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Synthesis and Characterization of New Macromolecular Epoxy Resin as an Effective Corrosion Inhibitor for C38 Steel in 1 M HCl Medium: Electrochemical Insights, Surface Morphological and Computational Approaches

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Abstract

Many efforts have been made recently to develop solutions to corrosion problems. The current study was focused on synthesizing a new epoxy compound called Tetraglycidyl orthophenyl diamine (TGOPDA) and using it as a powerful inhibitor of carbon steel C38 in 1 M HCl for the first time. Furthermore, the title molecule’s structure was discovered utilizing Fourier transform infrared spectroscopy. The corrosion inhibition and adsorption behavior of TGOPDA onto C38 surface was then evaluated in 1 M HCl utilizing the weight loss measurements, thermodynamic/kinetic parameters and electrochemical techniques (Open circuit potential), Potentiodynamic polarization (PDP) and Electrochemical impedance spectroscopy (EIS)). Additionally, surface morphology (SEM/EDX) with computational tools such as: DFT (Density functional theory) calculations, RDF (Radial distribution function) analysis, MC (Monte Carlo) and MD (Molecular dynamic) simulations were combined to get insights into our inhibitor adsorption on C38 steel surface. The EIS tests demonstrated that the addition of TGOPDA improved the effectiveness of C38 steel inhibition, reaching about 95.27% at 5 mM. Furthermore, the PDP investigation demonstrated that the TGOPDA worked via a mixed-type mechanism. According to the thermodynamic kinetic characteristics, TGOPDA adsorption on C38 steel surface sites follows the Langmuir adsorption isotherm. SEM and EDX studies revealed the production of an adsorbed inhibitor protective layer on the C38 steel surface. The computational investigations based on DFT, MD, MC, and RDF proved that TGOPDA adsorbed on the metal surface formed a corrosion-protective barrier film.

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Data Availability

The datasets generated and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Authors and Affiliations

  1. Environment, Materials and Sustainable Development Team–CERNE2D, High School of Technology, Mohammed V University in Rabat, Rabat, Morocco

    Mohamed Abouchane, Abdu Molhi, Mohamed Damej, Kawtar Tassaoui & Mohammed Benmessaoud

  2. Laboratory of Organic Chemistry, Bioorganic and Environment, Chemistry Department, Faculty of Sciences, Chouaib Doukkali University, El Jadida, Morocco

    Rachid Hsissou

  3. Laboratory of Materials Engineering and Sustainable Energy (IMED-LAB), Faculty of Science, Abdelmalek Essaadi University, Tetouan, Morocco

    Anas Chraka

  4. Laboratory of Spectroscopy. Molecular Modelling Materials Nanomaterials Water and Environment–CERNE2D, Faculty of Sciences, Mohamed V University in Rabat, Rabat, Morocco

    Abdu Molhi

  5. Department of Chemistry, Faculty of Natural and Mathematics Science, University of Prishtina, 10000, Prishtina, Kosovo

    Avni Berisha

  6. University of Paris, ITODYS, CNRS, UMR 7086, 15 rue J-A de Baïf, 75013, Paris, France

    Mahamadou Seydou

  7. Molecular Chemistry and Environment Unit, Department of Chemistry, FST, UN, Nouakchott, 880, Mauritanie

    Brahim Ould Elemine

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  1. Mohamed Abouchane
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Contributions

MA: writing—original draft, validation, experimental, formal analysis, visualization. RH: experimental, investigation, resources. AC: writing—review and editing, software, conceptualization (supporting). AM: methodology. MD: conceptualization, writing—review and editing. KT: validation, conceptualization. AB: methodology, resources, writing—original draft, software. MS: validation, resources. BOE: investigation, formal analysis. MB: supervision, writing—review and editing, investigation, methodology, conceptualization.

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Correspondence to Anas Chraka or Mohammed Benmessaoud.

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Abouchane, M., Hsissou, R., Chraka, A. et al. Synthesis and Characterization of New Macromolecular Epoxy Resin as an Effective Corrosion Inhibitor for C38 Steel in 1 M HCl Medium: Electrochemical Insights, Surface Morphological and Computational Approaches. J Bio Tribo Corros 10, 21 (2024). https://doi.org/10.1007/s40735-024-00824-6

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