Abstract
To improve the microhardness and wear resistance of Q235 steel, Stellite6/WC composite coatings were prepared on the surface of Q235 steel by laser cladding mixed powder (Stellite6, WC, W, and C powder) on its surface. The microstructure and mechanical properties of directly added WC and in situ synthesized WC were analyzed and compared by scanning electron microscope(SEM), X-ray diffractometer(XRD), microhardness tester, and friction and wear testing machine. The results showed that the main phases of the composite coatings were the γ-Co, Cr7C3, CoCx, WC, and W2C. The change of microhardness in the middle and lower parts of the composite coatings prepared by in-situ synthesized WC was smaller than that of the directly added WC. The best wear resistance was obtained for the composite coating with 12 wt% WC direct addition, which was slightly better than the composite coating with 3 wt% W in-situ. This is because when the amount of W was more than 6 wt%, some W particles could not be completely synthesized in situ in the friction test, and are easy to fall off, and the wear resistance of the cladding layer decreased sharply.
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References
Karmakar, D.P., Muvvala, G., Nath, A.K.: High-temperature abrasive wear characteristics of H13 steel modified by laser remelting and cladded with stellite 6 and stellite 6/30% WC. Surf. Coat. Technol. 422, 127498 (2021). https://doi.org/10.1016/j.surfcoat.2021.127498
Li, W., Xu, P.Q., Wang, Y.Y., Zou, Y., Gong, H.Y., Lu, F.G.: Laser synthesis and microstructure of micro- and nano-structured WC reinforced co-based cladding layers on titanium alloy. J. Alloys Compd. 749, 10–22 (2018). https://doi.org/10.1016/j.jallcom.2018.03.235
Han, T., Xiao, M., Zhang, Y., Shen, Y.: Effect of cr content on microstructure and properties of Ni-Ti-xCr coatings by laser cladding. Optik. 179, 1042–1048 (2019). https://doi.org/10.1016/j.ijleo.2018.11.044
Wang, G.Y., Zhang, J.Z., Shu, R.Y., Yang, S.: High temperature wear resistance and thermal fatigue behavior of Stellite-6/WC coatings produced by laser cladding with co-coated WC powder. Int. J. Refract. Met. Hard Mater. 81, 63–70 (2019). https://doi.org/10.1016/j.ijrmhm.2019.02.024
Weng, F., Yu, H.J., Liu, J.L., Chen, C.Z., Dai, J.J., Zhao, Z.H.: Microstructure and wear property of the Ti5Si3/TiC reinforced co-based coatings fabricated by laser cladding on Ti-6Al-4V. Opt. Laser Technol. 92, 156–162 (2017). https://doi.org/10.1016/j.optlastec.2017.01.014
Hu, M., Tang, J.C., Chen, X.G., Ye, N., Zhao, X.Y., Xu, M.M.: Microstructure and properties of WC-12Co composite coatings prepared by laser cladding. Trans. Nonferrous Met. Soc. China. 30(4), 1017–1030 (2020). https://doi.org/10.1016/s1003-6326(20)65273-6
Li, X., Zhang, C.H., Zhang, S., Wu, C.L., Liu, Y., Zhang, J.B., Babar Shahzad, M.: Manufacturing of Ti3SiC2 lubricated co-based alloy coatings using laser cladding technology. Opt. Laser Technol. 114, 209–215 (2019). https://doi.org/10.1016/j.optlastec.2019.02.001
Bartkowski, D., Kinal, G.: Microstructure and wear resistance of Stellite-6/WC MMC coatings produced by laser cladding using yb:YAG disk laser. Int. J. Refract. Met. Hard Mater. 58, 157–164 (2016). https://doi.org/10.1016/j.ijrmhm.2016.04.017
Chen, L., Chen, W.G., Li, D.Y., Jing, P.Y., Yin, H.Z., Wu, H.J., Xie, Y., Wang, X.N.: Effect of nano-La2O3 doping on the tribological behavior of laser cladded WC-12Co coating on 65Mn steel under water lubrication condition. Tribol. Int. 169, 107428 (2022). https://doi.org/10.1016/j.triboint.2022.107428
Ezquerra, B.L., Lozada, L., van den Berg, H., Wolf, M., Sánchez, J.M.: Comparison of the thermal shock resistance of WC based cemented carbides with Co and Co-Ni-Cr based binders. Int. J. Refract. Met. Hard Mater. 72, 89–96 (2018). https://doi.org/10.1016/j.ijrmhm.2017.12.021
Bartkowski, D., Młynarczak, A., Piasecki, A., Dudziak, B., Gościański, M., Bartkowska, A.: Microstructure, microhardness and corrosion resistance of Stellite-6 coatings reinforced with WC particles using laser cladding. Opt. Laser Technol. 68, 191–201 (2015). https://doi.org/10.1016/j.optlastec.2014.12.005
Xu, G.J., Kutsuna, M.: Cladding with stellite 6 + WC using a YAG laser robot system. Surf. Eng. 22(5), 345–352 (2013). https://doi.org/10.1179/174329406X98430
Quan, X.M., Ding, L.: Microstructure and property of In-Situ TiC Reinforced Co-Based Composite Coatings by Laser Cladding. Sci. Adv. Mater. 11(12), 1798–1805 (2019). https://doi.org/10.1166/sam.2019.3610
Shu, D., Li, Z.G., Zhang, K., Yao, C., Li, D., Dai, Z.: In-situ synthesized high volume fraction WC reinforced Ni-based coating by laser cladding. Mater. Lett. 195, 178–181 (2017). https://doi.org/10.1016/j.matlet.2017.02.076
Wu, P., Du, H.M., Chen, X.L., Li, Z.Q., Bai, H.L., Jiang, E.Y.: Influence of WC particle behavior on the wear resistance properties of Ni–WC composite coatings. Wear. 257(1–2), 142–147 (2004). https://doi.org/10.1016/j.wear.2003.10.019
Tian, Z.H., Zhao, Y.T., Jiang, Y.J., Ren, H.P.: Microstructure and properties of Inconel 625 + WC composite coatings prepared by laser cladding. Rare Met. 40(8), 2281–2291 (2020). https://doi.org/10.1007/s12598-020-01507-0
Zhou, S.W., Xu, T.Y., Hu, C., Wu, H., Liu, H.L., Ma, X.Q.: A comparative study of tungsten carbide and carbon nanotubes reinforced Inconel 625 composite coatings fabricated by laser cladding. Opt. Laser Technol. 140, 106967 (2021). https://doi.org/10.1016/j.optlastec.2021.106967
Li, W.Y., Yang, X.F., Xiao, J.P., Hou, Q.M.: Effect of WC mass fraction on the microstructure and friction properties of WC/Ni60 laser cladding layer of brake discs. Ceram. Int. 47(20), 28754–28763 (2021). https://doi.org/10.1016/j.ceramint.2021.07.035
Ortiz, A., García, A., Cadenas, M., Fernández, M.R., Cuetos, J.M.: WC particles distribution model in the cross-section of laser cladded NiCrBSi + WC coatings, for different wt% WC. Surf. Coat. Technol. 324, 298–306 (2017). https://doi.org/10.1016/j.surfcoat.2017.05.086
Liu, J.D., Sun, W.L., Huang, Y.: Effect of carbon nanotubes content on microstructure and properties of WC/Ni laser cladding coatings. Surf. Eng. 37(5), 650–657 (2020). https://doi.org/10.1080/02670844.2020.1812481
Zhou, S.F., Xu, Y.B., Liao, B.Q., Sun, Y.J., Dai, X.Q., Yang, J.X., Li, Z.Y.: Effect of laser remelting on microstructure and properties of WC reinforced Fe-based amorphous composite coatings by laser cladding. Opt. Laser Technol. 103, 8–16 (2018). https://doi.org/10.1016/j.optlastec.2018.01.024
Dai, Q.L., Luo, C.B., You, F.Y.: Crack Restraining Methods and their Effects on the Microstructures and Properties of Laser Cladded WC/Fe Coatings. Materials. 11(12) (2018). https://doi.org/10.3390/ma11122541
Li, Q.T., Lei, Y.P., Fu, H.G.: Laser cladding in-situ NbC particle reinforced Fe-based composite coatings with rare earth oxide addition. Surf. Coat. Technol. 239, 102–107 (2014). https://doi.org/10.1016/j.surfcoat.2013.11.026
Zhang, M.M., Liu, B., Bai, P.K.: Microstructure and properties of laser cladding of 316L stainless steel on hydraulic support tube. J. Meas. Sci. Instrum. 8(2), 154–161 (2017). https://doi.org/10.3969/j.issn.1674-8042-2017-02-007
Ren, M.F., Li, R.F., Zhang, X.Q., Gu, J.Y., Jiao, C.: Effect of WC particles preparation method on microstructure and properties of laser cladded Ni60-WC coatings. J. Mater. Res. Technol. 22, 605–616 (2023). https://doi.org/10.1016/j.jmrt.2022.11.120
Xia, Y.L., Chen, H.N., Liang, X.D., Lei, J.B.: Circular oscillating laser melting deposition of nickel-based superalloy reinforced by WC: Microstructure, wear resistance and electrochemical properties. J. Manuf. Process. 68, 1694–1704 (2021). https://doi.org/10.1016/j.jmapro.2021.06.074
Farahmand, P., Liu, S., Zhang, Z., Kovacevic, R.: Laser cladding assisted by induction heating of Ni–WC composite enhanced by nano-WC and La2O3. Ceram. Int. 40(10), 15421–15438 (2014). https://doi.org/10.1016/j.ceramint.2014.06.097
Siddiqui, A.A., Dubey, A.K.: Recent trends in laser cladding and surface alloying. Opt. Laser Technol. (2021). 134https://doi.org/10.1016/j.optlastec.2020.106619
Ma, Q.S., Li, Y.J., Wang, J., Liu, K.: Homogenization of Carbides in Ni60/WC Composite Coatings made by Fiber laser remelting. Mater. Manuf. Processes. 30(12), 1417–1424 (2015). https://doi.org/10.1080/10426914.2015.1026353
Ferozhkhan, M.M., Kumar, K.G., Ravibharath, R.: Metallurgical study of stellite 6 cladding on 309-16L Stainless Steel. Arab. J. Sci. Eng. 42(5), 2067–2074 (2017). https://doi.org/10.1007/s13369-017-2457-7
Wang, C.Y., Luo, K.Y., Bu, X.Y., Su, Y.Y., Cai, J., Zhang, Q.L., Lu, J.Z.: Laser shock peening-induced surface gradient stress distribution and extension mechanism in corrosion fatigue life of AISI 420 stainless steel. Corros. Sci. 177 (2020). https://doi.org/10.1016/j.corsci.2020.109027
Yong, Y.W., Fu, W., Zhang, X., Deng, Q.L., Yang, J.G.: In-situ synthesis of WC/TaC Reinforced Nickel-Based Composite Alloy Coating by Laser Cladding. Rare Metal Materials and Engineering. 46(11), 3176–3181 (2017)
Shen, X.H., Peng, H., Xue, Y.N., Wang, B.L., Su, G.S., Zhu, J., Li, A.H.: Microstructure and Properties of WC/Ni-Based laser-clad Coatings with different WC content values. Materials. 15(18) (2022). https://doi.org/10.3390/ma15186309
Wu, Q.L., Li, W.G., Zhong, N., Gang, W., Haishan, W.: Microstructure and wear behavior of laser cladding VC–Cr7C3 ceramic coating on steel substrate. Mater. Design. 49, 10–18 (2013). https://doi.org/10.1016/j.matdes.2013.01.067
Li, Z.Y., Yan, H., Zhang, P.L., Guo, J.L., Yu, Z.S., Ringsberg, J.W.: Improving surface resistance to wear and corrosion of nickel–aluminum bronze by laser-clad TaC/Co-based alloy composite coatings. Surf. Coat. Technol. 405, 126592 (2021). https://doi.org/10.1016/j.surfcoat.2020.126592
Xu, P.H., Zhu, L.D., Xue, P.S., Yang, Z.C., Wang, S.H., Ning, J.S., Meng, G.R., Lan, Q., Qin, S.Q.: Microstructure and properties of IN718/WC-12Co composite coating by laser cladding. Ceram. Int. 48(7), 9218–9228 (2022). https://doi.org/10.1016/j.ceramint.2021.12.108
Cao, Q.Z., Fan, L., Chen, H.Y., Hou, Y., Dong, L.H., Ni, Z.W.: Wear behavior of laser cladded WC-reinforced Ni-based coatings under low temperature. Tribol. Int. 176, 107939 (2022). https://doi.org/10.1016/j.triboint.2022.107939
Raahgini, C., Verdi, D.: Abrasive wear performance of laser cladded Inconel 625 based metal matrix composites: Effect of the vanadium carbide reinforcement phase content. Surf. Coat. Technol. 429, 127975 (2022). https://doi.org/10.1016/j.surfcoat.2021.127975
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This work was supported by the Natural Science Foundation of Hebei Province (No. E2021209026).
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Conceptualization: Haoqiang Zhang, Suoxia Hou; Methodology: Chengxiang Ren, Suoxia Hou; Formal analysis and investigation: Chengxiang Ren, Zhifeng Li; Writing - original draft preparation: Hao Liu, Chengxiang Ren; Writing - review and editing: Hao Liu; Funding acquisition: Haoqiang Zhang. All authors read and approved the final manuscript.
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Zhang, H., Liu, H., Ren, C. et al. Microstructure and Properties of the Stellite6/WC Composite Coatings Prepared by Laser Cladding. Lasers Manuf. Mater. Process. 10, 645–658 (2023). https://doi.org/10.1007/s40516-023-00228-3
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DOI: https://doi.org/10.1007/s40516-023-00228-3