Skip to main content

Advertisement

Log in

Effect of Alloying with Al, Nd and Ca and Heat Treatment on Microstructures and Mechanical Properties of Vacuum Die-Cast AM50 Alloy

  • Technical Paper
  • Published:
International Journal of Metalcasting Aims and scope Submit manuscript

Abstract

In this paper, Mg–Al–Mn (AM) series alloys were studied to develop high strength and toughness die-cast magnesium alloys by micro-multi-alloying method. AM50-X (Al, Nd, Ca) alloy samples were prepared by vacuum die casting using Al, Ca, Nd elements with obvious alloying effect. The microstructures and mechanical properties of AM50, AM70 and AM70–0.5Nd–0.5Ca alloys after die casting and heat treatment were investigated by means of microstructure observation and mechanical properties test. The results showed that the tensile strength of the die-cast AM70 alloy was higher than that of the die-cast AM50 alloy, but the elongation was lower. The AM70–0.5Nd–0.5Ca alloy showed a further increase in tensile strength and a slight decrease in plasticity. The addition of small amounts of Nd and Ca led to a refinement of the microstructure, and the elements Nd and Ca did not form new phases and dissolve mainly in the Mg17Al12 phase. T4 heat treatment slightly reduced alloy hardness, while T6 heat treatment could increase alloy hardness. AM70–0.5Nd–0.5Ca alloy had the optimal overall mechanical properties after T4 treatment. The ultimate tensile strength, yield strength, elongation and hardness of AM70–0.5Nd–0.5Ca alloy reached 243.6 MPa, 145.2 MPa, 6.7% and 60.9 HBS, espectively. The improvement in the mechanical properties of AM70–0.5Nd–0.5Ca–T4 alloy could be attributed to comprehensive effect of fine grain strengthening, solid solution strengthening and dispersion strengthening caused by the improvement of Mg17Al12 (Ca, Nd) phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
Figure 9
Figure 10

Similar content being viewed by others

References

  1. X.J. Wang, D.K. Xu, What is going on in magnesium alloys. J. Mater. Sci. Technol. 34, 245–247 (2018). https://doi.org/10.1016/j.jmst.2017.07.019

    Article  Google Scholar 

  2. Z. Tian, B. Song, Application and developing of AM magnesium alloy in automobile industry. Automob. Technol. Mater. 7, 21–23 (2004)

    Google Scholar 

  3. B. Richard, G. Wang, Magnesium applications in the automotive industry and the developing trends. Lightweight Technol. (2015). https://doi.org/10.26914/c.cnkihy.2015.002512

    Article  Google Scholar 

  4. G.F. Lv, F. Wang, X.D. Du, Microstructure, mechanical and wear properties of short carbon fiber-reinforced AM50 magnesium matrix composite. Int. Metalcast. (2023). https://doi.org/10.1007/s40962-023-01220-5

    Article  Google Scholar 

  5. P. Metalnikova, G. Ben-Hamu, The relation between Mn additions, microstructure and corrosion behavior of new wrought Mg–5Al alloys. Mater CharactCharact. 145, 101–115 (2018). https://doi.org/10.1016/j.matchar.2018.08.033

    Article  CAS  Google Scholar 

  6. J. Yang, J. Peng, E.A. Nyberg, Effect of Ca addition on the corrosion behavior of Mg–Al–Mn alloy. Appl. Surf. Sci. 369, 92–100 (2016). https://doi.org/10.1016/j.apsusc.2016.01.283

    Article  CAS  Google Scholar 

  7. C. Karabulut, G. Malko, Influence of different Fe Levels on mechanical properties of AlSi7Mg0.3 Aluminum casting alloys. Int. Metalcast. (2023). https://doi.org/10.1007/s40962-023-01227-y

    Article  Google Scholar 

  8. X. Li, B. Ma, Microstructure evolution and properties improvement of Fe-containing scrap brass alloy by Al microalloying and dispersion distribution regulation. Int. Metalcast. (2023). https://doi.org/10.1007/s40962-023-01213-4

    Article  Google Scholar 

  9. S.N. Lekakh, L. Bartlett, Improvement of high-temperature performance of high Si SGI by Al alloying and optimizing microstructural dispersity. Int. Metalcast. (2024). https://doi.org/10.1007/s40962-023-01228-x

    Article  Google Scholar 

  10. A.P. Agrawal, S.K. Srivastava, Investigating the effects of adding Si3N4 on microstructural and mechanical characteristics of AA7075-based TiB2-reinforced hybrid MMCs. Int. Metalcast. (2023). https://doi.org/10.1007/s40962-023-01193-5

    Article  Google Scholar 

  11. D. Itoh, Y. Terada, Effect of calcium additions on creep properties of a die-cast AM50 magnesium alloy. Mater. Trans. 49, 1957–1962 (2008). https://doi.org/10.2320/matertrans.MAW200830

    Article  CAS  Google Scholar 

  12. R. Arrabal, A. Pardo, Effect of Nd on the corrosion behaviour of AM50 and AZ91D magnesium alloys in 3.5wt.% NaCl solution. Corros. Sci.. Sci. 55, 301–312 (2012). https://doi.org/10.1016/j.corsci.2011.10.033

    Article  CAS  Google Scholar 

  13. F.S. Teimoory, M. Emamy, Effect of Pr on the grain refinement and mechanical properties of AM50 alloy in as-cast condition. AIP Conf. Proc. 1, 1920 (2018). https://doi.org/10.1063/1.5018948

    Article  CAS  Google Scholar 

  14. R. Arrabal, E. Matykina, A. Pardo, Corrosion behaviour of AZ91D and AM50 magnesium alloys with Nd and Gd additions in humid environments. Corros. Sci.. Sci. 55, 351–362 (2012). https://doi.org/10.1016/j.corsci.2011.10.038

    Article  CAS  Google Scholar 

  15. S. Jayalakshmi, S. Sankaranarayanan, S.P.X. Koh, Effect of Ag and Cu trace additions on the microstructural evolution and mechanical properties of Mg–5Sn alloy. J. Alloy. Compd. 565, 56–65 (2013). https://doi.org/10.1016/j.jallcom.2013.02.186

    Article  CAS  Google Scholar 

  16. S. Zhu, T. Luo, T. Zhang, Effects of Cu addition on the microstructure and mechanical properties of as-cast and heat treated Mg–6Zn–4Al magnesium alloy. Mater. Sci. Eng. A 689, 203–211 (2017). https://doi.org/10.1016/j.msea.2017.02.061

    Article  CAS  Google Scholar 

  17. L. Zhong, J. Peng, M. Li, Y. Wang, Y. Lu, F. Pan, Effect of Ce addition on the microstructure, thermal conductivity and mechanical properties of Mg–0.5Mn alloys. J. Alloys Compd. 661, 402–410 (2015)

    Article  Google Scholar 

  18. X. Liu, The effect of Nd contents on the micro structure and mechanical properties of AM60 Mg alloy. Light Alloy Fabr. Technol. 43, 62–64 (2015)

    Google Scholar 

  19. B. Kondori, R. Mahmudi, Effect of Ca additions on the microstructure, thermal stability and mechanical properties of a cast AM60 magnesium alloy. Mater. Sci. Eng. A 527, 2014–2021 (2010). https://doi.org/10.1016/j.msea.2009.11.043

    Article  CAS  Google Scholar 

  20. H. Li, H. Wang, Effect of Ca and Sr on microstructures and mechanical properties of AM50 magnesium alloy. Foundry Technol. 39, 1211–1214 (2018)

    CAS  Google Scholar 

  21. P. Cui, M. Hu, Effect of La/Nd ratio on microstructure and mechanical properties of as-cast AZ91-xLa/Nd alloy. Mater. Res. Express 7, 26531–26536 (2020)

    Article  CAS  Google Scholar 

  22. F. Wang, S. Sun, Effects of heat treatment on microstructure and mechanical properties of Mg–7Al–2Sn alloy prepared by vacuum die-casting. Trans. Mater. Heat Treat. 36, 72–77 (2015)

    Google Scholar 

  23. N. Jiang, L. Chen, Effect of neodymium, gadolinium addition on microstructure and mechanical properties of AZ80 magnesium alloy. J. Rare Earths 34, 632–637 (2016). https://doi.org/10.1016/S1002-0721(16)60072-8

    Article  CAS  Google Scholar 

  24. X. Huang, P. Fu, C. Lu, Influence of Nd on the mechanical properties and high temperature creep properties of AM50 magnesium alloy. J. Mater. Res. 6, 593–596 (2004)

    Google Scholar 

  25. X. Huang, X. Wang, Influence of Si on the mechanical properties and high temperature creep properties of AM50 magnesium alloy. J. Mater. Res. 18, 630–634 (2004)

    CAS  Google Scholar 

  26. H. Cui, T. Li, Effects of alloying element Sb on microstructure and mechanical properties of AM50 magnesium alloys. Foundry Technol. 6, 791–795 (2009)

    Google Scholar 

  27. M. Wang, H. Zhou, Effect of Yttrium and Cerium addition on microstructure and mechanical properties of AM50 magnesium alloy. J. Chin. Rare Earth Soc. 1, 69–73 (2007). https://doi.org/10.3321/j.issn:1000-4343.2007.01.012

    Article  Google Scholar 

  28. S. Shen, M. Yang, L. Zhang, Effects of Gd alloying on microstructure and corrosion resistance of AM50 alloy for automotive engine. Spec. Cast. Nonferr. Alloys 36, 313–315 (2016)

    Google Scholar 

  29. G. Mao, Y. Sun, Effects of Sr addition and solid-solution treatment on microstructure and elevated temperature mechanical properties of AM50 magnesium alloy. Trans. Mater. Heat Treat. 31, 105–109 (2010)

    CAS  Google Scholar 

  30. J. Jiang, X. Nie, Y. Wang et al., Microstructure and mechanical properties of AM50A magnesium alloy components prepared by die casting and double control forming. Adv. Mech. Eng. 6, 450826 (2014). https://doi.org/10.1155/2014/450826

    Article  CAS  Google Scholar 

  31. S. Dang, M. Zhao, Effect of Ca on microstructures and mechanical properties of Mg–5Al–1Bi alloys. Spec. Cast. Nonferr. Alloys 32, 593–597 (2012)

    CAS  Google Scholar 

  32. P. Li, E.G. Kandalova, Microstructure and properties of AZ91D alloy with Ca additions. Mater. Lett. 59, 671–675 (2005). https://doi.org/10.1016/j.matlet.2004.11.006

    Article  CAS  Google Scholar 

  33. Y. Bourezg, H. Azzeddine, The sequence and kinetics of pre-precipitation in Mg–Nd alloys after HPT processing: a synchrotron and DSC study. J. Alloy. Compd. 719, 236–241 (2017). https://doi.org/10.1016/j.jallcom.2017.05.166

    Article  CAS  Google Scholar 

  34. W. Ding, Magnesium alloy science and technology (Science Press, Beijing, 2007)

    Google Scholar 

Download references

Acknowledgements

The authors would like to acknowledge the financial support from Basic scientific research project of Liaoning Provincial Department of Education (key research project) (No: JYTZD2023108); High level innovation team of Liaoning Province (No: XLYC1908006); General Project of Liaoning Provincial Department of Education (No: JYTMS20231201); Liaoning Nature Fund Guidance Plan (No. 2022-BS-179) and General Project of Liaoning Provincial Department of Education (No. LJKMZ20220462).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Feng Wang.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yang, Y., Wang, F., An, S. et al. Effect of Alloying with Al, Nd and Ca and Heat Treatment on Microstructures and Mechanical Properties of Vacuum Die-Cast AM50 Alloy. Inter Metalcast (2024). https://doi.org/10.1007/s40962-024-01308-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s40962-024-01308-6

Keywords

Navigation