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A novel continuous electroflotation cell design for industrial effluent treatment

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Abstract

The performance of a continuous flow electroflotation (EF) unit designed for industrial effluents treatment was investigated. The employment of synthetic wastewater composed of some heavy metal ions (Cr3+, Cu2+ and Pb2+), soluble dyes (Acid Red 1 and Basic Violet 3), and ultrafine particles (copper metal and copper oxide) was set for studying the cell parameters. The affecting parameters of the EF unit which are current density and type and ionic strength (conductivity) and feed flow rate were studied. The continuous flow EF unit was employed for the treatment of different industrial effluents which was supplied by Textile, Tannery and Wood factories. For synthetic wastewater, the removal efficiency of industrial effluents increased with increasing current density and ionic strength. DC current causes passivation of the anode, thus AC current was preferred. The lower feed flow rate increased the removal efficiency but consumed more power. The removal efficiency was achieved up to 95% at 25 °C, 5 V and an AC current intensity of 1 A with a feed flow rate of 50 ml/min (3 l/h). The energy consumption was 1.67 kWh/m3. For different industrial effluents, the removal efficiency approached up to 90%, at 25 °C, 5 V and an AC current intensity of about 1 A and a 30 ml/min feed flow rate. The energy consumption was about 3 kWh/m3. The removal efficiency could be increased up to about 99% by a further cleaning step with total energy consumption of about 6 kWh/m3.

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References

  • Abdel Khalek MA (2011) Studies on industrial wastewater treatment by electrochemical coagulation. J Ore Dress Turkey 13(26):15–20 (ISSN 1302-6798)

    Google Scholar 

  • Abdel Khalek MA, Mahmoud GA (2012) Swelling behavior of cross-linked Poly (vinyl alcohol)/acrylic acid copolymer for removal of heavy metal ions from aqueous solutions. In: 12th International Eurasia conference on chemical science, Corfu, Greece, April 16–21

  • Abdel Khalek MA, Parekh BK (2003) Separation of ultra-fine wood particles from waste water to prevent water pollution. AFINIDAD VII(503):71–75

    Google Scholar 

  • Abdel Khalek MA, Mahmoud GA, El-Kelesh NA (2012) Synthesis and characterization of poly-methacrylic acid grafted chitosan- bentonite composite and its application for heavy metals recovery. Chem Mater Res 2(7):1–13

    Google Scholar 

  • Abdel Khalek MA, Abdel Rahman MK, Francis AA (2017) Exploring the adsorption behavior of cationic and anionic dyes on industrial waste shells of egg. J Environ Chem Eng 5:319–327

    Article  Google Scholar 

  • Adamoviuc Savka, Prica Miljana, Dalmacija Bozo (2015) Feasibility of electro-coagulation/flotation of waste offset printing developer based on the response surface analysis. Arabian J Chem. doi:10.1016/j.arabjc.2015.03.018

    Google Scholar 

  • Al-Abdealaali AA (2011) Removal of boron from simulated Iraqi surface water by electrocoagulation method, M.Sc. Thesis, college of engineering, Baghdad University

  • Alebrahim MF, Khattab IA, Sharif Adel O (2015) Electro-deposition of copper from a copper sulfate solution using a packed-bed continuous-recirculation flow reactor at high applied electric current. Egypt J Pet 24:325–331

    Article  Google Scholar 

  • Al-qudah YH, Mahmoud GA, Abdel Khalek MA (2014) Radiation crosslinked poly (vinyl alcohol)/acrylic acid copolymer for removal of heavy metal ions from aqueous solutions. J Radiat Res Appl Sci 7:135–145

    Article  Google Scholar 

  • APHA (1992) Standard methods for examination of water and wastewater, 17th Ed. American Public Health Association, New York

  • Aoudj S, Khelifa A, Drouiche N, Djamel M (2015) Simultaneous removal of chromium (VI) and fluoride by electrocoagulation electroflotation: application of a hybrid Fe-Al anode. Chem Eng J 267:153–162

    Article  Google Scholar 

  • Chaturvedi SI (2013) Electrocoagulation: a novel waste water treatment method. Int J Modern Eng Res 3(1):93–100

    Google Scholar 

  • Chen X, Chen G (2010) EF. In: Comninellis C, Chen G (eds.) Electrochemistry for the environment. Springer Science & Business Media LLC, pp 263–277. ISBN-10: 0387369228, ISBN-13: 978-0387369228.

  • Cleceri LS, Greenberg AE, Eaton AD (1998) Standard Methods for the Examination of Water and Wastewater, 20th edn. American Public Health Association, Washington DC

    Google Scholar 

  • Dermentzis K (2010) Removal of nickel from electroplating rinse waters using electrostatic shielding electrodialysis/electrodeionization. J Hazard Mater 173:647–652

    Article  Google Scholar 

  • Emam AA, Ismail LFM, AbdelKhalek MA, Azza Rehan (2016) Adsorption study of some heavy metal ions on modified kaolinite clay. Int J Adv Eng Technol Manag Appl Sci 3(7):152–163

    Google Scholar 

  • Emamjomeh MM, Sivakumar M (2009) Review of pollutants removed by electrocoagulation and electrocoagulation/flotation processes. J Environ Manage 90(5):1663–1679. doi:10.1016/j.jenvman.2008.12.011

    Article  Google Scholar 

  • Farghaly FE, Ahmed MM, Abdel-Khalek MA (2015) Industrial wastewater treatment using squid bones as a carbonate mineral. Aust J Basic Appl Sci 9(27):525–534

    Google Scholar 

  • Guidelines for the safe use of wastewater (2006) Excreta and grey water. World Health Organization, Geneva

    Google Scholar 

  • Guidelines for Water Reuse (2012) Environmental Protection Agency: Washington, DC, USA, EPA/600/R-12/618, September 2012

  • Gunatilake SK (2015) Methods of removing heavy metals from industrial wastewater. J Multi Discip Eng Sci Stud 1(1):234–241

    Google Scholar 

  • Hanisch B (1959) The scientific application of flotation with very small air bubbles for purification of sewage water. Stuttgart University of Technology, Humana Press, Springer, Library of Congress

  • Holt PK, Barton GW, Wark M, Mitchell CA (2002) Quantitative comparison between chemical dosing and electrocoagulation. Coll Surf Physicochem Eng Asp 211:233–248

    Article  Google Scholar 

  • Housecroft CJ, Sharpe AG (2008) Inorganic chemistry, 3rd edn. Pearson Education Limited, England

    Google Scholar 

  • Industrial Emission Directive - European Commission (2017) http://eippcb.jrc.ec.europa.eu/reference/BREF/FDM/FDM_31-01-2017-D1_b_w.pdf. Accessed 15 May 2017

  • Jedele K (1984) Use of the relaxation flotation to separate the animated sludge from the water. In: Application of DAF for separation of biological sludge and water. Commissioner R. Oldenbourg, Munich, 3, 35–52

  • Jeong H, Kim H, Jang T (2016) Irrigation water quality standards for indirect wastewater reuse in agriculture: a contribution toward sustainable wastewater reuse in South Korea. Water 8(169):1–18

    Google Scholar 

  • Karishma C, Vyas M, Mehta M (2014) Feasibility study of electro-coagulation as a treatment method for textile industry wastewater. Int J Eng Sci Res Technol 3(2):847–852

    Google Scholar 

  • Ketkar DR, Mallikarjunan R, Venkatachalam S (1988) Size determination of electro-generated gas bubbles. J Electrochem Soc India 37(4):313–318

    Google Scholar 

  • Khosla NK, Venkatachalam S, Somasundaran P (1991) Pulsed electrogeneration of bubbles for electro-flotation. J Appl Electrochem 21:986–990

    Article  Google Scholar 

  • Lin SH, Peng CF (1994) Treatment of textile wastewater by electrochemical method. Water Res 28:277–282

    Article  Google Scholar 

  • Mohora E, Roncević S, Dalmacija B, Agbaba J, Watson M, Karlović E, Dalmacija M (2012) Removal of natural organic matter and arsenic from water by electrocoagulation/flotation continuous flow reactor. J Hazard Mater 235–236:257–264

    Article  Google Scholar 

  • Mouedhen G, Feki M, Wery MDP, Ayedi HF (2008) Behavior of aluminum electrodes in electrocoagulation process. J Hazard Mater 150:124–135

    Article  Google Scholar 

  • Nouri J, Mahvi AH, Bazrafshan E (2010) Application of electrocoagulation process in removal of zinc and copper from aqueous solutions by aluminum electrodes. Int J Environ Res 4:201–208

    Google Scholar 

  • Paranychianakis NV, Salgot M, Snyder SA, Angelakis AN (2015) Water reuse in EU states: necessity for uniform criteria to mitigate human and environmental risks. Crit Rev Environ Sci Technol 45:1409–1468

    Article  Google Scholar 

  • Patil BN, Naik DB, Shrivastava VS (2011) Photocatalytic degradation of hazardous Ponceau-S dye from industrial wastewater. Desalination 269(1–3):276–283

    Article  Google Scholar 

  • Rhee HP, Yoon CG, Jung KW, Son JW (2009) Microbial risk assessment using E. coli in UV disinfected wastewater irrigation on paddy. Environ Eng Res 14:120–125

    Article  Google Scholar 

  • Sahu O, Mazumdar B, Chaudhari PK (2014) Treatment of wastewater by electrocoagulation: a review. Environ Sci Pollut Res 21:2397–2413

    Article  Google Scholar 

  • Selim KA, El Hosiny FI, Abdel Khalek MA, Osama Inge (2017) Kinetics and thermodynamics of some heavy metals removal from industrial effluents through electro -flotation process. Coll Surf Sci 2(2):47–53

    Google Scholar 

  • Senthikumar R, Vijaraghavan K, Jegan J, Velan M (2010) Batch and column removal of total chromium from aqueous solution using Sargassumpolycystum. Environ Progress Sustain Energy. doi:10.1002/ep.10416

    Google Scholar 

  • Tchamango S, NanseuNjiki CP, Ngameni E, Hadjiev D, Darchen A (2010) Treatment of dairy effluents by electrocoagulation using aluminum electrodes. Sci Total Environ 408:947–952

    Article  Google Scholar 

  • UNICEF (2017) Thematic Report on drinking water, World Health Organization, Avenue Appia 20 1211 Geneva 27, Switzerland

  • Xu J, Wu L, Chang AC, Zhang Y (2010) Impact of long term reclaimed wastewater irrigation on agricultural soils: a preliminary assessment. J Hazard Mater 183:780–786

    Article  Google Scholar 

Download references

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Abdel Khalek, M.A., El Hosiny, F.I., Selim, K.A. et al. A novel continuous electroflotation cell design for industrial effluent treatment. Sustain. Water Resour. Manag. 5, 457–466 (2019). https://doi.org/10.1007/s40899-017-0199-z

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  • DOI: https://doi.org/10.1007/s40899-017-0199-z

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