Skip to main content
Log in

The Effects of Holding Time in the Heating/Pouring Unit on the Metallurgical Quality of Spheroidal Graphite Iron

  • Technical Paper
  • Published:
International Journal of Metalcasting Aims and scope Submit manuscript

A Correction to this article was published on 02 October 2022

This article has been updated

Abstract

The metallurgical quality of a ductile iron is determined by the components of the metallic charge, as well as by the liquid treatment (spheroidization, inoculation) and the holding temperature and time. All these factors directly affect the nucleation potential of the melt, and consequently the formation of undesired carbides and microshrinkage. The goal of this industrial research was to investigate the effect of holding times in the heating/pouring unit on the microstructure and nucleation propensity of a 3.73% C, 2.53% Si spheroidal graphite iron. Thermal analysis was conducted at different processing times, and metallographic analysis was performed on the thermal analysis cups to evaluate the graphite particle count, the graphite shape parameters, and their size distribution. As expected, longer holding times produced higher amounts of carbides. SEM examination revealed that sulfides and Mg–Si–Al nitrides were the main nuclei. Their evolution in time was evaluated. The improvement of the metallurgical quality by inoculation even after prolonged holding times was demonstrated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
Figure 9
Figure 10
Figure 11
Figure 12
Figure 13
Figure 14
Figure 15

Similar content being viewed by others

Change history

References

  1. Z. Glavas, The influence of metallic charge on metallurgical quality and properties of ductile iron. Kovove Mater. 50, 75–82 (2012)

    Article  CAS  Google Scholar 

  2. S. Bockus, A. Dobrovolskis, Effect of melting techniques on ductile iron castings properties. Metalurgija 45(1), 13–16 (2006)

    CAS  Google Scholar 

  3. C.F. Yeung, H. Zhao, W.B. Lee, The morphology of solidification of thin-section ductile iron castings. Mater. Charact. 40(4–5), 201–208 (1998)

    Article  CAS  Google Scholar 

  4. K. Janerka, D. Bartocha, J. Szajnar, J. Jezierski, The carburizer influence on the crystallization process and the microstructure of synthetic cast iron. Arch. Metall. 55, 851–859 (2010)

    CAS  Google Scholar 

  5. K. Janerka, J. Jezierski, J. Szajnar, D. Bartocha, Cast iron: produced from steel scrap, in Encyclopedia of Iron, Steel and their Alloys. ed. by R. Colás, G.E. Totten (Taylor & Francis, New York, NY, USA, 2015), pp.735–749

    Google Scholar 

  6. M. Gagné, The Sorelmetal Book of Ductile Iron (Rio Tinto Iron & Titanium Inc, Montreal, 2004)

    Google Scholar 

  7. G.M. Goodrich, Cast iron microstructure anomalies and their causes. AFS Trans. 105, 669–683 (1997)

    CAS  Google Scholar 

  8. L.E. Umoru, J.A. Ali, A.A. Afonja, Evaluation of the Influence of bainitic transformation on some mechanical properties of calcium treated irons. J. Mineral Mater. Charact. Eng. 6(2), 109–120 (2007)

    Google Scholar 

  9. Y.S. Lerner, G.V. Panteleev, Magnesium treatments in ductile iron production – part 2. Foundry Manag. Technol. 131(2), 24–29 (2003)

    Google Scholar 

  10. V.I. Litovka, A.A. Sheyko, B.G. Zeliony, Technology for ductile iron production. Liteynoje Proizvodstvo. 4, 13–14 (1983)

    Google Scholar 

  11. C. Labrecque, M. Gagné, E. Planque, Effect of charge materials on slag formation in ductile iron melts. Keith Millis Symposium on Ductile Cast Iron (2003)

  12. M. Riebisch, H.G. Sönke, B. Pustal et al., Influence of carbide-promoting elements on the pearlite content and the tensile properties of high silicon SSDI ductile iron. Int. J. Metalcast. 12, 106–112 (2018). https://doi.org/10.1007/s40962-017-0146-7

    Article  Google Scholar 

  13. J.V. Dawson, The stimulating effect of strontium on ferrosilicon and other silicon containing inoculants. Mod. Cast. 49, 171–177 (1966)

    CAS  Google Scholar 

  14. N.C. McClure, A.V. Khan, D. McCrady, H.L. Womochel, Inoculation of gray cast iron relative effectiveness of some silicon alloys and active metals as ladle additions. AFS Trans. 65, 340–349 (1957)

    Google Scholar 

  15. M. Popescu, R. Zavadil, M. Sahoo, SiC-the most efficient addition to increase the nodule count in ductile iron. Int. J. Metalcast. 3, 53–63 (2009). https://doi.org/10.1007/BF03355441

    Article  CAS  Google Scholar 

  16. W. Maschke, M. Jonuleit, Inoculation of Cast Iron. ASK Chemiclas L.P., Dublin, Ohio, USA

  17. D.M. Stefanescu, Analysis of the rationale and accuracy of the use of carbon equivalent and thermal analysis in the quality control of cast iron. Int. J. Metalcast. 16, 1057–1078 (2022). https://doi.org/10.1007/s40962-021-00685-6

    Article  Google Scholar 

  18. G. Alonso, D.M. Stefanescu, P. Larrañaga, J. Sertucha, R. Suárez, Grey cast iron with high austenitic-to-eutectic-ratio part I - calculation and experimental evaluation of the fraction of primary austenite in cast iron. AFS Trans. 120, 329–335 (2012)

    CAS  Google Scholar 

  19. Y. Yan, L. Chang, X. Chen, Q. Hua, Q. Zhai, Effect of niobium on the morphology of nodular graphite in ductile iron. Adv. Mater. Res. 852, 163–167 (2014)

    Article  Google Scholar 

  20. M. Rezvani, R.A. Harding, J. Campbell, The effect of vanadium in as-cast ductile iron. Int. J. Cast Met. Res. 10, 1–15 (1997)

    Article  CAS  Google Scholar 

  21. S.N. Lekakh, B. Hrebec, Solidification kinetics of graphite nodules in cast iron and shrinkage porosity. Int. J. Metalcast 10, 389–400 (2016). https://doi.org/10.1007/s40962-016-0053-3

    Article  Google Scholar 

  22. G. Alonso, D.M. Stefanescu, J. Sanchez, G. Zarrabeitia, R. Suarez, Effect of the type of inoculant on the shrink-age porosity of high silicon SG iron. Int. J. Metalcast. 16, 106–118 (2022). https://doi.org/10.1007/s40962-021-00605-8

    Article  CAS  Google Scholar 

  23. G. Alonso, D.M. Stefanescu, B. Bravo, G. Zarrabeitia, R. Suarez, Nodule count, end of solidification cooling rate, and shrinkage porosity correlations in high silicon spheroidal graphite irons. Minerals 11, 155 (2021). https://doi.org/10.3390/min11020155

    Article  CAS  Google Scholar 

  24. Z. Glavas, D. Lisjak, F. Unkic, The application of artificial neural network in the prediction of the as-cast impact toughness of spheroidal graphite cast iron. Kovove Mater. 45, 41–49 (2007)

    CAS  Google Scholar 

  25. M. Chisamera, I. Riposan, S. Stan, P. Toboc, T. Skaland, D. White, Shrinkage evaluation in ductile iron as influenced by mould media and inoculant type. Int. J. Cast Metals Res. 24, 28 (2011)

    Article  CAS  Google Scholar 

  26. J. Tartera, Cast iron inoculation mechanisms. AFS Int. Cast Metals J. 5(4), 7–14 (1980)

    Google Scholar 

  27. T. Skaland, Ductile iron shrinkage control through graphite nucleation and growth. Int. J. Cast Metals Res. 16(1–3), 11–16 (2003)

    Article  CAS  Google Scholar 

  28. G. Alonso, D.M. Stefanescu, P. Larrañaga, E. De la Fuente, R. Suarez, The role of titanium and nitrogen in graphite nucleation of ductile iron. 5th Decennial International Conference on Solidification Processing, SP17, Old Windsor, UK (2017)

  29. G. Alonso, A. Crişan, D.M. Stefanescu, R. Suarez, Effect of titanium in the nucleation process of spheroidal and compacted graphite cast iron. 11th Int. Conf. on Mater. Sci. & Eng., BRAMAT, Poiana Brasov, Romania, 13-16 March (2019)

  30. I. Rivera, A. Roca, F. Patino, M. Cruells, Microalloyed niobium influence on ductile ferrite cast iron. Int. J. Cast Met. Res. 16, 65–70 (2003)

    Article  Google Scholar 

  31. G.S. Cho, K.H. Choe, K.W. Lee, A. Ikenaga, Effects of alloying elements on the microstructures and mechanical properties of heavy section ductile cast iron. J. Mater. Sci. Technol. 23, 97–101 (2007)

    CAS  Google Scholar 

  32. S. Hasse, Niedriglegiertes Gusseisen mit Kugel-graphit. Giesserei-Praxis 8, 293–301 (2005)

    Google Scholar 

  33. S.N. Lekakh, Searching for graphite nodule nuclei using automated SEM/EDX analysis. Int. J. Metalcast. 14, 1078–1089 (2020). https://doi.org/10.1007/s40962-020-00418-1

    Article  CAS  Google Scholar 

  34. N.G. Kok Long, H. Sasaki, H. Kimura, T. Yoshikawa, M. Maeda, Heterogeneous nucleation of graphite on rare Earth compounds during solidification of cast iron. ISIJ Int. 58(1), 123–131 (2018)

    Article  Google Scholar 

  35. G. Alonso, D.M. Stefanescu, P. Larrañaga, E. De la Fuente, R. Suarez, Reassessment of nucleation models for spheroidal graphite through advanced SEM analysis. AFS Trans. 125, 131–146 (2017)

    CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by Diputación Foral de Bizkaia, Spain.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to D. M. Stefanescu.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

The original online version of this article was revised: An Authors’ Note was added to the end of the article and Table 1 and Fig. 2b were corrected.

Rights and permissions

Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Alonso, G., Stefanescu, D.M., Olaizola, J.R. et al. The Effects of Holding Time in the Heating/Pouring Unit on the Metallurgical Quality of Spheroidal Graphite Iron. Inter Metalcast 17, 1361–1372 (2023). https://doi.org/10.1007/s40962-022-00866-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40962-022-00866-x

Keywords

Navigation