Abstract
Co–Ni–Ga alloys represent a new class of promising high-temperature shape memory alloys allowing realization of functional components for applications at elevated temperatures. Single crystals show a fully reversible pseudoelastic response at temperatures up to 500 °C. However, for most industrial applications, the application of polycrystalline material is needed. Polycrystalline Co–Ni–Ga alloys suffer from the anisotropic properties inherent to shape memory alloys, i.e., a strong orientation dependence of transformation strains, and therefore, are prone to intergranular fracture. This drawback can be curtailed by using appropriately textured material with a favorable grain-boundary orientation distribution. The current study discusses the impact of a hot-extrusion process on microstructural evolution and functional properties of polycrystalline Co–Ni–Ga high-temperature shape memory alloys paving the way to their robust application.
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References
Otsuka K, Waymann CM (1998) Shape memory materials. University Press, Cambridge
Otsuka K, Ren X (2005) Physical metallurgy of Ti–Ni-based shape memory alloys. Prog Mater Sci 50:511–678
Morgan NB (2004) Medical shape memory alloy applications - the market and its products. Mater Sci Eng, A 378:16–23
Lagoudas DC (2008) Shape memory alloys: modeling and engineering applications. Springer, LLC
Duerig TW, Melton KN, Stockel D, Wayman CM (1990) Engineering aspects of shape memory alloys. Butterworth-Heinemann, Oxford
Funakubo H (1987) Shape memory alloys. Gordon and Breach, New York
Ma J, Karaman I, Noebe RD (2010) High temperature shape memory alloys. Int Mater Rev 55(5):257–315
Liu J, Xie H, Huo Y, Zheng H, Li J (2006) Microstructure evolution in CoNiGa shape memory alloys. J Alloy Compd 420:145–157
Dadda J, Maier HJ, Karaman I, Karaca HE, Chumlyakov YI (2010) High-temperature in situ microscopy during stress-induced phase transformations in Co49Ni21Ga30 shape memory alloy single crystals. Int J Mater Res 101(12):1–11
Dadda J, Maier HJ, Karaman I, Karaca HE, Chumlyakov YI (2006) Pseudoelasticity at elevated temperatures in [001] oriented Co49Ni21Ga30 single crystals under compression. Scripta Mater 55:663–666
Dadda J, Maier HJ, Niklasch D, Karaman I, Karaca HE, Chumlyakov YI (2008) Pseudoelasticity and cyclic stability in Co49Ni21Ga30 shape-memory alloy single crystals at ambient temperature. Metall Mater Trans A 39:2026–2039
Niendorf T, Krooß P, Chumlyakov Y, Maier HJ (2015) Martensite aging—avenue to new high temperature shape memory alloys. Acta Mater 89:298–304
Dadda J, Maier HJ, Karaman I, Chumlyakov YI (2009) Cyclic deformation and austenite stabilization in Co35Ni35Al30 single crystalline high-temperature shape memory alloys. Acta Mater 57:6123–6134
Dadda J, Canadinc D, Maier HJ, Karaman I, Karaca HE, Chumlyakov YI (2007) Stress-strain-temperature behaviour of [001] single crystals of Co49Ni21Ga30 ferromagnetic shape memory alloys uder compression. Philos Mag 87(16):2313–2322
Oikawa K, Ota T, Gejima F, Ohmori T, Kainuma R, Ishida K (2001) Phase equilibria and phase transformations in new B2-type ferromagnetic shape memory alloys of Co–Ni–Ga and Co–Ni–Al systems. Mater Trans 42(11):2472–2475
Brown PJ, Ishida K, Kainuma R, Kanomata T, Neumann K-U, Oikawa K (2005) Crystal structures and phase transitions in ferromagnetic shape memory alloys based on Co–Ni–Al and Co–Ni–Ga. J Phys: Condens Matter 17(8):1301–1310
Liu J, Zheng H, Xia M, Huang Y, Li J (2005) Martensitic transformation and magnetic properties in Heusler CoNiGa magnetic shape memory alloys. Scripta Mater 52(9):935–938
Liu J, Xia M, Huang Y, Zheng H, Li J (2006) Effect of annealing on the microstructure and martensitic transformation of magnetic shape memory alloys CoNiGa. J Alloys Compd 417(1–2):96–99
Yan L, Yan X, Liang C, Yunqing M, Huibin X (2010) Microstructures and shape memory characteristics of dual-phase Co–Ni–Ga high-temperature shape memory alloys. Acta Mater 58:3655–3663
Dogan E, Karaman I, Chumlyakov YI, Luo ZP (2011) Microstructure and martensitic transformation characteristics of CoNiGa high temperature shape memory alloys. Acta Mater 59(3):1168–1183
Vollmer M, Krooss P, Segel Ch, Weidner A, Paulsen A, Frenzel J, Schaper M, Eggeler G, Maier HJ, Niendorf T (2015) Damage evolution in pseudoelastic polycristalline Co-Ni-Ga high-temperature shape memory alloys. J Alloys Compd 633:288–295
Omori T, Kusama T, Kawata S, Ohnuma I, Sutou Y, Araki Y, Ishida K, Kainuma R (2013) Abnormal grain growth induced by cyclic heat treatment. Science 341:1500–1502
Omori T, Iwaizako H, Kainuma R (2016) Abnormal grain growth induced by cyclic heat treatment in Fe-Mn-Al-Ni superelastic alloy. Mater Des 101:263–269
Krooss P, Niendorf T, Lauhoff C, Karsten E, Gerstein G, Liehr A, Maier HJ (2019) Direct microstructure design by hot extrusion - High-temperature shape memory alloys with bamboo-like microstructure corresponding. Scripta Mater 162:127–131
Maier HJ, Niendorf T, Bürgel R (2015) Handbuch Hochtemperatur-Werkstofftechnik. Springer Fachmedien, Wiesbaden
Humphreys FJ, Hatherly M (1995) Recrystallization and related annealing phenomena. Elsevier, Amsterdam
Arroyave R, Junkaew A, Chivukula A, Bajaj S, Yao C-Y, Garay A (2010) Investigation of the structural stability of Co2NiGa shape memory alloys via ab initio methods. Acta Mater 58:5220–5231
Oikawa K, Ota T, Imano Y, Omori T, Kainuma R, Ishida K (2006) Phase equilibria and phase transformation of Co − Ni − Ga ferromagnetic shape memory alloy system. J Phase Equilib Diffus 27(1):75–82
Braun C, Dake JM, Krill CE, Birringer R (2018) Abnormal grain growth mediated by fractal boundary migration at the nanoscale. Sci Rep 8(1592):1–6
Li Y, Liu HY, Fan-Bin M, Liu GD, Dai XF, Zhang M, Liu ZH, Chen JL, Wu GH (2004) Magnetic field-controlled two-way shape memory on CoNiGa single crystals. Appl Phys Lett 84(18):3594–3596
Dai XF, Wang HY, Liu GD, Wang YG, Duan XF, Chen JL, Wu GH (2006) Effenct of heat treatment on the properties of Co50Ni20Ga30 ferromagnetic shape memory alloy ribbons. J Phys D Appl Phys 39:2886–2889
Dogan E, Karaman I, Singh N, Chivukula A, Thawabi HS, Arroyave R (2012) The effect of electronic and magnetic valences on the martensitic transformation on CoNiGa shape memory alloys. Acta Mater 60:3535–3558
Lackmann J, Niendorf T, Maxisch M, Grundmeier G, Maier HJ (2011) High-resolution in situ characterization of the surface evolution of a polycrystalline NiTi SMA alloy under pseudoelastic deformation. Mater Charact 62(3):298–303
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Financial support by the Deutsche Forschungsgemeinschaft (DFG) within the Research Unit Program “Hochtemperatur-Formgedächtnislegierungen” (Project Number 200999873; Grant Nos. NI1327/3-2 and MA1175/34-2) is gratefully acknowledged.
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Karsten, E., Gerstein, G., Golovko, O. et al. Tailoring the Microstructure in Polycrystalline Co–Ni–Ga High-Temperature Shape Memory Alloys by Hot Extrusion. Shap. Mem. Superelasticity 5, 84–94 (2019). https://doi.org/10.1007/s40830-019-00208-7
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DOI: https://doi.org/10.1007/s40830-019-00208-7