Abstract
Reinforced epoxy polymer nanocomposites have been employed as anti-corrosion coatings on various metallic substrates due to their beneficial characteristics and high electrochemical performances. In this work, we explore the anti-corrosion behavior of reinforced epoxy (EP) polymer nanocomposite consists of polyaniline (PANI)-tin oxide (SnO2) doped with camphor sulfonic acid (CSA). PANI-SnO2 nanocomposites doped with CSA were prepared by in situ chemical oxidative polymerization of aniline in the presence of SnO2 nanoparticles. The morphological and structural features of the prepared nanocomposites were investigated through scanning electron microcopy (SEM), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). Further, the coatings of these PANI:SnO2 nanocomposites with epoxy were employed on A-36 steel (carbon steel) substrates to investigate their corrosion protection behavior. The effect of SnO2 presence in the composite towards enhancing the corrosion protection was discussed through the Tafel polarization, polarization resistance, and electrochemical impedance spectroscopy (EIS) as well as oxygen gas permeability studies. Successful formation of potential barriers and their corrosion inhibition abilities were discussed. The EP:PANI:SnO2 composite coatings demonstrate an excellent corrosion inhibition efficiency of 98% in comparison to neat epoxy (43%). The investigation on mechanical properties of these coatings indicates improved adhesion, Young’s modulus, and tensile strength due to the presence of SnO2 nanoparticles. Owing to their enhanced conductivity, superior electrochemical performance and excellent mechanical properties, these EP:PANI:SnO2 nanocomposite coatings could form smart anti-corrosion formulations in protecting A-36 steel against harsh environments.
Similar content being viewed by others
References
Radhakrishnan S, Siju CR, Mahanta D, Patil S, Madras G (2009) Conducting polyaniline-nano-TiO2 composite for smart corrosion resistant coatings. Electrochim Acta 54:1249–1254
Fang J, Xu K, Zhu L, Tang H (2007) A study on mechanism of corrosion protection coating and its failure. Corros Sci 49(11):4232–4242
Ashassi-Sorkhabi EH (2014) Corrosion protection of mild steel by nano-colloidal polyaniline/nanodiamond composite coating in NaCl solution. J Coat Technol Res 11(3):371–380
Li J, Zhu L, Luo W, Liu Y, Tang H (2007) Correlation between one directional helical growth of polyaniline and its optical activity. J Phys Chem C 111:8383–8388
Syed JA, Lu H, Tang S, Meng X (2015) Enhanced corrosion protection of PANI-PAA/PEI multilayer composite coating for 316SS by spin coating method. Appl Surf Sci 325:160–169
Al-Hartomy OA, Khasim S, Roy A, Pasha A (2019) Highly conductive polyaniline/graphene nano-platelet composite sensor towards detection of toluene and benzene gases. Appl Phys A 125(1):12
Hamed RS, Ismail EA, Al-Sahfey HI, Abbas MA (2020) Expired indomethacin therapeutics as corrosion inhibitor for carbon steel in 1 MHcl media. J Bio Tribo Corros 6:114
Sathiyanarayannam S, Azim SS, Venkatachari G (2007) Corrosion protection of magnesium ZM 21 alloy with polyaniline-TiO2 composite containing organic coating. Prog Org Coat 59:291–296
Christopher G, Kulandainathan MA, Harichandran G (2015) Comparative study of effect of corrosion on mild steel with waterborne polyurethane dispersion containing graphene oxide versus carbon black nanocomposites. Prog Org Coat 89:199–211
Bhadra J, Al-Thani NJ, Madi NK, Al-Maadeed MA (2017) Effects of aniline concentrations on the electrical and mechanical properties of polyaniline polyvinyl alcohol blends. Arb J Chem 10(5):664–672
Arenas MC, Gabriela S, Martinez-Alvarez O, Castano VM (2014) Electrical and morphological properties of polyaniline-polyvinyl alcohol in situ nanocomposite. Composite B 56:857–861
Alam M, Ansari AA, Shaik MR, Alandis NM (2013) Optical and electrical conducting properties of Polyaniline/Tin oxide nanocomposite. Arab J Chem 6(3):341–345
Islam MA, Khan ME, Hossain MM, Hasan M (2016) Electrical conductivity retention and electrochemical activity of CSA doped graphene/gold nanoparticle@ polyaniline composites. Prog Nat Sci Mater Int 26(4):341–346
Rajyalakshmi T, Pasha A, Khasim S, Lakshmi M, Murugendrappa MV, Badi N (2020) Enhanced charge transport and anticorrosion properties of CNTs doped PANI on mild steel. J Electron Mater 49:341–352
Qi B, Lu SR, Xiao XE, Pan LL, Tan FZ, Yu JH (2014) Enhanced thermal and mechanical properties of epoxy composite by mixing thermotropic liquid crystalline epoxy grafted graphene oxide. Polym Lett 8(7):467–479
Wan YJ, Cong LX, Tang LC, Wu LB, Jiang JX (2014) Mechanical properties of epoxy composites filled with silane functionalized graphene oxide. Composite A 64:79–89
Ramezanzaden B, Ghasemi E, Mahdavian M, Changizi E, Mohammadzadeh M (2015) Covalent grafted graphene oxide nanosheets to improve the barrier and corrosion protection properties of polyerethene coatings. Carbon 93:555–573
Wang X, Xing W, Song L, Yang H, Hu Y, Yeoh GH (2012) Fabrication and characterization of graphene-reinforced waterborne polyurethane nanocomposite coatings by the sol gel method. Surf Coat Technol 206:4778–4784
Pal S, Bhadauria SS, Kumar P (2019) Pitting corrosion behavior of F304 stainless steel under the exposure of ferric chloride solution. J Bio Tribo Corros 5:91
Chang C-H, Huang T-C, Peng C-W (2012) Novel anticorrosion coatings prepared from polyaniline/graphene composites. Carbon 50(14):5044–5051
Xinliang Z (2020) Electrochemical evidence of corrosion resistance of polyaniline film on the copper surface. Int J Electrochem Sci 15:4470–4480
Reka Devi M, Saranya A, Pandiarajan J, Dharmaraja J, Prithivikumaran N, Jeyakumaran N (2019) Fabrication, spectral characterization, XRD and SEM studies on some organic acids doped polyaniline thin films on glass substrate. J King Saud Univ Sci 31(4):1290–1296
Bhadra S, Khastgir D, Singha NK, Lee JH (2009) Progress in preparation, processing and applications of polyaniline. Prog Polym Sci 34:783–810
Swarup B, Bhattacharya S (2017) Influence of SnO2 nanoparticles on the relaxation dynamics of the conductive processes in polyaniline. Phys Lett A 381(39):3424–3430
Kumar E (2019) Synthesis and characterization of SnO2 and PANI doped SnO2 nanoparticles by microwave-assisted solution method. Int J Eng Technol 2(9):2634–2640
Syed K (2019) Polyaniline-graphene nanoplatelet composite films with improved conductivity for high performance X-band microwave shielding applications. Results Phys 12:1073–1081
Pang Z, Fu J, Lv P, Huang F, Wei Q (2014) Effect of CSA concentration on the ammonia sensing properties of CSA-doped PA6/PANI composite nano fibers. Sensors 14(11):21453–21465
Syed JA, Lu H, Tang S, Meng X (2015) Enhanced corrosion protective PANI-PAA/PEI multilayer composite coatings for 316SS by spin coating technique. Appl Surf Sci 325:160–169
Ramezanzaden B, Mohamadzadeh Moghadam MH, Shohani N, Mahadavian M (2017) Effects of highly crystalline and conductive polyaniline/garphene oxide composites on the corrosion protection performance of a zinc-rich epoxy coating. Chem Eng J 320:363–375
Asifa MP, Rezaei M, Bahlakeh G (2010) Corrosion prevention of AISI 304 stainless steel in hydrochloric acid medium using garlic extract as a green corrosion inhibitor: electrochemical and theoretical studies. J Mol Liq 315:113679
Zhang ZH, Zhu LH, Gao LX, Lin T, Li WG (2017) Performance enhancement of the anti-corrosion coating based on Ce3+-polyaniline–montmorillonite composite/epoxy-ester system. J Coat Technol Res 14(5):1083–1093
Amir M, Nasirpouri F (2014) Epoxy/polyaniline-ZnO nanorods hybrid nanocomposite coatings: synthesis, characterization and corrosion protection performance of conducting paints. Prog Org Coat 77:146–159
Pourhashem S, Vaezi MR, Rashidi A (2017) Exploring Corrosion protection properties of epoxy-graphene oxide nanocomposite coatings on mild steel. Corros Sci 115:78–92
Zuo S, Chen Y, Liu W, Yao C, Li Y, Ma J, Kong Y, Mao H, Li Z, Fu Y (2017) Polyaniline/gC3N4 composites as novel media for anticorrosion coatings. J Coat Technol Res 14(6):1307–1314
Wang X, Tang F, Qi X, Lin Z, Battocchi D, Chen X (2019) Enhanced protective coatings based on nanoparticle fullerene C60 for oil & gas pipeline corrosion mitigation. Nanomaterials 9(10):1476
Chang CH, Huang TC, Peng CW, Yeh TC, Lu HI, Hung WI, Weng CJ, Yang TI, Yeh JM (2012) Novel anticorrosion coatings prepared from polyaniline/graphene composites. Carbon 50(14):5044–5051
Valentova H, Stejskal J (2010) Mechanical properties of polyaniline. Synth Met 160(7–8):832–834
Sukitpaneenit P, Thanpitcha T, Sirivat A, Weder C, Rujiravanit R (2007) Electrical conductivity and mechanical properties of polyaniline/natural rubber composite fibers. J Appl Polym Sci 106(6):4038–4046
Author information
Authors and Affiliations
Contributions
SK and AP contributed equally to carry out this research work and designing of the manuscript.
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Khasim, S., Pasha, A. Enhanced Corrosion Protection of A-36 Steel Using Epoxy-Reinforced CSA-Doped Polyaniline-SnO2 Nanocomposite Smart Coatings. J Bio Tribo Corros 7, 26 (2021). https://doi.org/10.1007/s40735-020-00455-7
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s40735-020-00455-7