Abstract
This study establishes the Orientation Relationship (OR) between the austenitic and martensitic phases of the new Shape Memory Alloy (SMA) FeMnNiAl from both experiments and analytical modeling. Through Transmission Electron Microscopy (TEM) and Electron Back-Scatter Diffraction, three distinct ORs, namely the Nishiyama-Wassermann (N-W), Pitsch, and Kurdjumov–Sachs (K-S) ORs are established. The observations of non-unique ORs are explained using the energy-minimization theory of martensite revealing dependence of OR on the internal morphology of the martensitic phase, whether twinned or stacking-faulted. It is shown that the twin-variants of an internally twinned martensitic structure individually explain the Pitsch and K-S ORs. The N-W OR was observed in a stacking-faulted substructure of martensite. Through a novel extension to the energy-minimization theory for stacking-faulted substructures, the N-W OR is explained. Thus, the current study challenges the notion of OR as a material-characteristic and reveals a dependence of the OR on the internal substructure of the martensitic phase in SMAs, further establishing the OR for the new SMA FeMnNiAl.
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Introduction
Materials of today exhibit microstructures that most often feature multiple phases, with these phases exercising strong influence on the materials’ properties. For instance, precipitate-phases in structural alloys elevate the mechanical strength [1,2,3,4], second-phase fiber/particle-reinforcements within a binding matrix-phase dictate the stiffness of composite materials [5,6,7], and stimuli-induced nucleation of a product-phase within a primary parent-phase can attribute high-deformability in several functional materials [8,9,10,11]. This study focuses on a class of functional materials known as Shape Memory Alloys (SMA) where a mechanically induced phase-transformation from a parent Austenitic (A) phase to a product Martensitic (M) phase attributes functional characteristics relevant in several applications spanning biomedical, automotive, and aerospace domains [12,13,14]. Specifically, this study uses experiments and theory to expound the relative Orientation Relationship (OR) between the lattices of the A and M phases in SMAs.
This Orientation Relationship (OR) between the A and M phases are generally described by two parallelism conditions: (i) the first parallelism is between two crystallographic planes, one in the A-lattice \({\left(hkl\right)}_{A}\) and another in the M-lattice \({\left({h}^{\prime}{k}^{\prime}{l}^{\prime}\right)}_{M}\), (ii) the second parallelism is between two crystallographic directions, one in the A-lattice \({\left[uvw\right]}_{A}\) and another in the M-lattice \({\left[{u}^{\prime}{v}^{\prime}{w}^{\prime}\right]}_{M}\) (refer Fig. 1). Such ORs have long been established experimentally for several SMAs [15,16,17,18,19,20,21,22] and are often tacitly attributed to be a property of the material. The OR can equivalently be stated as an invariancy of the two elements in the parent phase involved in the parallelism condition—a crystallographic plane \({\left(hkl\right)}_{\mathrm{A}}\) and a crystallographic direction \({\left[uvw\right]}_{A}\)—during the transformation. Therefore, the OR can be specified by the invariant plane \({\left(hkl\right)}_{\mathrm{A}}\) and direction \({\left[uvw\right]}_{A}\) in the parent phase, or more generally by the families \({\left\{hkl\right\}}_{A}\) and \({\langle uvw\rangle }_{A}\).
Understanding the OR in SMAs is particularly critical to address the challenge of fatigue in this material class. Fatigue in SMAs occurs by a mechanism of transformation-induced slip where slip-dislocations are emitted in the A phase from the A-M transformation front. And it is well-established that the activated slip-system in the A phase exhibits a close agreement with internal interfaces within the M phase [23,24,25,26,27,28]. Thus, to predict the propensity for slip-emission and consequently of fatigue, it is necessary to address the relative orientation of the slip-planes in the A-phase in relation to the internal interfaces of the M-phase. Although ORs for multiple SMAs have been proposed and well-characterized experimentally, there are few knowledge-gaps that remain in these relationships, listed as follows:
-
a.
Relation of OR to internal morphology of the M-phase: The ORs are generally specified for the SMA system in a manner that is independent from the internal structure of the martensite, whether twinned or stacking faulted. Particularly if the M-phase is internally twinned, it is important to know how the OR connects with the orientation of each of the twin variants.
-
b.
Lattice-correspondence and OR: In converting the A-crystal structure to the M-crystal structure, there are known lattice-correspondences that are proposed. These correspondences describe which crystallographic vector-basis of the parent transforms into the unit cell crystallographic basis of the martensite. It is unclear how the lattice-correspondences are linked to the OR. If the lattice-correspondence describes a relationship between crystallographic directions in the A-phase and M-phase (as described previously), it is necessary to understand how it differs from the observed OR.
-
c.
Exactness of the OR: It is important to know if the parallelism conditions used to define the OR are exact in nature or if there is a tolerance of a few degrees in them. The existence of such tolerance and their magnitude is essential to understand the gradient of crystal structures at the transformation front.
This study focuses on addressing all aforementioned issues. The framework is developed from the energy-minimization theory of martensite, typically used to predict the crystallography of habit planes. The study target is chosen from the new FeMnNiAl SMA system, specifically the alloy with composition \({\mathrm{Fe}}_{43.5}{\mathrm{Mn}}_{34}{\mathrm{Al}}_{15}{\mathrm{Ni}}_{7.5}\). This SMA alloy has been of recent interest in the field as a promising inexpensive alternative to NiTi, offering a temperature-invariant transformation stress and large transformation strains exceeding 10% [29,30,31,32]. This system has thus far been reported to exhibit the Pitsch OR [33,34,35] and this study investigates the OR further. Furthermore, there is the added advantage of working with cubic crystal structures in the A and M phases. With a cubic structure, the reciprocal space lattice is in perfect alignment with the real-space lattice. This affords the convenience of discussing alignment of crystallographic planes and directions in an interchangeable manner. In other words, the parallelism of two crystallographic planes \({\left(hkl\right)}_{A}\) and \({\left(mnp\right)}_{M}\) is exactly equivalent to stating parallelism of the normal crystallographic directions \({\left[hkl\right]}_{A}\) and \({\left[mnp\right]}_{M}\). In FeMnNiAl, the austenitic phase is Body-Centered-Cubic and the martensitic phase is Face-Centered-Cubic. These structures provide an ideal starting case to examine the OR between the A and M phases. The layout of the paper is as follows. Sect. “Methodology and Results” develops the methodology and presents the experimental/model results, Sect. “Discussion” discusses the implications and Sect. “Conclusions” presents the conclusions.
Methodology and Results
This section begins with the experimental observations of ORs between the BCC (\(\alpha\)) austenite (lattice constant \({a}_{A}=2.903\) Å) and FCC (\(\gamma^ {\prime}\)) martensite (lattice constant \({a}_{M}=3.672\) Å) in \({\mathrm{Fe}}_{43.5}{\mathrm{Mn}}_{34}{\mathrm{Al}}_{15}{\mathrm{Ni}}_{7.5}\) (the experimentally measured lattice constants are reported in ref [30]). Results from Selected Area Electron Diffraction (SAED) obtained from Transmission Electron Microscopy (TEM) and from Electron Backscatter Diffraction (EBSD) are presented. Then the predictive framework for the OR is elaborated starting from the lattice correspondence between the phases. The energy minimization theory of martensite is outlined and applied to the problem. The resulting ORs from the theory are compared with the experimentally observed ORs.
Experimental Observations
Compression-tested samples of FeMnNiAl were used to characterize the OR. These samples exhibited stress-induced transformation at room-temperature. TEM samples were milled out of transformed region using Focused Ion Beam (FIB) milling and thinned to electron-transparency. The results of the TEM imaging and SAED are presented in Fig. 2. The martensite is observed to form in a diamond-shaped self-accommodation morphology as shown in Fig. 2a consistent with prior reports in this system [35]. The diamond-morphology consists of 4 distinct Habit-Plane Variants (HPVs) with four planar transformation fronts. These variants form together and alongside to comprise the diamond-shape. Other independent HPVs forming parallel to the sides of the diamond-martensite are also observed. SAED patterns are collected from multiple regions as indicated in figures (b-e). When the austenite crystal structure is aligned to the \({\left[110\right]}_{\alpha }\) zone axis (Fig. 2b), the martensite crystal structure is also on an aligned zone-axis of \({\left[211\right]}_{\gamma^ {\prime}}\). This yields the SAED pattern shown in Fig. 2d. There is also the diffraction signature from fine B2 precipitates in the matrix, shown in Fig. 2b. By placing the SAED aperture on a region that includes both A and M phases, the combined diffraction patterns from both phases are obtained and used to infer the OR. It is found that the planes \({\left(\overline{1 }11\right)}_{\gamma^ {\prime}}||{\left(\overline{1 }10\right)}_{\alpha }\) are nearly parallel as their diffraction spots are at close proximity to each other. And, as noted before, the crystallographic zone-axes \({\left[211\right]}_{\gamma^ {\prime}}||{\left[110\right]}_{\alpha }\) are aligned. Therefore for this OR, we have \({\left(hkl\right)}_{A}={\left(\overline{1 }10\right)}_{\alpha }\) and \({\left[uvw\right]}_{A}={\left[110\right]}_{\alpha }\). More generally, the OR is expressed based on the family of corresponding planes and directions i.e., \({\left\{hkl\right\}}_{A}={\left\{\overline{1}10\right\} }_{\alpha }\) and \({\langle uvw\rangle }_{A}={\langle 110\rangle }_{\alpha }\). This OR is known as the Nishiyama-Wassermann OR [36].
The ORs were further examined using EBSD. Figure 3 presents an EBSD map on the surface of a deformed FeMnNiAl sample. The EBSD scan provides the Euler-angles at each spatial location as indicated—a triad \(({\varphi }_{1A},{\Phi }_{A},{\varphi }_{2A})\) for austenite and \(({\varphi }_{1M},{\Phi }_{M},{\varphi }_{2M})\) for martensite, with respect to a common global frame of reference \({x}_{1}-{y}_{1}-{z}_{1}\). These measured Euler angles are used to determine the OR between the phases. The orientation of each phase is given by the rotation matrices \({Q}_{A}\), \({Q}_{M}\), respectively, the columns of which represent the coordinates of the crystallographic vectors of each respective phase in the global frame. The Euler angles are obtained in the extrinsic “zxz” convention and the respective rotation matrices for both phases are given by:
The OR is visualized in a stereographic projection as illustrated in Fig. 4. All unit crystallographic directions are projected onto a selected crystallographic plane (\((0\overline{1 }1)\) in the case shown in Fig. 4a) and visualized as a 2D plot of points (Fig. 4b). The closest points from the A phase and M phase correspond to the most closely aligned/parallel directions between the phases and are used to determine the OR. The crystallographic orientation of the FCC (M) phase is taken as reference, and the BCC (A) orientation is plotted relative to it. A unit vector along the crystallographic direction \({C}_{A}={a}_{A}{\left[uvw\right]}_{\mathrm{A}}\) in the austenite phase has the components \(({x}_{A},{y}_{A})\) in the stereographic projection where:
A unit vector along the crystallographic direction \({C}_{M}={a}_{M}{\left[rst\right]}_{M}\) in the martensite phase has the components \(({x}_{M},{y}_{M})\) in the stereographic projection where:
Results of the relative orientations from EBSD site-pairs 2 and 3 from Fig. 3 are plotted in Fig. 5a, b, respectively. It is found that the Pitsch OR is followed at site 2 where \({\left\{hkl\right\}}_{A}={\left\{112\right\}}_{\alpha }\) and \({\langle uvw\rangle }_{A}={\langle 1\overline{1}0\rangle }_{\alpha }\). Whereas at site 3, the Kurdjumov–Sachs OR is followed, where \({\left\{hkl\right\}}_{A}={\left\{110\right\}}_{\alpha }\) and \({\langle uvw\rangle }_{A}={\langle 1\overline{1}1\rangle }_{\alpha }\) [36]. All three observed ORs are listed in Table 1.
Theoretical Predictions: Twinned Martensite
To predict the OR, the crystallography of the transformed martensite must be predicted in relation to the parent austenitic phase. The Bain lattice-correspondence provides the relation of the martensitic crystal structure with the austenite parent. This correspondence is such that the parent A-phase requires the least stretch, alternatively called the “Bain strain,” to transform to the M-phase crystal structure. For the BCC parent and FCC transformed martensite, the lattice correspondence and required Bain strains are shown in Fig. 6. The lattice correspondences are represented by the equations:
Note that although a crystallographic family of directions is used to represent the correspondence in (4), an orthogonal triad must be chosen for the directions in the austenite phase that become the crystallographic basis of the martensite crystal structure. There are 3 such unique correspondences. They are given by the following correspondence matrices \({Q}^{LAT}\) in Eq. (5) below. The rows of the matrix represent the lattice vectors of the austenite phase that transform to the crystallographic basis in the martensite phase, \({\left[100\right]}_{M}-{\left[010\right]}_{M}-{\left[001\right]}_{M}\) respectively. For example, in the first correspondence matrix \({Q}_{1}^{LAT}\), the orthogonal triad of lattice vectors \({\left[100\right]}_{A}-{\left[01\overline{1 }\right]}_{A}-{\left[011\right]}_{A}\) in the austenite phase transform to the crystallographic basis vectors \({\left[100\right]}_{M}-{\left[010\right]}_{M}-{\left[001\right]}_{M}\) in the martensite phase.
The corresponding unitary rotation matrices are given by \({Q}^{ROT}\) as follows:
The corresponding stretch tensors for the above correspondences, expressed in the crystallographic basis of the A phase are given by the equation:
where \({\eta }_{1}={a}_{M}/({a}_{A}\sqrt{2})\), \({\eta }_{2}={a}_{M}/{a}_{A}\).
Given the lattice-correspondences, the energy-minimization theory of martensite can be used to determine the relative orientation between the M and A phases. A brief summary of the theory is provided here and the reader is referred to refs. [37, 38] for further details. Based on the theory, the M-phase forms within the A-phase such that it follows an Invariant Plane Strain (IPS) deformation, so that the strain-energy is minimized. And to achieve such a deformation, the M-phase is generally internally twinned. In such a case, there are two variants of martensite \({{\varvec{U}}}_{{\varvec{i}}}\) and \({{\varvec{U}}}_{{\varvec{j}}}\) with \(i\ne j\) that form and the orientation of both variants must be considered individually. The fundamental equations of the theory are as follows:
where \({{\varvec{U}}}_{{\varvec{i}}}\) and \({{\varvec{U}}}_{{\varvec{j}}}\) are the two variants considered, f is the volume-fraction of \({{\varvec{U}}}_{{\varvec{j}}}\), \({{\varvec{R}}}_{{\varvec{h}}},\boldsymbol{ }{{\varvec{R}}}_{{\varvec{i}}{\varvec{j}}}\) are rotation tensors, \({\varvec{I}}\) is the identity tensor, \(\overrightarrow{a}\) is the twinning shear, \(\widehat{n}\) is the twinning plane between the variants, \(\overrightarrow{b}\) is the effective transformation shear of the IPS deformation and \(\widehat{m}\) is the habit plane of the transformation. Using Eq. (8) in (9) we have the simpler form:
The theory is well-developed to the point that, given a choice of two variants \({{\varvec{U}}}_{{\varvec{i}}}\) and \({{\varvec{U}}}_{{\varvec{j}}}\), every other term in the Eq. (9) can be determined. In other words, all Habit Plane Variants (HPVs) of the transformation can be determined starting from the choice of \({{\varvec{U}}}_{{\varvec{i}}}\) and \({{\varvec{U}}}_{{\varvec{j}}}\). Only those HPVs are considered that yield the twinning normal to be parallel to \(\langle 111\rangle\) in the M phase and the twinning shear direction parallel to the corresponding \(\langle 112\rangle\) twinning direction on the plane. In other words, it must be checked that:
By ensuring \({\overrightarrow{a}}_{FCC}\) satisfies Eq. (11), it is ensured that \(\Vert {a}_{FCC}\Vert =0.707\) which is the twinning shear in FCC. It is found that 24 independent HPV solutions exist, all within the family of habit planes \(\{0.1678, 0.6455, 0.7451\}\), consistent with prior predictions in ref. [35]. Considering one of the HPV solutions in this family, say with \(i=2\) and \(j=3\), the deformation gradients \({{\varvec{F}}}_{{\varvec{M}}2}={{\varvec{R}}}_{{\varvec{h}}}{{\varvec{U}}}_{2}\) and \({{\varvec{F}}}_{{\varvec{M}}3}={{\varvec{R}}}_{{\varvec{h}}}{{\varvec{R}}}_{{\varvec{i}}{\varvec{j}}}{{\varvec{U}}}_{{\varvec{j}}}\) are calculated. These deformation gradients represent the mapping between the crystal structure of the austenite to form each individual twin variant. To determine which OR is followed by each variant, the condition of invariance is checked for the crystallographic planes and directions corresponding to each OR (listed in Table 1). For instance, to check if the variant with deformation gradient \({{\varvec{F}}}_{{\varvec{M}}2}\) follows the Ptisch OR, the invariance of a plane normal \(\widehat{n}\in {\left\{112\right\}}_{\alpha^{\prime}}\) and unit vector \(\widehat{v}\in {\langle 1\overline{1}0\rangle }_{\alpha^{\prime}}\) must be checked. The plane normal \(\widehat{n}\) and the unit vector \(\widehat{v}\) transform under the deformation gradient as per the following equation:
An error-function \(\Delta {e}_{PCH}\) is computed as follows,
Similar error-functions are computed to check for the Kurdjumov–Sachs OR, \(\Delta {e}_{KS}\), and Nishiyama-Wassermann OR, \(\Delta {e}_{NW}\), by selecting the respective plane \(\widehat{n}\) and direction \(\widehat{v}\) accordingly from Table 1. The least magnitude of the error within the set \(\{\Delta {e}_{PCH},\Delta {e}_{NW},\Delta {e}_{KS}\}\) decides the OR. It is found that in all the HPV solutions of internally twinned martensites, one of the twin variants follows the Pitsch OR, while the other follows the Kurdjumov–Sachs OR. These predictions explain the ORs observed from EBSD in Fig. 5. To further confirm the OR, the stereographic projection of both the BCC and FCC phases are plotted. An example of a HPV solution with variants \(({\varvec{i}}=2,\boldsymbol{ }{\varvec{j}}=3)\) is used to illustrate the model predicted results. The variant \({{\varvec{U}}}_{2}\), with the deformation gradient \({{\varvec{F}}}_{{\varvec{M}}2}\) follows the Pitsch OR, while variant \({{\varvec{U}}}_{3}\) with the deformation gradient \({{\varvec{F}}}_{{\varvec{M}}3}\) follows the Kurdjumov–Sachs OR.
The stereographic projections are plotted with reference to the parent BCC phase, and a \({\left(001\right)}_{\alpha}\) projection is chosen. In this standard projection, the unit directions in the BCC crystal structure can be plotted trivially. For the FCC crystal structure, a unit vector along the crystallographic direction \({C}_{M}={a}_{M}{\left[uvw\right]}_{M}\) within variant \({{\varvec{U}}}_{2}\) has the components \(\left( {x_{M} ,y_{M} } \right)\) in the stereographic projection given by:
The stereographic projections for the variants \({{\varvec{U}}}_{2}\) and \({{\varvec{U}}}_{3}\) for the twinned martensite HPV are plotted in Figs. 7 and 8, respectively, illustrating the Pitsch OR and Kurdjumov–Sachs OR.
Theoretical Predictions: Stacking-Faulted Martensite
In addition to twinning, formation of stacking-faults is an alternative Lattice-Invariant-Deformation (LID) mode for the transformation. And given the observations of stacking faults from the SAED results in Fig. 2e, a predictive model for the OR of such a morphology is developed. A novel theory is proposed for the case of stacking-faulted martensite, proposed for the first time to the best of the authors’ knowledge. Consider the martensite forming as a single variant \({{\varvec{U}}}_{{\varvec{i}}}\) with periodically spaced stacking-faults on planes \(\widehat{n}\) and direction of faulting is parallel to the Shockley-partial Burgers vector on the plane \(\overrightarrow{a}\). Let the faults be periodically spaced by magnitude \(d\). The-stacking-faulted martensite is represented schematically in Fig. 9a. Then, for the martensite to follow an IPS deformation, the following condition must be satisfied:
where \({{\varvec{R}}}_{{\varvec{h}}}\) is a rotation tensor, \({\varvec{I}}\) is the identity tensor, \(\overrightarrow{b}\) is the effective transformation shear of the IPS deformation and \(\widehat{m}\) is the habit plane of the transformation.
For a given variant \({{\varvec{U}}}_{{\varvec{i}}}\), the slip-plane is given by \(\hat{n}_{FCC} \in {\raise0.7ex\hbox{$1$} \!\mathord{\left/ {\vphantom {1 {\sqrt 3 }}}\right.\kern-0pt} \!\lower0.7ex\hbox{${\sqrt 3 }$}}\left\{ {111} \right\}\) and \(\vec{a}_{{FCC}} \in {\raise0.7ex\hbox{$s$} \!\mathord{\left/ {\vphantom {s {\sqrt 6 }}}\right.\kern-\nulldelimiterspace} \!\lower0.7ex\hbox{${\sqrt 6 }$}}\left\langle {112} \right\rangle\), where \(s = {\raise0.7ex\hbox{$1$} \!\mathord{\left/ {\vphantom {1 {\sqrt 2 }}}\right.\kern-0pt} \!\lower0.7ex\hbox{${\sqrt 2 }$}}\), comprising a total of 12 slip systems. The normal vector \(\widehat{n}\) and fault-shear \(\overrightarrow{a}\) are given by:
Note that Eq. (16) is identical to (10) if we redefine \(d = {\raise0.7ex\hbox{$1$} \!\mathord{\left/ {\vphantom {1 f}}\right.\kern-0pt} \!\lower0.7ex\hbox{$f$}}\) Therefore, Eq. (16) can be solved following the same method as solving (10), for a given variant \({{\varvec{U}}}_{{\varvec{i}}}\), and for a given Shockley-partial slip system defined by \(\overrightarrow{a}\) and \(\widehat{n}\). It is found that 24 independent HPV solutions exist, which are also the same family of habit planes \(\{0.1678, 0.6455, 0.7451\}\). Therefore, the same HPVs can form with either an internally twinned morphology (with 2 twin variants \({{\varvec{U}}}_{{\varvec{i}}}\) and \({{\varvec{U}}}_{{\varvec{j}}}\)) or stacking-faulted morphology (with a single variant \({{\varvec{U}}}_{{\varvec{i}}}\)). Considering one of the HPV solutions in this family of stacking-faulted solutions, say with \(i=1\), the deformation gradient \({{\varvec{F}}}_{{\varvec{M}}1}\) is calculated from (16). Following the same procedures for computing the error-functions and plotting the stereographic projections as described in Sect. “Theoretical Predictions: Twinned Martensite,” it is found that the stacking-faulted variant obeys the Nishiyama-Wassermann OR (shown in Fig. 9b). Thus, all observations of ORs have been explained from a theoretical standpoint.
Discussion
A fundamental knowledge-gap in understanding of martensitic transformations lies in the interpretation of the Orientation Relationship (OR) between the parent Austenite (A) and product Martensite (M) phase. Thorough knowledge of these ORs are a prerequisite to construct and understand behavior of the A-M transformation front. Such an understanding will ultimately help uncover the unknown mechanisms of slip-emission at these interfaces. These relationships have been proposed for several SMAs and it can often be a tacit presumption that these relationships are “exact” and are unique for a specific SMA system. In this study, experimental results on FeMnNiAl show that multiple ORs are possible, independently observing a combination of the Nishiyama-Wassermann OR, the Pitsch OR, and the Kurdjumov–Sachs OR. And in all the results, it is obvious that the ORs are not obeyed exactly but only within a certain tolerance of mismatch, of the order of few degrees. This can be observed in the lacking coincidence of the TEM diffraction spots in Fig. 2c or of the points on the stereographic projections in Fig. 5. Although it must be mentioned that the alignment is still close, evidenced by the high proximity of the spots/points. Given these results, the focus is to address the origin of these multiple ORs based on the morphology of the underlying martensitic structure.
The modeling approach applies the energy-minimization theory of martensite to predict the ORs. This is a continuum theory that is generally used to predict the irrational Miller indices of the habit planes of the transformation. In this study, the same theory is combined with the crystallography of the transformation, involving the Bain lattice correspondences to predict the OR. The OR is clearly shown to depend on the internal morphology of martensite whether twinned or stacking-faulted. If the martensite is twinned, then the individual twin variants explain the Pitsch and Kurdjumov–Sachs ORs. And if the martensite is stacking-faulted, the Nishiyama-Wassermann OR is explained. Additionally, it is proposed that the effective rotation \({{\varvec{R}}}_{{\varvec{h}}}\) in both morphologies has a role to play [Eqs. (10) and (16)], and this rotation comes about to ensure the martensite follows an Invariant Plane-Strain (IPS) deformation. Therefore, there is an additional misorientation introduced in the variants in an effort by the martensite to minimize its strain-energy via formation on an invariant irrational plane (i.e., the habit plane). Further, the prediction of the theory checks the OR by computing finite-valued error-functions as discussed in 2.2. In that sense, the question is not which exact OR is followed but rather which OR is followed to the “nearest extent” (therefore least error \(\Delta e\)) by the martensite. And by this interpretation it is plausible to expect the material to exhibit more than one OR as it only describes the nearest rotational orientation relation between the planes and directions of both A and M phases.
This study also develops a novel theory for stacking-faulted martensite, for the first time in literature to the best of the authors’ knowledge. The stacking-faulted structure appends an additional shear \({\raise0.7ex\hbox{$1$} \!\mathord{\left/ {\vphantom {1 d}}\right.\kern-0pt} \!\lower0.7ex\hbox{$d$}}\left( {\vec{a} \otimes \hat{n}} \right)\) to the single variant \({{\varvec{U}}}_{{\varvec{i}}}\). Once this understanding is reached it becomes clear that the HPV solution for this morphology can be obtained analogously to the twinned case, as mentioned in Sect. “Theoretical Predictions: Stacking-Faulted Martensite.” The predictions are consistent with the experimental results where existence of stacking-faults in the martensite is evidenced in Fig. 2e. It is interesting to note that given the one–one correspondence between the OR and the underlying substructure of the martensite, the observed OR can be used as a marker to identify the underlying martensitic morphology as either twinned or stacking-faulted.
Conclusion
There are two key knowledge-gaps in the understanding and interpretation of these ORs. The first is regarding the exactness of these relationships. The second is regarding its uniqueness for a given material, where in fact it depends on the internal morphology of martensite. In this study, experimental research for the first time showed 3 distinct ORs for transforming FeMnNiAl (BCC to FCC transformation) Shape Memory Alloy. They are the Kurdjumov–Sachs, Nishiyama-Wassermann and Pitsch ORs. Observations of such a non-unique OR poses a basic question of whether the OR is a material property or if it can evolve depending on other microstructural factors. A theoretical treatment to predict these ORs is undertaken. It is shown that the OR depends on the internal microstructural morphology of the martensitic phase. Depending on whether the morphology corresponds to a twinned structure or stacking-faulted structure, the OR can vary. When the martensite is internally twinned, it exhibits two twin variants with a distinct twin plane. One of the variants reproduces the Pitsch OR and the other variant results in the Kurdjumov–Sachs OR. When the martensite involves stacking-faults, the corresponding single variant sustaining the faults is shown to reproduce the Nishiyama-Wassermann OR. A novel theoretical framework underlying the predictions for stacking-faulted martensite was developed for this purpose. It is shown that these ORs are not exact and there exists a non-trivial tolerance in the parallelism relations that have been proposed thus far, of the order of few degrees. It is crucial to know of the existence of such a tolerance as it dictates how the A and M lattices are oriented relative to each other and how the transformation front between them can behave during the transformation.
Data Availability
Not applicable.
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Acknowledgements
The work was initially supported by the Air Force Office of Scientific Research (AFOSR) under award number FA9550–18–1–0198 and later by the National Science Foundation (NSF-DMR) under award number 2104971, which is gratefully acknowledged.
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This article is an invited submission to Shape Memory and Superelasticity selected from presentations at the 12th European Symposium on Martensitic Transformations (ESOMAT 2022) held September 5–9, 2022 at Hacettepe University, Beytepe Campus, Ankara, Turkey, and has been expanded from the original presentation. The issue was organized by Prof. Dr. Benat Koҫkar, Hacettepe University.
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Mohammed, A.S.K., Sidharth, R., Abuzaid, W. et al. Orientation Relationships in FeMnNiAl Governed by Martensitic Substructure. Shap. Mem. Superelasticity 9, 473–484 (2023). https://doi.org/10.1007/s40830-023-00458-6
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DOI: https://doi.org/10.1007/s40830-023-00458-6