Abstract
Corrosion is a major problem in industries. It leads to tremendous economic losses in every country. It also causes accidents. Corrosion can be prevented by various practical methods, including using inhibitors. The use of organic corrosion inhibitors is one of the most popular, economical, and effective methods for the prevention of corrosion. Most of these organic inhibitors are toxic and for sustainable solution of corrosion, it is desirable to replace the toxic inhibitors by effective, potent and environment benign corrosion inhibitors. Recently, drugs have emerged as environmentally benign and effective alternatives to be used as corrosion inhibitors in place of traditional organic corrosion inhibitors. They provide reasonably high anticorrosive activity. Besides fresh drugs, expired drugs also act as effective corrosion inhibitors for metals and alloys. The performance of drugs can be further improved by chemical functionalization and the use of synergistic agents. This review presents recent literature on fresh and expired drugs as corrosion inhibitors for various metals and alloys in different corrosion environments encountered in the industries. The chemical structure, classification of drugs based on their medicinal/biological properties, and corrosion inhibition properties have been described in this paper. The effect of chemical modification on the performance of drugs has also been elaborated with example.
Similar content being viewed by others
Availability of Data and Materials
Data sharing does not apply to this article as no datasets were generated or analysed during the current study.
References
Sparrow GR (1994) Asia Pacific Interfinish, Australian Institute of Metal Finishing, North Melbourne,Victoria, Australia, Oct 2–6
Schiopescu A, Antonescu L, Moraru M, Camenita I (2001) EUROCORR, The European Corrosion Congress,Lake Garda, Italy, Sept–Oct.
Chen TY, Batton C B (2000) Proceedings of the 9thEuropeanSymposium on Corrosion Inhibitors, Ferrara, Italy, 1.
Ateya BG, Al Kharafi FM, El-Shamy AM et al (2009) Electrochemical desulfurization of geothermal fluids under high temperature and pressure. J Appl Electrochem 39:383–389. https://doi.org/10.1007/s10800-008-9683-3
El-Shamy AM, Shehata MF, Ismail AIM (2015) Effect of moisture contents of bentonitic clay on the corrosion behavior of steel pipelines. App Clay Sci 114:461–466. https://doi.org/10.1016/j.clay.2015.06.041
Reda Y, El-Shamy AM, Eessaa AK (2018) Effect of hydrogen embrittlement on the microstructures of electroplated steel alloy 4130. Ain Shams Engi J 9(4):2973–2982. https://doi.org/10.1016/j.asej.2018.08.004
Mukherjee D, Benchman R, Marthamuthu S (1997) Tool Alloy Steels (India) 31:22
Miksic B, Splavov T L(1995) University of Ferrara, Italy, 569.
Smith G (1984) Corrosion inhibitors for Acid mediaJ, Br. Corros 19:165
Tanwer S, Shukla S K (2022) Recent advances in the applicability of drugs as corrosion inhibitor on metal surface: A review, Current Research in Green and Sustainable Chemistry, 5: 100227, https://doi.org/10.1016/j.crgsc.2021.100227.
Sykes JM (1990) Br Corros J 25:175
Ajmal M, Mideen AS, Quraishi MA (1994) Corros Sci 36:76
Reda Y, Zohdy KM, Eessaa AK, El-Shamy A (2020) Effect of Plating Materials on the Corrosion Properties of Steel Alloy 4130. Egypt J Chem 63(2):579–597. https://doi.org/10.21608/ejchem.2019.11023.1706
Abbas AMA, Zakaria ZA, El-Shamy AM et al (2019) Utilization of 1- butylpyrrolidinium Chloride Ionic Liquid as an Eco-friendly Corrosion Inhibitor and Biocide for Oilfield Equipment: Combined Weight Loss, Electrochemical and SEM Studies. Z Phys Chem 235(4):377–406. https://doi.org/10.1515/zpch-2019-1517
Shehata MF, El-Shamy AM, Zohdy KM, Sherif E-SM, Zein E, Abedin S (2020) Studies on the Antibacterial Influence of Two Ionic Liquids and their Corrosion Inhibition Performance. Appl Sci 10(4):1444. https://doi.org/10.3390/app10041444
Nassef A E, EL-Bindary R A, El-Shamy A M, El-Hadek M A(2020) Box-Behnken design to enhance the corrosion resistance of high strength steel alloy in 3.5 wt.% NaCl solution, Moroccan Journal of Chemistry, 8(4): 788–80 doi:https://doi.org/10.48317/IMIST.PRSM/morjchem-v8i4.21594
Muhammad F et al .(2018) General properties and comparison of the corrosion inhibition efficiencies of the triazole derivatives for mild steel" Corrosion Reviews, vol. 36( 6) 2018: 507–545. https://doi.org/10.1515/corrrev-2018-0006
El-Shamy A (2020) A Review on: Biocidal Activity of Some Chemical Structures and Their Role in Mitigation of Microbial Corrosion. Egypt J Chem 63(12):5251–5267. https://doi.org/10.21608/ejchem.2020.32160.2683
Alamry KA, Khan A, Aslam J, Hussein MA, Aslam R(2023) Corrosion inhibition of mild steel in hydrochloric acid solution by the expired Ampicillin drug, Sci Rep.25;13(1):6724. doi: https://doi.org/10.1038/s41598-023-33519-y.
El-Shamy A et al (2022) Fabrication, Characterization, And Monitoring Of The Propagation Of Nanocrystalline Zno Thin Film On Ito Substrate Using Electrodeposition Technique. Egypt J Chem 66(2):33–44. https://doi.org/10.21608/ejchem.2022.126134.5595
Megahed M, Abdel Bar M, Abouelez ES, El-Shamy A (2021) Polyamide Coating as a Potential Protective Layer Against Corrosion of Iron Artifacts. Egypt J Chem 64(10):5693–5702. https://doi.org/10.21608/ejchem.2021.70550.3555
Mouneir S, Elhagrasi A, El-Shamy A (2022) A Review on The Chemical Compositions of Natural Products and Their Role in Setting Current Trends and Future Goals. Egypt J Chem 65(5):491–506. https://doi.org/10.21608/ejchem.2021.95577.4486
Popoola L (2019) Organic green corrosion inhibitors (OGCIs): a critical review. Corros Rev 37(2):71–102. https://doi.org/10.1515/corrrev-2018-0058
Franger S, Sherif, El-Sayed M. et al (2014) Corrosion and Corrosion Inhibition of High Strength Low Alloy Steel in 2.0 M Sulfuric Acid Solutions by 3-Amino-1,2,3-triazole as a Corrosion Inhibitor, Journal of Chemistry, 2014, 538794 https://doi.org/10.1155/2014/538794
El-Shamy A M et al(2020) Optimization of the Influencing Variables on the Corrosion Property of Steel Alloy 4130 in 3.5 wt.% NaCl Solution, Journal of Chemistry, 2020: 9212491 https://doi.org/10.1155/2020/9212491
Megahed M, Youssif M, El-Shamy A (2020) Selective Formula as A Corrosion Inhibitor to Protect the Surfaces of Antiquities Made of Leather-Composite Brass Alloy. Egypt J Chem 63(12):5269–5287. https://doi.org/10.21608/ejchem.2020.41575.2841
Zohdy K M, El-Sherif R M, Ramkumar S, El-Shamy A M (2021) Quantum and electrochemical studies of the hydrogen evolution findings in corrosion reactions of mild steel in acidic medium, Upstream Oil and Gas Technology, 6: 100025 https://doi.org/10.1016/j.upstre.2020.100025.
Zohdy KM, El-Sherif RM, El-Shamy AM (2021) Corrosion and Passivation Behaviors of Tin in Aqueous Solutions of Different pH. J Bio Tribo Corros 7:74. https://doi.org/10.1007/s40735-021-00515-6
Abdel-Karim Amal & El-Shamy A (2022) A Review on Green Corrosion Inhibitors for Protection of Archeological Metal Artifacts, Journal of Bio- and Tribo-Corrosion., 8. https://doi.org/10.1007/s40735-022-00636-6.
Abdel-Karim A, El-Shamy, A & Reda Y (2022)Corrosion and Stress Corrosion Resistance of Al Zn Alloy 7075 by Nano-Polymeric Coatings. Journal of Bio- and Tribo-Corrosion. 8. https://doi.org/10.1007/s40735-022-00656-2.
Gad E & El-Shamy A (2022) Mechanism of Corrosion and Microbial Corrosion of 1,3-Dibutyl Thiourea Using the Quantum Chemical Calculations, Journal of Bio- and Tribo-Corrosion, (8) 3: 101007. https://doi.org/10.1007/s40735-022-00669-x.
Zohdy K, El-Shamy A, Kalmouch A, Gad E (2019) The corrosion inhibition of (2Z,2′Z)-4,4′-(1,2-phenylene bis(azanediyl))bis(4-oxobut-2-enoic acid) for carbon steel in acidic media using DFT. Egypt J Pet 28(4):355–359
Reda Y, Yehia HM, Mm E-S (2022) Microstructural and mechanical properties of Al-Zn alloy 7075 during RRA and triple aging. Egypt J Pet 31(1):9–13. https://doi.org/10.1016/j.ejpe.2021.12.001
Abbas MA, Ismail AS, Zakari K et al (2022) Adsorption, thermodynamic, and quantum chemical investigations of an ionic liquid that inhibits corrosion of carbon steel in chloride solutions. Sci Rep 12:12536. https://doi.org/10.1038/s41598-022-16755-6
Gece G (2011) Drugs: A review of promising novel corrosion inhibitors. Corros Sci 53(12):3873–3898. https://doi.org/10.1016/j.corsci.2011.08.006
Enick OV (2006) Do pharmaceutically active compounds have an ecological impact. Thesis, Simon Fraser University, Burnaby, M.Sc
Struck S, Schmidt U, Gruening B, Jaeger IS, . Hossbach J,Preissner R(2008) Toxicity vs. potency: elucidation of toxicity properties discriminating between toxins, drugs, and natural compoundsGenome Inform, 20: 231–242
Dohare P, Chauhan DS, Hammouti B, Quraishi MA (2017) Experimental and Dft Investigation on the Corrosion Inhibition Behavior of Expired Drug Lumerax on Mild Steel in Hydrochloric Acid. Anal Bioanal Electrochem 9:762–783
Karthikeyan S (2016) Drugs/Antibiotics as potential corrosion inhibitors for Metals-A Review Int. J Chem Tech Res 9:251
Revie RW. Uhlig's Corrosion Handbook: John Wiley & Sons; 2011.
Koch G, Varney J, Thompson N, Moghissi O, Gould M, Payer J. Corrosion NACE International. 2016:A1-F5.
Quraishi MA, Chauhan DS, Saji VS. Elsevier Inc. Amsterdam; 2020.
Hossain N, Chowdhury MA, Kchaou M. J. Adhesion Sci. Technol. 2020:1–18.
Zhuang W, Wang X, Zhu W, Zhang Y, Sun D, Zhang R, Wu C (2021) Imidazoline Gemini Surfactants as Corrosion Inhibitors for Carbon Steel X70 in NaCl Solution. ACS Omega 6(8):653–5660. https://doi.org/10.1021/acsomega.0c06103
Onyeachu IB, Obot IB, Sorour A, Abdul A, Rashid MI (2019) Corros Sci 150:183–193
Finšgar M, Jackson J (2014) Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: A review. Corros Sci 86:17–41
Onyeachu IB, Obot IB, Adesina AY (2020) Corros Sci 168:108589
Chauhan D S , Quraishi M , Sorour A A , Verma C , (2022,b). A review on corrosion inhibitors for high-pressure supercritical CO2 environment: Challenges and opportunities. Journal of Petroleum Science and Engineering 215, 110695.
Chauhan D S , El-Hajjaji F, Quraishi M (2022a). Heterocyclic ionic liquids as environmentally benign corrosion inhibitors: recent advances and future perspectives. Ionic Liquid-Based Technologies for Environmental Sustainability, pp. 279–294
Ansari F, Chauhan D S, Quraishi M ( 2021) Organic Corrosion Inhibitors: Synthesis, Characterization, Mechanism, and Applications. https://www.wiley.com/en-br/9781119794509, 343–369.
Chauhan DS, Quraishi MA (2021) Recent trends in environmentally sustainable Sweet corrosion inhibitors. J Mol Liq 326:115117
Chauhan DS, Quraishi MA, Srivastava V, Haque J, El ibrahimi B, (2021) Virgin and chemically functionalized amino acids as green corrosion inhibitors: Influence of molecular structure through experimental and in silico studies. J Mol Struct 1226:129259
Chauhan DS, Verma C, Quraishi MA (2021) Molecular structural aspects of organic corrosion inhibitors: Experimental and computational insights. J Mol Struct 1227:129374
Quraishi M A, Chauhan D S (2022a) Environmentally sustainable corrosion inhibitors in oil and gas industry. Organic Corrosion Inhibitors: Synthesis, Characterization, Mechanism, and Applications. John Wiley & Sons,. 221–240.
Quraishi M A, Chauhan D S, Ansari, A F( 2021a) Development of environmentally benign corrosion inhibitors for organic acid environments for oil-gas industry. Journal of Molecular Liquids 329, 115514.
Quraishi MA, Chauhan DS, Saji VS (2021) Heterocyclic biomolecules as green corrosion inhibitors. J Mol Liq 341:117265
Quraishi MA, Chauhan DS et al (2021) Polyethyleneimine Functionalized Graphene Oxide: A Promising Inhibitor for Corrosion of Copper in the Hydrochloric Acid Environment. J Nanosci Nanotechnol 21:3256–3268
Ramesh T, Chauhan DS, Quraishi MA (2021) Coconut coir dust extract (CCDE) as green corrosion inhibitor for rebar’ steel in concrete environment. International Journal of Corrosion and Scale Inhibition 10:618–633
Salman M, Ansari K, Srivastava V, Chauhan DS, Haque J, Quraishi M (2021) Chromeno naphthyridines based heterocyclic compounds as novel acidizing corrosion inhibitors: Experimental, surface and computational study. J Mol Liq 322:114825
Singh P, Singh Chauhan D, Singh Chauhan, S, Ahmad Quraishi M A( 2021). Synergistic Effect of Iodide Ion and N‐methyl‐N, N, N‐trioctylammonium Chloride on Corrosion Inhibition of Carbon Steel in 0.5 M H2SO4: Experimental and Computational Approach. ChemistrySelect, 6, 11417–11430.
Srivastava V, Salman M, Chauhan DS, Abdel-Azeim S, Quraishi MA (2021) (E)-2-styryl-1H-benzo [d] imidazole as novel green corrosion inhibitor for carbon steel: Experimental and computational approach. J Mol Liq 324:115010
El Ibrahimi B, Jmiai A, Bazzi L, El Issami S (2020) 2020 Amino acids and their derivatives as corrosion inhibitors for metals and alloys. Arab J Chem 13(1):740–771. https://doi.org/10.1016/j.arabjc.2017.07.013
Pathak RK, Mishra P (2015) Drugs as corrosion inhibitors: A Review. Inter Jour of Sci and Res 5(4):671–677
Abdallah M, Zaafarany I, Al-Karanee SO, Abd El-Fattah AA (2012) Antihypertensive drugs as an inhibitors for corrosion of aluminum and aluminum silicon alloys in aqueous solutions. Arab J Chem 5(2):225–234. https://doi.org/10.1016/j.arabjc.2010.08.017
Golestani G, Shahidi M, Ghazanfari D (2014) Appl Sur Sci 308:347
Hari Kumar S , Sathasivam K , Narayanan S, Srinivasan K. (2012). Inhibition Effect of Amoxycillin drug on the Corrosion of Mild Steel in 1N Hydrochloric acid Solution, International Journal of ChemTech Research, 4(3)
Mahdi AS (2014) Amoxicillin as green corrosion inhibitor for concrete reinforced steel in simulated concrete pore solution containing chloride”. International Journal of Advanced Research in Engineering and Technology 5:99–107
Aldana-Gonzalez J, Espinoza-Vazquez A,Romero-RomoM,Uruchurtu-ChavarinJ,Palomar-Pardave M (2015)Arabian J. Chem., xxx, xxx–xxx;https://doi.org/10.1016/j.arabjc.2015.08.033
Obot IB, Ebenso EE, Kabanda MM (2013) J Environ Chem Eng 1:431
Eddy NO, AandMbabaAJ OS (2008) African J Pure Appl Chem 2:132
Reza I, Ahmad E, Kareem F (2012)Afinidad LXVIII, Enero–Marzo., 557, 47.
Khan MZH, Aziz AMA, Hasan MR, Al-Mamun, (2016) Anti-Corros. Meth Mater 63:308
Naqvi I, Saleemi AR, Naveed S (2011) Cefixime: Int. J Electrochem Sci 6:146
Yao N’guessan et al (2021) Experimental and Theoretical Investigations on Copper Corrosion Inhibition by Cefixime Drug in 1M HNO3 Solution, J. of Mat. Sci. & Chem. Engi., 9(5): 11- 28https://doi.org/10.4236/msce.2021.95002
Shukla SK, Quraishi MA (2009) J Appl Electrochem 39:1517
Li HD et al (2021) Insight into Anticorrosion Mechanism of Ampicillin on Mild Steel in Acidic Environment: A Combined Experimental and Theoretical Approach. J Chem 2021:2090. https://doi.org/10.1155/2021/7675971
Shukla SK, Quraishi MA (2010) Corros Sci 52:314
Shukla SK, Quraishi MA (2009) Ceftriaxone: A Novel Corrosion Inhibitor for Mild Steel in Hydrochloric Acid. J Appl Electrochem 39(9):1517–1523
Obot IB, Obi-Egbedi NO (2010) Corros Sci 52:198
Singh AK, Quraishi MA (2011) Adsorption Properties and Inhibition of Mild Steel Corrosion in Hydrochloric Acid Solution by Ceftobiprole. J Appl Electrochem 41(1):7–18
Singh AK, Ebenso EE, Quraishi, MA (2013) Corrosion inhibition behavior of cefuzonam at mild steel/HCl acid interface. Res Chem Intermed 39:3033–3042. https://doi.org/10.1007/s11164-012-0815-3
Singh AK, Shukla SK, Singh M, Quraishi MA (2011) Inhibitive Effect of Ceftazidime on Corrosion of Mild Steel in Hydrochloric Acid Solution. Mater Chem Phys 129:68–76
Hippolyte N, Coulibaly, (2018) Copper Corrosion Inhibition by Cefpodoxime Drug in 1M Nitric Acid : Experimental and DFT approaches. Int J Innov Appl Stud 24:1299–1311
Abeng F, Anadebe V, Idim V, Edim M (2020) Anti-Corrosion Behaviour of Expired Tobramycin Drug on Carbon Steel in Acidic Medium. S Afr J Chem 73:125–130
Jebakumar T, Edison Immanuel, Sethuraman M G (2013) Inter. J. Corros., 1.
Obot I B, Obi-Egbedi N O, Umoren S A (2009) Antifungal drugs as corrosion inhibitors for aluminium in 0.1M HCl, Corrosion Science, 51(8): 1868–1875 https://doi.org/10.1016/j.corsci.2009.05.017.
Obot IB, Onyeachu IB, Umoren SA (2019) Corros Sci 159:108140
Mohammed KZ, Hamdy A, Abbas M (2012) RJPBCS 3:912
Singh P, Quraishi MA, Ebenso E (2012) Int J Electrochem Sci 7:12270
Singh A, Ebenso EE, Quraishi MA (2012) Int J Electrochem Sci 7:4766
Sundaram RG, Vengatesh G, Sundaravadivelu M (2021) Surface Morphological and Quantum Chemical Studies of Some Expired Drug Molecules as Potential Corrosion Inhibitors for Mild Steel in Chloride Medium. Surf Interfaces 22:100841
Bhata JI, Alva VDP (2011) Arch Appl Sci Res 3:343
Singh P, Singh A, Quraishi MA, Ebenso EE (2012) Int J Electrochem Sci 7:7065
Ahamad I, Prasad R, Quraishi MA (2010) Experimental and Theoretical Investigations of Adsorption of Fexofenadine at Mild Steel/Hydrochloric Acid Interface as Corrosion Inhibitor. J Solid State Electrochem 14(11):2095–2105
Quartarone G, Ronchin L, Vavasori A, Tortato C, Bonaldo L (2012) Corros Sci 64:82
Karthik G, Sundaravadivelu M (2016) Egyptian J. Petrol, 25,:183.
Verma C, Quraishi MA,Verma NK (2016) Ain Shams Eng. J. xxx, xxx–xxx; https://doi.org/10.1016/j.asej.2016.07.003
Reza I, Saleemi AR, Naveed S (2011) Polish J. Chem Tech 13:67
Al-Shafey H I,Hameed A,Ali RS, Abd el-Aleem FA, Aboul-Magd S, Salah M (2014) Int. J. Pharm. Sci. Rev. Res., 27: 146.
Akpan A, Offiong NO (2015) Chem Mater Res 7:17
Singh AK, Khan S, Singh A, Quraishi SM, Quraishi MA, Ebenso EE (2013) Inhibitive effect of chloroquine towards corrosion of mild steel in hydrochloric acid solution. Res Chem Intermed 39(3):1191–1208
Verma C, Quraishi MA, Ebenso EE (2013) Int J Electrochem Sci 8:7401
Deyab MA, El-Shamy OAA, Thabet HK et al (2023) Electrochemical and theoretical investigations of favipiravir drug performance as ecologically benign corrosion inhibitor for aluminum alloy in acid solution. Sci Rep 13:8680. https://doi.org/10.1038/s41598-023-35226-0
Matad PB, Mokshanatha PB, Hebbar N, Venkatesha VT, Tandon HC (2014) Ind Eng Chem Res 53:8436
Tasić ZZ, Mihajlović MBP, Simonović AT et al ( 2019) Ibuprofen as a corrosion inhibitor for copper in synthetic acid rain solution. Sci Rep 9:14710. https://doi.org/10.1038/s41598-019-51299-2
Singh AK, Quraishi MA (2010) Inhibitive effect of diethylcarbamazine on the corrosion of mild steel in hydrochloric acid. Corros Sci 52(4):1529–1535
Samide A, Tutunaru B, Ionescu C, Rotaru P, Simoiu L (2014) J Therm Anal Calorim 118:631
Gupta NK, Gopal C, Srivastava V, Quraishi MA (2017) Application of expired drugs in corrosion inhibition of mild steel. Int J Pharm Chem Anal 4:8–12
Abood HA (2011) The study of the inhibitory properties of Omeprazole on the corrosion of Aluminum 6063 in alkaline media. Bas J Sci 28:74–93
Adil H (2015) Corrosion inhibition of zinc metal in 2M hydrochloric acid solution by using Guaifenesin drug as an inhibitor and theoretical calculations. Journal of AlNahrain University 18:60–65
Abdallah M (2019) Ketamine drug as an inhibitor for the corrosion of 316 stainless steel in 2M HCl solution. Int J Electrochem Sci 14:10227–10247. https://doi.org/10.20964/2019.11.10
Raghavendra NL et al (2019) Corrosion inhibition property of expired fluoxymesterone drug on the aluminum (Al) surface In 3 % Nacl solution. Int J Curr Pharm Res 11(3):48–50. https://doi.org/10.22159/ijcpr.2019v11i3.34100
Smith JS (2003) Outdated drugs may be useful. BMJ 326(7379):51
Dahiya Shefali et al (2018) Corrosion inhibition activity of an expired antibacterial drug in acidic media amid elucidate DFT and MD simulations. Portugaliae Electrochimica Acta 2018 36(3):213–230. https://doi.org/10.4152/pea.201803213
Vaszilcsin N, Ordodi V, Borza A (2012) Corrosion inhibitors from expired drugs. Int J Pharm 431(1–2):241–244
Chauhan DS, Sorour AA, Quraishi MA (2016) An overview of expired drugs as novel corrosion inhibitors for metals and alloys. Int J Chem Pharm Sci 4:680–691
Dan M, Vaszilcsin N, Labosel M, Pancan B (2014) Expired zosyn drug as corrosion inhibitor for carbon steal in sodium chloride solution. Chemical Bulletin of “Politehnica” University of Timisoara. Romania Series of Chemistry and Environmental Engineering 59:13–18
Onyeachu IB, Abdel-Azeim S, Chauhan DS, Quraishi MA (2021) ACS Omega 6(1):65–76
Haruna K, Saleh TA, Quraishi MA (2020) Expired metformin drug as green corrosion inhibitor for simulated oil/gas well acidizing environment. J Mol Liq 315:113716
Singh AK, Chugh B, Sah K, Banerjee P, Ebenso EE, Thakur S, Pani B (2019) Results Phys 14:102383
Hameed RSA (2010) Ranitidine drugs as non-toxic corrosion inhibitors for mild steel in hydrochloric acid medium. Port Electrochim Acta 29(4):273–285
Singh P, Chauhan DS, Srivastava K, Srivastava V, Quraishi MA (2017) Expired atorvastatin drug as corrosion inhibitor for mild steel in hydrochloric acid solution. Int J Ind Chem 8(4):363–372
Fadila B, Sihem A, Sameh A, Kardas G (2019) A study on the inhibition effect of expired amoxicillin on mild steel corrosion in 1 N HCl. Mate Res Exp 6(4):46419
Dohare P, Chauhan DS, Quraishi MA (2017) Expired podocip drug as potential corrosion inhibitor for carbon steel in acid chloride solution. Int J Corros Scale Inhib 7:25–37
El-Desoky AM, Ahmed HM, Ali AE (2015) Electrochemical and analytical study of the corrosion inhibitory behavior of expired pharmaceutical compounds for C-steel corrosion. Int J Electrochem Sci 10:5112–5129
Singh P, Chauhan DS, Chauhan SS, Singh G, Quraishi MA (2019) Chemically modifiedExpired dapsone drug as environmentally benign corrosion inhibitor for mild steel in sulphuric acid useful for industrial pickling process. J Mol Liq 286:110903
Singh A, Ansari KR, Quraishi MA, Kaya S, Guo L (2020) Aminoantipyrine derivatives as a novel eco-friendly corrosion inhibitors for P110 steel in simulating acidizing environment: experimental and computational studies. J Nat Gas Sci Eng 83:103547
Singh AK, Pandey AK, Banerjee P, Saha SK et al (2019) Eco-friendly disposal of expired anti-tuberculosis drug isoniazid and its role in the protection of metal. J Environ Chem Eng 7(2):102971
Dariva CG, Galio A F(2014) Corrosion inhibitors–principles, mechanisms and applications. In: Aliofkhazraei M (ed) Developments in corrosion protection, INTECH:Winchester, UK, pp 365–379
Acknowledgements
The authors alone are responsible for the content and writing of the paper.
Funding
No funding was received for conducting this study.
Author information
Authors and Affiliations
Contributions
All authors contributed to the study’s conception and design. Data collection and preparation of tables and figures were done by S. Yadav, M. Shukla, R. Mishra, C. Gupta, K.S. Tiwari and R.S. Nigam. The first draft of the manuscript was written by S. Yadav. All authors read and approved the final manuscript.
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no competing interests.
Consent for publication
Not applicable.
Ethics approval and consent to participate
Not applicable.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Yadav, S., Shukla, M., Mishra, R. et al. Drugs: On Sustainable and Green Solution for the Prevention of Metallic Corrosion. J Bio Tribo Corros 9, 79 (2023). https://doi.org/10.1007/s40735-023-00799-w
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s40735-023-00799-w