Abstract
With the increasing dilemma of energy crisis and climate change caused by excessive greenhouse gas emissions, it is an effective way to design low-cost and efficient catalysts to recycle CO2 into value-added chemicals and fuels to solve these problems. Downsizing catalysts close to a single crystal cell, sub-nanomaterials(SNMs) show unique size-dependent properties and great potential applications in CO2 reduction reaction (CO2RR) compared with conventional nanomaterials. In this review, basic principles of CO2RR and brief classification of SNMs are elucidated. Then, recent advances of SNMs in photo/electrocatalytic CO2 reduction are comprehensively summarized. Finally, the current challenges and future outlooks are emphasized to pave the development of CO2RR on SNMs. It is anticipated that this review would provide new insights to this unique scale and guided information on rational construction of SNMs for photo/electrocatalytic CO2RR.
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This work was supported by the National Natural Science Foundation of China (No.22071172).
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Wang, X., Zhao, Z., Zahra, K. et al. Sub-nanomaterials for Photo/Electro-catalytic CO2 Reduction: Achievements, Challenges, and Opportunities. Chem. Res. Chin. Univ. 39, 580–598 (2023). https://doi.org/10.1007/s40242-023-3123-0
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DOI: https://doi.org/10.1007/s40242-023-3123-0