1199-1959 (2004) Methods of sampling and analysis of concrete. https://doi.org/10.2174/18722105130103.
Singh S, Nagar R, Agrawal V, Rana A, Tiwari A (2016) Sustainable utilization of granite cutting waste in high strength concrete. J Clean Prod 116:223–235. https://doi.org/10.1016/j.jclepro.2015.12.110
Gupta LK, Vyas AK (2018) Impact on mechanical properties of cement sand mortar containing waste granite powder. Constr Build Mater 191:155–164. https://doi.org/10.1016/j.conbuildmat.2018.09.203
I.S. 516-1959 (1959) Method of tests for strength of concrete. Bur Indian Stand, pp 1–30
Jain A, Gupta R, Chaudhary S (2019) Performance of self-compacting concrete comprising granite cutting waste as fine aggregate. Constr Build Mater 221:539–552. https://doi.org/10.1016/j.conbuildmat.2019.06.104
Savadkoohi MS, Reisi M (2020) Environmental protection based sustainable development by utilization of granite waste in reactive powder concrete. J Clean Prod 266:121973. https://doi.org/10.1016/j.jclepro.2020.121973
Medina G, Sáez del Bosque IF, Frías M, Sánchez de Rojas MI, Medina C (2017) Mineralogical study of granite waste in a pozzolan/Ca(OH)2 system: influence of the activation process. Appl Clay Sci 135:362–371. https://doi.org/10.1016/j.clay.2016.10.018
I.S. 5816-1999 (1999) Indian standard Splitting tensile strength of concrete- method of test. Bur Indian Stand., pp 1–14
Shilar FA, Ganachari SV, Patil VB, Nisar KS, Abdel-Aty AH, Yahia IS (2022) Evaluation of the effect of granite waste powder by varying the molarity of activator on the mechanical properties of ground granulated blast-furnace slag-based geopolymer concrete. Polymers (Basel). https://doi.org/10.3390/polym14020306
Ghannam S, Najm H, Vasconez R (2016) Experimental study of concrete made with granite and iron powders as partial replacement of sand. Sustain Mater Technol 9:1–9. https://doi.org/10.1016/j.susmat.2016.06.001
A.- C642-97 (2005) Standard test methods for density, absorption, and voids in hardened concrete. ASTM Int., pp 1–3
Zafar MS, Javed U, Khushnood RA, Nawaz A, Zafar T (2020) Sustainable incorporation of waste granite dust as partial replacement of sand in autoclave aerated concrete. Constr Build Mater 250:118878. https://doi.org/10.1016/j.conbuildmat.2020.118878
Mashaly AO, Shalaby BN, Rashwan MA (2018) Performance of mortar and concrete incorporating granite sludge as cement replacement. Constr Build Mater 169:800–818. https://doi.org/10.1016/j.conbuildmat.2018.03.046
A. C1202-12 (2012) Standard test method for electrical indication of concrete’s ability to resist chloride ion penetration. ASTM, pp 1–8. https://doi.org/10.1520/C1202-12.2
Jain KL, Sancheti G, Gupta LK (2020) Durability performance of waste granite and glass powder added concrete. Constr Build Mater 252:119075. https://doi.org/10.1016/j.conbuildmat.2020.119075
Vijayalakshmi M, Sekar ASS, Ganesh Prabhu G (2013) Strength and durability properties of concrete made with granite industry waste. Constr Build Mater 46:1–7. https://doi.org/10.1016/j.conbuildmat.2013.04.018
ASTM-C267-98 (1998) Standard test methods for chemical resistance of mortars, grouts and monolithic surfacings and polymer concretes. ASTM Int, vol 4, pp 1–6
Saxena R, Gupta T, Sharma RK, Panwar NL (2021) Influence of granite waste on mechanical and durability properties of fly ash-based geopolymer concrete. Environ Dev Sustain 23:17810–17834. https://doi.org/10.1007/s10668-021-01414-z
Benalia S, Zeghichi L, Benghazi Z (2022) A comparative study of metakaolin/slag-based geopolymer mortars incorporating natural and recycled sands. Civ Eng J 8:1622–1638. https://doi.org/10.28991/CEJ-2022-08-08-07
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Ganesh, A.C., Raju, H.P., Prasad, J.R. et al. Effect of granite waste in slag-based geopolymer activated by RHA derivative. Innov. Infrastruct. Solut. 8, 269 (2023). https://doi.org/10.1007/s41062-023-01241-3
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DOI: https://doi.org/10.1007/s41062-023-01241-3